PMID- 36208512
OWN - NLM
STAT- MEDLINE
DCOM- 20221109
LR  - 20221109
IS  - 1095-8630 (Electronic)
IS  - 0301-4797 (Linking)
VI  - 324
DP  - 2022 Dec 15
TI  - Catalytic pyrolysis of high-density polyethylene over nickel-waste chicken 
      eggshell/HZSM-5.
PG  - 116392
LID - S0301-4797(22)01965-X [pii]
LID - 10.1016/j.jenvman.2022.116392 [doi]
AB  - The main objective of the current work is to investigate the effect of 
      nickel-waste chicken eggshell modified Hydrogen exchanged Zeolite Socony Mobil-5 
      (Ni-WCE/HZSM-5) on pyrolysis of high-density polyethylene (HDPE). Ni-WCE/HZSM-5 
      was synthesized via the impregnation incipient wetness (IWI) method with Ni and 
      WCE mass loading of 4 and 12 wt% respectively. HZSM-5, CaO, WCE, WCE/HZSM-5, and 
      Ni/HZSM-5 were prepared for comparison purposes with Ni-WCE/HZSM-5. All the 
      synthesized catalysts were characterized for phase analysis, metal loading, 
      surface morphology, and textural properties. The impregnation of nickel and WCE 
      had significantly affected the original framework of HZSM-5, where the 
      crystallinity percentage and average crystal size of HZSM-5 dropped to 44.97% and 
      increased to 47.90 nm respectively. The surface morphology of HZSM-5 has 
      drastically changed from a cubic-like shape into a spider web-like surface after 
      the impregnation of WCE. The BET surface area of HZSM-5 has been lowered due to 
      the impregnation of nickel and WCE, but the total pore volume has increased 
      greatly from 0.2291 cm(3)/g to 0.2621 cm(3)/g. The catalyst performance was 
      investigated in the pyrolysis of HDPE via a fixed bed reactor and the pyrolysis 
      oil was further analysed to evaluate the distribution of C(6) to C(9)> 
      hydrocarbons. Among the tested catalytic samples, the highest pyrolysis oil yield 
      was achieved by WCE (80%) followed by CaO (78%), WCE/HZSM-5 (63%), HZSM-5 (61%), 
      Ni/HZSM-5 (44%) and Ni-WCE/HZSM-5 (50%). For hydrocarbon distribution in 
      pyrolysis oil, the Ni/HZSM-5 produced the highest of total C(6) and C(7) 
      hydrocarbons at 12% and 27% respectively followed by WCE/HZSM-5 (4% and 20%), 
      non-catalytic (5% and 13%), Ni-WCE/HZSM-5 (0% and 15%), WCE (0% and 10%), HZSM-5 
      (0% and 6%) and CaO (0% and 0%).
CI  - Copyright (c) 2022 Elsevier Ltd. All rights reserved.
FAU - Mohamad Dzol, M A A
AU  - Mohamad Dzol MAA
AD  - Malaysia-Japan International Institute of Technology, Universiti Teknologi 
      Malaysia, Jalan Sultan Yahya Petra, 54100, Kuala Lumpur, Malaysia.
FAU - Balasundram, V
AU  - Balasundram V
AD  - Malaysia-Japan International Institute of Technology, Universiti Teknologi 
      Malaysia, Jalan Sultan Yahya Petra, 54100, Kuala Lumpur, Malaysia. Electronic 
      address: vekes@utm.my.
FAU - Shameli, K
AU  - Shameli K
AD  - Malaysia-Japan International Institute of Technology, Universiti Teknologi 
      Malaysia, Jalan Sultan Yahya Petra, 54100, Kuala Lumpur, Malaysia.
FAU - Ibrahim, N
AU  - Ibrahim N
AD  - Energy Research Group, School of Chemical and Energy Engineering, Faculty of 
      Engineering, Universiti Teknologi Malaysia, 81310, Johor Bahru, Johor, Malaysia.
FAU - Manan, Z A
AU  - Manan ZA
AD  - Process Systems Engineering Centre (PROSPECTS), School of Chemical and Energy 
      Engineering, Universiti Teknologi Malaysia, 81310, Johor Bahru, Johor, Malaysia.
FAU - Isha, R
AU  - Isha R
AD  - College of Engineering, Universiti Malaysia Pahang, 26600, Pekan, Pahang, 
      Malaysia.
LA  - eng
PT  - Journal Article
DEP - 20221005
PL  - England
TA  - J Environ Manage
JT  - Journal of environmental management
JID - 0401664
RN  - 9002-88-4 (Polyethylene)
RN  - 7OV03QG267 (Nickel)
RN  - 1318-02-1 (Zeolites)
RN  - 0 (Hydrocarbons)
RN  - 0 (Biofuels)
SB  - IM
MH  - Animals
MH  - *Pyrolysis
MH  - Polyethylene
MH  - Nickel/chemistry
MH  - Chickens
MH  - Egg Shell
MH  - Hot Temperature
MH  - Catalysis
MH  - *Zeolites/chemistry
MH  - Hydrocarbons
MH  - Biofuels
OTO - NOTNLM
OT  - HZSM-5
OT  - Hydrocarbons
OT  - Nickel
OT  - Plastic wastes
OT  - Pyrolysis
OT  - Waste chicken eggshell
COIS- Declaration of competing interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2022/10/09 06:00
MHDA- 2022/11/10 06:00
CRDT- 2022/10/08 18:15
PHST- 2022/03/15 00:00 [received]
PHST- 2022/09/12 00:00 [revised]
PHST- 2022/09/26 00:00 [accepted]
PHST- 2022/10/09 06:00 [pubmed]
PHST- 2022/11/10 06:00 [medline]
PHST- 2022/10/08 18:15 [entrez]
AID - S0301-4797(22)01965-X [pii]
AID - 10.1016/j.jenvman.2022.116392 [doi]
PST - ppublish
SO  - J Environ Manage. 2022 Dec 15;324:116392. doi: 10.1016/j.jenvman.2022.116392. 
      Epub 2022 Oct 5.