PMID- 36229467
OWN - NLM
STAT- MEDLINE
DCOM- 20221017
LR  - 20221206
IS  - 2041-1723 (Electronic)
IS  - 2041-1723 (Linking)
VI  - 13
IP  - 1
DP  - 2022 Oct 13
TI  - Coemissive luminescent nanoparticles combining aggregation-induced emission and 
      quenching dyes prepared in continuous flow.
PG  - 6034
LID - 10.1038/s41467-022-33857-x [doi]
LID - 6034
AB  - Achieving an ideal light-harvesting system at a low cost remains a challenge. 
      Herein, we report the synthesis of a hybrid dye system based on tetraphenylene 
      (TPE) encapsulated organic dyes in a continuous flow microreactor. The composite 
      dye nanoparticles (NPs) are synthesized based on supramolecular self-assembly to 
      achieve the co-emission of aggregation-induced emission dyes and 
      aggregation-caused quenching dyes (CEAA). Numerical simulations and molecular 
      spectroscopy were used to investigate the synthesis mechanism of the CEAA dyes. 
      Nanoparticles of CEAA dyes provide a platform for efficient cascade Forster 
      resonance energy transfer (FRET). Composite dye nanoparticles of TPE and Nile red 
      (NiR) are synthesized for an ideal light-harvesting system using coumarin 6 (C-6) 
      as an energy intermediate. The light-harvesting system has a considerable 
      red-shift distance (~126 nm), high energy-transfer efficiency (Phi(ET)) of 99.37%, 
      and an antenna effect of 26.23. Finally, the versatility of the preparation 
      method and the diversity of CEAA dyes are demonstrated.
CI  - (c) 2022. The Author(s).
FAU - Li, Chong
AU  - Li C
AUID- ORCID: 0000-0003-4132-0943
AD  - State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart 
      Materials, School of Chemical Engineering, Dalian University of Technology, 
      Dalian, 116024, China.
AD  - Department of Chemistry, School of Chemical Engineering, Dalian University of 
      Technology, Dalian, 116024, Liaoning, China.
FAU - Liu, Qi
AU  - Liu Q
AD  - Department of Chemistry, School of Chemical Engineering, Dalian University of 
      Technology, Dalian, 116024, Liaoning, China.
FAU - Tao, Shengyang
AU  - Tao S
AUID- ORCID: 0000-0002-0567-8860
AD  - State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart 
      Materials, School of Chemical Engineering, Dalian University of Technology, 
      Dalian, 116024, China. taosy@dlut.edu.cn.
AD  - Department of Chemistry, School of Chemical Engineering, Dalian University of 
      Technology, Dalian, 116024, Liaoning, China. taosy@dlut.edu.cn.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20221013
PL  - England
TA  - Nat Commun
JT  - Nature communications
JID - 101528555
RN  - 0 (Fluorescent Dyes)
SB  - IM
MH  - Fluorescence Resonance Energy Transfer
MH  - *Fluorescent Dyes/chemistry
MH  - Luminescence
MH  - *Nanoparticles/chemistry
PMC - PMC9562343
COIS- The authors declare no competing interests.
EDAT- 2022/10/14 06:00
MHDA- 2022/10/18 06:00
PMCR- 2022/10/13
CRDT- 2022/10/13 23:18
PHST- 2022/06/02 00:00 [received]
PHST- 2022/10/05 00:00 [accepted]
PHST- 2022/10/13 23:18 [entrez]
PHST- 2022/10/14 06:00 [pubmed]
PHST- 2022/10/18 06:00 [medline]
PHST- 2022/10/13 00:00 [pmc-release]
AID - 10.1038/s41467-022-33857-x [pii]
AID - 33857 [pii]
AID - 10.1038/s41467-022-33857-x [doi]
PST - epublish
SO  - Nat Commun. 2022 Oct 13;13(1):6034. doi: 10.1038/s41467-022-33857-x.