PMID- 36100997
OWN - NLM
STAT- MEDLINE
DCOM- 20220929
LR  - 20220929
IS  - 1520-5118 (Electronic)
IS  - 0021-8561 (Linking)
VI  - 70
IP  - 38
DP  - 2022 Sep 28
TI  - Hydrophilic Covalent Organic Frameworks Coated Steel Sheet As a Mass 
      Spectrometric Ionization Source for the Direct Determination of Zearalenone and 
      Its Derivatives.
PG  - 12211-12219
LID - 10.1021/acs.jafc.2c02868 [doi]
AB  - Zearalenone has attracted worldwide attention due to its toxic properties and 
      threat to public health. A rapid determination method for zearalenone and its 
      derivatives by hydrophilic covalent organic frameworks coated steel sheet 
      (HCOFCS) combined with ambient mass spectrometry (AMS) was developed. The HCOFCS 
      behaved as both a tip for solid-phase microextraction and a solid substrate for 
      electrospray ionization mass spectrometry (ESI-MS). To evaluate the HCOFCS-ESI-MS 
      method, five zearalenone and its derivatives in milk samples were determined, 
      including zearalenone (ZEA), alpha-zearalenol (alpha-ZEL), beta-zearalenol (beta-ZEL), 
      alpha-zearalanol (alpha-ZAL), and beta-zearalanol (beta-ZAL). After the extraction procedure, 
      the HCOFCS was directly added with a high voltage for ESI-MS, and the analysis 
      could be completed within 1 min. The developed method showed good linearity in 
      the range 0.1-100 mug/L with a coefficient of determination (R(2)) > 0.9991. The 
      limits of detection (LODs) and limits of quantitation (LOQs) ranged from 0.05 to 
      0.1 and 0.2 to 0.3 mug/L, respectively. The results demonstrated that the HCOFCS 
      combined with ESI-MS can be used for the rapid and sensitive determination of 
      trace ZEA and its derivatives in milk samples with satisfactory recoveries from 
      80.58% to 109.98% and reproducibility with relative standard deviations (RSDs) no 
      more than 11.18%. Furthermore, HCOFCS showed good reusability, which could reuse 
      at least 10 extraction cycles with satisfactory adsorption performance.
FAU - Wang, Wenhua
AU  - Wang W
AD  - Institute of Food Safety, Chinese Academy of Inspection & Quarantine, Beijing 
      100176, China.
AD  - School of Food Science and Engineering, Qingdao Agricultural University, Qingdao, 
      Shandong 266109, China.
AD  - Key Laboratory of Food Quality and Safety for State Market Regulation, Beijing 
      100176, China.
FAU - Liu, Tong
AU  - Liu T
AUID- ORCID: 0000-0002-4334-6111
AD  - Institute of Food Safety, Chinese Academy of Inspection & Quarantine, Beijing 
      100176, China.
AD  - Key Laboratory of Food Quality and Safety for State Market Regulation, Beijing 
      100176, China.
FAU - Wang, Youfa
AU  - Wang Y
AD  - Institute of Food Safety, Chinese Academy of Inspection & Quarantine, Beijing 
      100176, China.
AD  - Key Laboratory of Food Quality and Safety for State Market Regulation, Beijing 
      100176, China.
FAU - Mu, Guodong
AU  - Mu G
AD  - Institute of Food Safety, Chinese Academy of Inspection & Quarantine, Beijing 
      100176, China.
AD  - Key Laboratory of Food Quality and Safety for State Market Regulation, Beijing 
      100176, China.
FAU - Zhang, Feng
AU  - Zhang F
AUID- ORCID: 0000-0002-7888-9669
AD  - Institute of Food Safety, Chinese Academy of Inspection & Quarantine, Beijing 
      100176, China.
AD  - Key Laboratory of Food Quality and Safety for State Market Regulation, Beijing 
      100176, China.
FAU - Yang, Qingli
AU  - Yang Q
AD  - School of Food Science and Engineering, Qingdao Agricultural University, Qingdao, 
      Shandong 266109, China.
FAU - Hou, Xiudan
AU  - Hou X
AD  - School of Food Science and Engineering, Qingdao Agricultural University, Qingdao, 
      Shandong 266109, China.
LA  - eng
PT  - Journal Article
DEP - 20220913
PL  - United States
TA  - J Agric Food Chem
JT  - Journal of agricultural and food chemistry
JID - 0374755
RN  - 0 (Metal-Organic Frameworks)
RN  - 0 (zearalenol)
RN  - 12597-69-2 (Steel)
RN  - 5W827M159J (Zearalenone)
RN  - 76LO2L2V39 (Zeranol)
SB  - IM
MH  - Chromatography, High Pressure Liquid/methods
MH  - *Metal-Organic Frameworks
MH  - Reproducibility of Results
MH  - Solid Phase Extraction/methods
MH  - Steel/analysis
MH  - Tandem Mass Spectrometry/methods
MH  - *Zearalenone/chemistry
MH  - *Zeranol/analogs & derivatives
OTO - NOTNLM
OT  - HCOFCS-ESI-MS
OT  - ambient mass spectrometry
OT  - covalent organic frameworks
OT  - zearalenones
EDAT- 2022/09/15 06:00
MHDA- 2022/09/30 06:00
CRDT- 2022/09/14 00:23
PHST- 2022/09/15 06:00 [pubmed]
PHST- 2022/09/30 06:00 [medline]
PHST- 2022/09/14 00:23 [entrez]
AID - 10.1021/acs.jafc.2c02868 [doi]
PST - ppublish
SO  - J Agric Food Chem. 2022 Sep 28;70(38):12211-12219. doi: 10.1021/acs.jafc.2c02868. 
      Epub 2022 Sep 13.