PMID- 36080728
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220913
IS  - 2073-4360 (Electronic)
IS  - 2073-4360 (Linking)
VI  - 14
IP  - 17
DP  - 2022 Sep 2
TI  - Effect of Increased Powder-Binder Adhesion by Backbone Grafting on the Properties 
      of Feedstocks for Ceramic Injection Molding.
LID - 10.3390/polym14173653 [doi]
LID - 3653
AB  - The good interaction between the ceramic powder and the binder system is vital 
      for ceramic injection molding and prevents the phase separation during 
      processing. Due to the non-polar structure of polyolefins such as high-density 
      polyethylene (HDPE) and the polar surface of ceramics such as zirconia, there is 
      not appropriate adhesion between them. In this study, the effect of adding 
      high-density polyethylene grafted with acrylic acid (AAHDPE), with high polarity 
      and strong adhesion to the powder, on the rheological, thermal and chemical 
      properties of polymer composites highly filled with zirconia and feedstocks was 
      evaluated. To gain a deeper understanding of the effect of each component, 
      formulations containing different amounts of HDPE and or AAHDPE, zirconia and 
      paraffin wax (PW) were prepared. Attenuated total reflection spectroscopy (ATR), 
      scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and 
      rotational and capillary rheology were used for the characterization of the 
      different formulations. The ATR analysis revealed the formation of hydrogen bonds 
      between the hydroxyl groups on the zirconia surface and AAHDPE. The improved 
      powder-binder adhesion in the formulations with more AAHDPE resulted in a better 
      powder dispersion and homogeneous mixtures, as observed by SEM. DSC results 
      revealed that the addition of AAHDPE, PW and zirconia effect the melting and 
      crystallization temperature and crystallinity of the binder, the polymer-filled 
      system and feedstocks. The better powder--binder adhesion and powder dispersion 
      effectively decreased the viscosity of the highly filled polymer composites and 
      feedstocks with AAHDPE; this showed the potential of grafted polymers as binders 
      for ceramic injection molding.
FAU - Ghasemi-Mobarakeh, Laleh
AU  - Ghasemi-Mobarakeh L
AD  - Department of Textile Engineering, Isfahan University of Technology, Isfahan 
      84156-83111, Iran.
AD  - Polymer Processing, Montanuniversitaet Leoben, 8700 Leoben, Austria.
FAU - Cano, Santiago
AU  - Cano S
AUID- ORCID: 0000-0001-6361-6185
AD  - Polymer Processing, Montanuniversitaet Leoben, 8700 Leoben, Austria.
FAU - Momeni, Vahid
AU  - Momeni V
AD  - Polymer Processing, Montanuniversitaet Leoben, 8700 Leoben, Austria.
FAU - Liu, Dongyan
AU  - Liu D
AUID- ORCID: 0000-0002-1621-0083
AD  - Institute of Metal Research (IMR), Chinese Academy of Sciences, Shenyang 110016, 
      China.
FAU - Duretek, Ivica
AU  - Duretek I
AD  - Polymer Processing, Montanuniversitaet Leoben, 8700 Leoben, Austria.
FAU - Riess, Gisbert
AU  - Riess G
AUID- ORCID: 0000-0002-7642-7794
AD  - Chemistry of Polymeric Materials, Montanuniversitaet Leoben, 8700 Leoben, 
      Austria.
FAU - Kukla, Christian
AU  - Kukla C
AUID- ORCID: 0000-0002-2233-009X
AD  - Industrial Liaison Department, Montanuniversitaet Leoben, 8700 Leoben, Austria.
FAU - Holzer, Clemens
AU  - Holzer C
AUID- ORCID: 0000-0001-5149-7895
AD  - Polymer Processing, Montanuniversitaet Leoben, 8700 Leoben, Austria.
LA  - eng
GR  - 875650/Austrian Research Promotion Agency/
PT  - Journal Article
DEP - 20220902
PL  - Switzerland
TA  - Polymers (Basel)
JT  - Polymers
JID - 101545357
PMC - PMC9460726
OTO - NOTNLM
OT  - acrylic acid grafted high density polyethylene
OT  - binder
OT  - ceramic injection molding
OT  - feedstock
OT  - high density polyethylene
OT  - paraffin wax
COIS- The authors declare no conflict of interest.
EDAT- 2022/09/10 06:00
MHDA- 2022/09/10 06:01
PMCR- 2022/09/02
CRDT- 2022/09/09 01:31
PHST- 2022/07/28 00:00 [received]
PHST- 2022/08/27 00:00 [revised]
PHST- 2022/08/28 00:00 [accepted]
PHST- 2022/09/09 01:31 [entrez]
PHST- 2022/09/10 06:00 [pubmed]
PHST- 2022/09/10 06:01 [medline]
PHST- 2022/09/02 00:00 [pmc-release]
AID - polym14173653 [pii]
AID - polymers-14-03653 [pii]
AID - 10.3390/polym14173653 [doi]
PST - epublish
SO  - Polymers (Basel). 2022 Sep 2;14(17):3653. doi: 10.3390/polym14173653.