PMID- 36067689 OWN - NLM STAT- MEDLINE DCOM- 20220922 LR - 20220929 IS - 1873-7072 (Electronic) IS - 0308-8146 (Linking) VI - 400 DP - 2023 Jan 30 TI - Determination of a novel pesticide cyetpyrafen and its two main metabolites in crops, soils and water. PG - 134049 LID - S0308-8146(22)02011-8 [pii] LID - 10.1016/j.foodchem.2022.134049 [doi] AB - Novel insecticide cyetpyrafen is frequently used in various crops, however, knowledge of its fate in crops and environments is largely unexplored. In this study, an effective method was firstly established for simultaneous determination of cyetpyrafen and its metabolites (M-309 and M-391) in 13 matrices (e.g., plants and soils) to explore their fate. Mean recoveries of the three compounds ranged from 73.1 % to 118.7 % with the relative standard deviations (RSDs) less than 17.9 %. Further, after 28 days of exposure in a field soil-strawberry system, cyetpyrafen and M-309 exhibited great accumulations in strawberry leaves by foliar spray while both compounds were predominately accumulated in roots by root irrigation, where cyetpyrafen was poorly translocated within plant. An equal amount of M-309 was measured in both strawberry plants and soils indicates the extensive transformation of cyetpyrafen in soil-strawberry system. Therefore, metabolism of cyetpyrafen in foods need to be considered for its better risk assessment. CI - Copyright (c) 2022 Elsevier Ltd. All rights reserved. FAU - Wang, Sijia AU - Wang S AD - State Key Laboratory for Biology of Plant Disease and Insect Pests, Institute of Plant Protection, Chinese Academy of Agricultural Sciences, Beijing 100193, China. FAU - Li, Runan AU - Li R AD - State Key Laboratory for Biology of Plant Disease and Insect Pests, Institute of Plant Protection, Chinese Academy of Agricultural Sciences, Beijing 100193, China. FAU - Dong, Fengshou AU - Dong F AD - State Key Laboratory for Biology of Plant Disease and Insect Pests, Institute of Plant Protection, Chinese Academy of Agricultural Sciences, Beijing 100193, China. FAU - Zheng, Yongquan AU - Zheng Y AD - Shandong Engineering Research Center for Environment-Friendly Agricultural Pest Management, College of Plant Health and Medicine, Qingdao Agricultural University, Qingdao 266109, China. Electronic address: zhengyongquan@qau.edu.cn. FAU - Li, Yuanbo AU - Li Y AD - State Key Laboratory for Biology of Plant Disease and Insect Pests, Institute of Plant Protection, Chinese Academy of Agricultural Sciences, Beijing 100193, China. Electronic address: liyuanbo@caas.cn. LA - eng PT - Journal Article DEP - 20220830 PL - England TA - Food Chem JT - Food chemistry JID - 7702639 RN - 0 (Insecticides) RN - 0 (Pesticides) RN - 0 (Soil) RN - 059QF0KO0R (Water) SB - IM MH - Crops, Agricultural/*chemistry/metabolism MH - *Fragaria MH - Insecticides/analysis/metabolism MH - Pesticides/*analysis/metabolism MH - Plant Leaves/metabolism MH - Plant Roots/metabolism MH - Soil/*chemistry MH - Water/*analysis/metabolism OTO - NOTNLM OT - Cyetpyrafen OT - Metabolism OT - Metabolites OT - Multiple-matrices OT - Residue analysis OT - UHPLC-MS/MS COIS- Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2022/09/07 06:00 MHDA- 2022/09/23 06:00 CRDT- 2022/09/06 18:24 PHST- 2022/02/26 00:00 [received] PHST- 2022/07/19 00:00 [revised] PHST- 2022/08/26 00:00 [accepted] PHST- 2022/09/07 06:00 [pubmed] PHST- 2022/09/23 06:00 [medline] PHST- 2022/09/06 18:24 [entrez] AID - S0308-8146(22)02011-8 [pii] AID - 10.1016/j.foodchem.2022.134049 [doi] PST - ppublish SO - Food Chem. 2023 Jan 30;400:134049. doi: 10.1016/j.foodchem.2022.134049. Epub 2022 Aug 30.