PMID- 36105968 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20220917 IS - 2046-2069 (Electronic) IS - 2046-2069 (Linking) VI - 12 IP - 35 DP - 2022 Aug 10 TI - Superior quality chemically reduced graphene oxide for high performance EMI shielding materials. PG - 22608-22622 LID - 10.1039/d2ra02678c [doi] AB - The chemical reduction process of graphene oxide combined with a mild and controllable thermal treatment under vacuum at 200 degrees C for 4 hours provided a cost-effective, scalable, and high-yield route for Reduced Graphene Oxide (RGO) industrial production and became a potential candidate for producing electromagnetic interference (EMI) shielding. We investigated graphite, and RGO using l-ascorbic acid and Sodium borohydride before and after thermal treatment by carefully evaluating the chemical and morphological structures. The thermally treated l-ascorbic Acid reduction route (TCRGOL) conductivity was 2.14 x 10(3) S m(-1) and total shielding efficiency (SET) based on mass loadings per area of shielding was 94 dB with about one-tenth less graphite weight and surpassing other graphene reduction mechanisms in the frequency range of 8.2-12.4 GHz, i.e., X-band, at room temperature while being tested using the waveguide line technique. The developed treatment represents valuable progress in the path to chemical reduction using a safe reducing agent and offering superior quality RGO rarely achieved with the top-down technique, providing a high EMI shielding performance. CI - This journal is (c) The Royal Society of Chemistry. FAU - Sadek, Ramy AU - Sadek R AUID- ORCID: 0000-0001-9710-0566 AD - Chemical Engineering Department, Polytechnique Montreal Montreal H3C 3A7 Canada jamal.chaouki@polymtl.ca +1 514 340 4711, ext. 4034. FAU - Sharawi, Mohammad S AU - Sharawi MS AD - Poly-Grames Research Center, Electrical Engineering Department, Polytechnique Montreal Montreal QC H3C 3A7 Canada. FAU - Dubois, Charles AU - Dubois C AD - Chemical Engineering Department, Polytechnique Montreal Montreal H3C 3A7 Canada jamal.chaouki@polymtl.ca +1 514 340 4711, ext. 4034. FAU - Tantawy, Hesham AU - Tantawy H AUID- ORCID: 0000-0001-5481-7049 AD - Chemical Engineering Department, Military Technical College Cairo Egypt. FAU - Chaouki, Jamal AU - Chaouki J AD - Chemical Engineering Department, Polytechnique Montreal Montreal H3C 3A7 Canada jamal.chaouki@polymtl.ca +1 514 340 4711, ext. 4034. LA - eng PT - Journal Article DEP - 20220812 PL - England TA - RSC Adv JT - RSC advances JID - 101581657 PMC - PMC9372871 COIS- There are no conflicts to declare. EDAT- 2022/09/16 06:00 MHDA- 2022/09/16 06:01 PMCR- 2022/08/12 CRDT- 2022/09/15 02:34 PHST- 2022/04/27 00:00 [received] PHST- 2022/08/02 00:00 [accepted] PHST- 2022/09/15 02:34 [entrez] PHST- 2022/09/16 06:00 [pubmed] PHST- 2022/09/16 06:01 [medline] PHST- 2022/08/12 00:00 [pmc-release] AID - d2ra02678c [pii] AID - 10.1039/d2ra02678c [doi] PST - epublish SO - RSC Adv. 2022 Aug 12;12(35):22608-22622. doi: 10.1039/d2ra02678c. eCollection 2022 Aug 10.