PMID- 36132248 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20231103 IS - 2516-0230 (Electronic) IS - 2516-0230 (Linking) VI - 1 IP - 2 DP - 2019 Feb 12 TI - A high-energy sodium-ion capacitor enabled by a nitrogen/sulfur co-doped hollow carbon nanofiber anode and an activated carbon cathode. PG - 746-756 LID - 10.1039/c8na00219c [doi] AB - Nonaqueous Na-ion capacitors (NICs) have been recently regarded as potential sustainable power devices due to their high specific energy/power and the abundant distribution of sodium resources on the Earth. However, the power performance of current NICs is usually restricted by the kinetics imbalance between sodium deintercalation/intercalation in the anode and surface ion adsorption/desorption in the cathode. Herein, we demonstrate superior sodium-ion storage properties of nitrogen/sulfur co-doped hierarchical hollow carbon nanofibers (N/S-HCNFs) for their application as an ideal anode material for NICs. The N/S-HCNFs are fabricated through in situ gas sulfuration of a hollow polyaniline nanofiber precursor, which is obtained with the aid of citric acid templates. Benefiting from the positive synergistic effects of both N and S co-doping in carbon and the hierarchical hollow one-dimensional structure, the sodium-storage performance of N/S-HCNFs half-cell versus Na/Na(+) exhibits a high capacity ( approximately 447 mA h g(-1) at 50 mA g(-1)), excellent rate capability ( approximately 185 mA h g(-1) at 10 A g(-1)), and outstanding cycling stability (no capacity decay after 3000 cycles at 5 A g(-1)), which is among the best sodium-ion storage performances of carbonaceous Na-storage anodes. Furthermore, a dual-carbon NIC device is constructed with N/S-HCNFs as an anode and activated carbon (AC) as a cathode, and it has a large energy density of 116.4 W h kg(-1), a high power density of 20 kW kg(-1) (at 48.2 W h kg(-1)) and a long cycle life of 3000 cycles, which is superior to most reported AC-based NICs. CI - This journal is (c) The Royal Society of Chemistry. FAU - Liao, Ke AU - Liao K AD - Engineering Research Center of Nano-Geomaterials of Ministry of Education, Faculty of Material and Chemistry, China University of Geosciences Wuhan 430074 China wanghw@cug.edu.cn. FAU - Wang, Huanwen AU - Wang H AUID- ORCID: 0000-0001-9880-7723 AD - Engineering Research Center of Nano-Geomaterials of Ministry of Education, Faculty of Material and Chemistry, China University of Geosciences Wuhan 430074 China wanghw@cug.edu.cn. FAU - Wang, Libin AU - Wang L AD - State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology Wuhan 430074 China huxl@mail.hust.edu.cn. FAU - Xu, Dongming AU - Xu D AD - Engineering Research Center of Nano-Geomaterials of Ministry of Education, Faculty of Material and Chemistry, China University of Geosciences Wuhan 430074 China wanghw@cug.edu.cn. FAU - Wu, Mao AU - Wu M AD - Engineering Research Center of Nano-Geomaterials of Ministry of Education, Faculty of Material and Chemistry, China University of Geosciences Wuhan 430074 China wanghw@cug.edu.cn. FAU - Wang, Rui AU - Wang R AD - Engineering Research Center of Nano-Geomaterials of Ministry of Education, Faculty of Material and Chemistry, China University of Geosciences Wuhan 430074 China wanghw@cug.edu.cn. FAU - He, Beibei AU - He B AD - Engineering Research Center of Nano-Geomaterials of Ministry of Education, Faculty of Material and Chemistry, China University of Geosciences Wuhan 430074 China wanghw@cug.edu.cn. FAU - Gong, Yansheng AU - Gong Y AD - Engineering Research Center of Nano-Geomaterials of Ministry of Education, Faculty of Material and Chemistry, China University of Geosciences Wuhan 430074 China wanghw@cug.edu.cn. FAU - Hu, Xianluo AU - Hu X AUID- ORCID: 0000-0002-5769-167X AD - State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology Wuhan 430074 China huxl@mail.hust.edu.cn. LA - eng PT - Journal Article DEP - 20181105 PL - England TA - Nanoscale Adv JT - Nanoscale advances JID - 101738708 PMC - PMC9473211 COIS- There are no conflicts to declare. EDAT- 2018/11/05 00:00 MHDA- 2018/11/05 00:01 PMCR- 2018/11/05 CRDT- 2022/09/22 03:35 PHST- 2018/09/17 00:00 [received] PHST- 2018/11/04 00:00 [accepted] PHST- 2022/09/22 03:35 [entrez] PHST- 2018/11/05 00:00 [pubmed] PHST- 2018/11/05 00:01 [medline] PHST- 2018/11/05 00:00 [pmc-release] AID - c8na00219c [pii] AID - 10.1039/c8na00219c [doi] PST - epublish SO - Nanoscale Adv. 2018 Nov 5;1(2):746-756. doi: 10.1039/c8na00219c. eCollection 2019 Feb 12.