PMID- 36067896 OWN - NLM STAT- MEDLINE DCOM- 20221019 LR - 20221019 IS - 1873-2976 (Electronic) IS - 0960-8524 (Linking) VI - 363 DP - 2022 Nov TI - Microwave catalytic co-pyrolysis of Chlorella vulgaris and high density polyethylene over activated carbon supported monometallic: Characteristics and bio-oil analysis. PG - 127881 LID - S0960-8524(22)01211-1 [pii] LID - 10.1016/j.biortech.2022.127881 [doi] AB - Activated carbon (AC) has attracted much attention owing to its low cost and abundant sources. In this paper, three monometallic supported catalysts were prepared using AC as support (Ce/AC, Fe/AC, Ni/AC), and the effects of three catalysts on the microwave co-pyrolysis of Chlorella vulgaris (C. vulgaris) with high density polyethylene (HDPE) were studied. The results showed that the co-pyrolysis characteristics of C. vulgaris/HDPE = 1:1 (C1HP1) were significantly improved by three catalysts at high additions (>20 %). Among them, the C1HP1 group with 50 % Fe/AC addition had the shortest co-pyrolysis reaction time (2901 s). Besides, Ce/AC and Fe/AC have a promoting effect on bio-oil yields, while Ni/AC has an inhibiting effect. The maximum bio-oil yield (25.6 %) was obtained under 40 % addition of Fe/AC. Moreover, Ce/AC obtained the highest hydrocarbons content (66.68 %), while Fe/AC obtained the highest aromatic hydrocarbons content (36.64 %). Additionally, Ce/AC had the highest deoxygenation efficiency (47.33 %) and denitrification efficiency (42.28 %). CI - Copyright (c) 2022 Elsevier Ltd. All rights reserved. FAU - Chen, Chunxiang AU - Chen C AD - College of Mechanical Engineering, Guangxi University, University Road 100, Xixiangtang District, Nanning City 530004, China; Guangxi Key Laboratory of Petrochemical Resources Processing and Process Intensification Technology, Nanning City 530004, China; Guangdong Province Key Laboratory of Efficient and Clean Energy Utilization, Guangzhou City 510640, China. Electronic address: xiangxiang570@163.com. FAU - Fan, Dianzhao AU - Fan D AD - College of Mechanical Engineering, Guangxi University, University Road 100, Xixiangtang District, Nanning City 530004, China. FAU - Ling, Hongjian AU - Ling H AD - College of Mechanical Engineering, Guangxi University, University Road 100, Xixiangtang District, Nanning City 530004, China. FAU - Huang, Xiaodong AU - Huang X AD - College of Mechanical Engineering, Guangxi University, University Road 100, Xixiangtang District, Nanning City 530004, China. FAU - Yang, Gaixiu AU - Yang G AD - Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China. FAU - Cai, Dayong AU - Cai D AD - College of Mechanical Engineering, Guangxi University, University Road 100, Xixiangtang District, Nanning City 530004, China. FAU - Zhao, Jian AU - Zhao J AD - College of Mechanical Engineering, Guangxi University, University Road 100, Xixiangtang District, Nanning City 530004, China. FAU - Bi, Yingxin AU - Bi Y AD - College of Mechanical Engineering, Guangxi University, University Road 100, Xixiangtang District, Nanning City 530004, China. LA - eng PT - Journal Article DEP - 20220905 PL - England TA - Bioresour Technol JT - Bioresource technology JID - 9889523 RN - 0 (Bio-Oil) RN - 0 (Biofuels) RN - 0 (Hydrocarbons) RN - 0 (Plant Oils) RN - 0 (Polyphenols) RN - 16291-96-6 (Charcoal) RN - 9002-88-4 (Polyethylene) SB - IM MH - Biofuels MH - Catalysis MH - Charcoal MH - *Chlorella vulgaris MH - Hot Temperature MH - Hydrocarbons MH - Microwaves MH - Plant Oils MH - Polyethylene MH - Polyphenols MH - *Pyrolysis OTO - NOTNLM OT - Activated carbon supported catalyst OT - Bio-oil OT - Chlorella vulgaris OT - High density polyethylene OT - Microwave catalytic co-pyrolysis COIS- Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2022/09/07 06:00 MHDA- 2022/10/20 06:00 CRDT- 2022/09/06 19:25 PHST- 2022/07/18 00:00 [received] PHST- 2022/08/26 00:00 [revised] PHST- 2022/08/27 00:00 [accepted] PHST- 2022/09/07 06:00 [pubmed] PHST- 2022/10/20 06:00 [medline] PHST- 2022/09/06 19:25 [entrez] AID - S0960-8524(22)01211-1 [pii] AID - 10.1016/j.biortech.2022.127881 [doi] PST - ppublish SO - Bioresour Technol. 2022 Nov;363:127881. doi: 10.1016/j.biortech.2022.127881. Epub 2022 Sep 5.