PMID- 36082833
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220921
IS  - 1463-9084 (Electronic)
IS  - 1463-9076 (Linking)
VI  - 24
IP  - 36
DP  - 2022 Sep 21
TI  - Probing combustion and catalysis intermediates by synchrotron vacuum ultraviolet 
      photoionization molecular-beam mass spectrometry: recent progress and future 
      opportunities.
PG  - 21567-21577
LID - 10.1039/d2cp02899a [doi]
AB  - Soft photoionization molecular-beam mass spectrometry (PI-MBMS) using synchrotron 
      vacuum ultraviolet (SVUV) light has been significantly developed and applied in 
      various fields in recent decades. Particularly, the tunability of SVUV light 
      enables two-dimensional measurements, i.e. mass spectrum and photoionization 
      efficiency spectrum measurements, affording isomer distinguishment in complex 
      reaction processes. Many key intermediates have been successfully detected in 
      combustion and catalysis reactions with the help of the state-of-the-art 
      SVUV-PI-MBMS, promoting the understanding of the chemical mechanisms. Herein, we 
      present a brief review of the instrumentation of beamline and PI-MBMS machines at 
      the current synchrotron user facility Hefei Light Source II and exemplify the 
      advantages of the SVUV-PI-MBMS method with recent applications in combustion and 
      catalysis research, especially in probing key reaction intermediates. Future 
      opportunities with the next generation synchrotron light source and bench-top 
      light source have also been discussed.
FAU - Zhou, Zhongyue
AU  - Zhou Z
AUID- ORCID: 0000-0002-5576-1400
AD  - School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, 
      P. R. China. zhongyue.zhou@sjtu.edu.cn.
FAU - Yang, Jiuzhong
AU  - Yang J
AUID- ORCID: 0000-0002-7076-3412
AD  - National Synchrotron Radiation Laboratory, University of Science and Technology 
      of China, Hefei, Anhui 230029, P. R. China.
FAU - Yuan, Wenhao
AU  - Yuan W
AD  - School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, 
      P. R. China. zhongyue.zhou@sjtu.edu.cn.
FAU - Wang, Zhandong
AU  - Wang Z
AD  - National Synchrotron Radiation Laboratory, University of Science and Technology 
      of China, Hefei, Anhui 230029, P. R. China.
FAU - Pan, Yang
AU  - Pan Y
AUID- ORCID: 0000-0002-9360-3809
AD  - National Synchrotron Radiation Laboratory, University of Science and Technology 
      of China, Hefei, Anhui 230029, P. R. China.
FAU - Qi, Fei
AU  - Qi F
AUID- ORCID: 0000-0003-3638-714X
AD  - School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, 
      P. R. China. zhongyue.zhou@sjtu.edu.cn.
LA  - eng
PT  - Journal Article
PT  - Review
DEP - 20220921
PL  - England
TA  - Phys Chem Chem Phys
JT  - Physical chemistry chemical physics : PCCP
JID - 100888160
SB  - IM
EDAT- 2022/09/10 06:00
MHDA- 2022/09/10 06:01
CRDT- 2022/09/09 06:53
PHST- 2022/09/10 06:00 [pubmed]
PHST- 2022/09/10 06:01 [medline]
PHST- 2022/09/09 06:53 [entrez]
AID - 10.1039/d2cp02899a [doi]
PST - epublish
SO  - Phys Chem Chem Phys. 2022 Sep 21;24(36):21567-21577. doi: 10.1039/d2cp02899a.