PMID- 36073015
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220921
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 14
IP  - 37
DP  - 2022 Sep 21
TI  - Metal-Induced Aminosilica Rigidity Improves Highly Permeable Microporous 
      Membranes via Different Types of Pendant Precursors.
PG  - 42692-42704
LID - 10.1021/acsami.2c11588 [doi]
AB  - In this study, nickel-doped aminosilica membranes containing pendant groups were 
      prepared with 3-aminopropyltriethoxysilane (APTES), 
      trimethoxy[3-(methylamino)propyl]silane (MAPTS), 3 N,N-dimethyl 
      aminopropyltrimethoxysilane (DAPTMS), N-[3-(trimethoxysilylpropyl]ethylene 
      diamine (TMSPED), and 1-[3-(trimethoxysilyl)propyl] urea (TMSPU). Differences in 
      the structures of terminal amine ligands significantly contributed to the 
      formation of a coordinated structural assembly. Ultraviolet-visible spectroscopy 
      (UV-vis), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction 
      (XRD), and N(2) adsorption isotherms revealed that short and rigid pendant amino 
      groups successfully coordinated with nickel to produce subnanopores in the 
      membranes, while an ion-exchange interaction was suggested for longer and 
      sterically hindered aminosilica precursors. Moreover, the basicity of amine 
      precursors affected the affinity of ligands for the development of a coordinated 
      network. A pristine aminosilica membrane showed low levels of H(2) permeance that 
      range from 0.1 to 0.5 x 10(-6) mol m(-2) s(-1) Pa(-1) with a H(2)/N(2) permeance 
      ratio that ranges from 15 to 100. On the contrary, nickel coordination increased 
      the H(2) permeance to 0.1-3.0 x 10(-6) mol m(-2) s(-1) Pa(-1) with H(2)/N(2) 
      permeance ratios that range from 10 to 68, which indicates the formation of a 
      microporous structure and enlargement of pore sizes. The strong level of 
      coordination affinity between nickel ions and amine groups induced rearrangement 
      of the flexible pendant chain into a more rigid structure.
FAU - Anggarini, Ufafa
AU  - Anggarini U
AUID- ORCID: 0000-0003-4969-0025
AD  - Department of Chemical Engineering, Hiroshima University, 1-4-1 Kagamiyama, 
      Higashihiroshima, Hiroshima 739-8527, Japan.
AD  - Department of Chemical Engineering, Universitas Internasional Semen Indonesia, 
      Kompleks PT. Semen Indonesia (Persero) Tbk., Jln. Veteran, Gresik, 61122 East 
      Java, Indonesia.
FAU - Yu, Liang
AU  - Yu L
AUID- ORCID: 0000-0002-9071-6277
AD  - Advanced Research Institute of Multidisciplinary Science, Beijing Institute of 
      Technology, Beijing 100081, China.
FAU - Nagasawa, Hiroki
AU  - Nagasawa H
AUID- ORCID: 0000-0001-7972-2425
AD  - Department of Chemical Engineering, Hiroshima University, 1-4-1 Kagamiyama, 
      Higashihiroshima, Hiroshima 739-8527, Japan.
FAU - Kanezashi, Masakoto
AU  - Kanezashi M
AUID- ORCID: 0000-0003-1435-9754
AD  - Department of Chemical Engineering, Hiroshima University, 1-4-1 Kagamiyama, 
      Higashihiroshima, Hiroshima 739-8527, Japan.
FAU - Tsuru, Toshinori
AU  - Tsuru T
AUID- ORCID: 0000-0002-8561-4962
AD  - Department of Chemical Engineering, Hiroshima University, 1-4-1 Kagamiyama, 
      Higashihiroshima, Hiroshima 739-8527, Japan.
LA  - eng
PT  - Journal Article
DEP - 20220907
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
SB  - IM
OTO - NOTNLM
OT  - aminosilica membrane
OT  - coordination
OT  - gas permeation
OT  - nickel doping
OT  - pendant precursors
EDAT- 2022/09/09 06:00
MHDA- 2022/09/09 06:01
CRDT- 2022/09/08 02:59
PHST- 2022/09/09 06:00 [pubmed]
PHST- 2022/09/09 06:01 [medline]
PHST- 2022/09/08 02:59 [entrez]
AID - 10.1021/acsami.2c11588 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2022 Sep 21;14(37):42692-42704. doi: 
      10.1021/acsami.2c11588. Epub 2022 Sep 7.