PMID- 36297968 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20221030 IS - 2073-4360 (Electronic) IS - 2073-4360 (Linking) VI - 14 IP - 20 DP - 2022 Oct 18 TI - Influence of Viscose Fibre Geometry on the Structure-Property Relationships of High-Density Polyethylene Composites. LID - 10.3390/polym14204389 [doi] LID - 4389 AB - This study investigated the influence of viscose fibre (VF) geometry on the microstructures and resulting properties of high-density polyethylene (HDPE) composites. Seven types of viscose fibres varying in cross-section shape, linear density, and length were pelletised, compounded into HDPE with a twin-screw extruder, and injection moulded. The microstructures of the composites were characterised by investigating their cross-sections and by extracting the fibres and measuring their lengths using optical microscopy (OM). The mechanical and thermal properties of the composites were characterised using differential scanning calorimetry (DSC), tensile tests, Charpy impact tests, and dynamic mechanical analysis (DMA). The composites prepared using cylindrical fibres with a linear density of 1.7 dtex exhibited the best fibre dispersion, highest orientation, and lowest fibre-fibre contact area. The decrease in the linear density of the cylindrical fibres resulted in increasingly worse dispersion and orientation, while composites containing non-cylindrical fibres exhibited a comparably larger fibre-fibre contact area. The initial fibre length of about 3 to 10 mm decreased to the mean values of 0.29 mm to 0.41 mm during processing, depending on the initial geometry. In general, cylindrical fibres exhibited a superior reinforcing effect in comparison to non-cylindrical fibres. The composites containing cylindrical fibres with a linear density of 1.7 dtex and a length of 5 mm exhibited the best reinforcing effect with an increase in tensile modulus and strength of 323% and 141%, respectively. FAU - Slapnik, Janez AU - Slapnik J AUID- ORCID: 0000-0001-6779-2012 AD - Faculty of Polymer Technology, Ozare 19, 2380 Slovenj Gradec, Slovenia. FAU - Kraft, Gregor AU - Kraft G AUID- ORCID: 0000-0002-9914-8915 AD - Faculty of Polymer Technology, Ozare 19, 2380 Slovenj Gradec, Slovenia. FAU - Wilhelm, Thomas AU - Wilhelm T AD - Faculty of Polymer Technology, Ozare 19, 2380 Slovenj Gradec, Slovenia. FAU - Hribernik, Marcel AU - Hribernik M AD - Faculty of Polymer Technology, Ozare 19, 2380 Slovenj Gradec, Slovenia. FAU - Svab, Iztok AU - Svab I AD - Faculty of Polymer Technology, Ozare 19, 2380 Slovenj Gradec, Slovenia. FAU - Lucyshyn, Thomas AU - Lucyshyn T AUID- ORCID: 0000-0003-0048-0334 AD - Department of Polymer Engineering and Science, Polymer Processing, Montanuniversitaet Leoben, Otto Gloeckel-Strasse 2, 8700 Leoben, Austria. FAU - Pinter, Gerald AU - Pinter G AUID- ORCID: 0000-0002-1790-3420 AD - Department of Polymer Engineering and Science, Polymer Processing, Montanuniversitaet Leoben, Otto Gloeckel-Strasse 2, 8700 Leoben, Austria. LA - eng GR - C3330-16-529004/Republic of Slovenia, Ministry of Education, Science and Sport and European Union, European Regional Development Fund/ PT - Journal Article DEP - 20221018 PL - Switzerland TA - Polymers (Basel) JT - Polymers JID - 101545357 PMC - PMC9607336 OTO - NOTNLM OT - compounding OT - fibre geometry OT - fibre length OT - high-density polyethylene OT - injection moulding OT - man-made cellulose fibres OT - mechanical properties OT - microstructure OT - renewable fibres OT - thermoplastic matrix composites COIS- The authors declare no conflict of interest. EDAT- 2022/10/28 06:00 MHDA- 2022/10/28 06:01 PMCR- 2022/10/18 CRDT- 2022/10/27 01:54 PHST- 2022/09/30 00:00 [received] PHST- 2022/10/13 00:00 [revised] PHST- 2022/10/14 00:00 [accepted] PHST- 2022/10/27 01:54 [entrez] PHST- 2022/10/28 06:00 [pubmed] PHST- 2022/10/28 06:01 [medline] PHST- 2022/10/18 00:00 [pmc-release] AID - polym14204389 [pii] AID - polymers-14-04389 [pii] AID - 10.3390/polym14204389 [doi] PST - epublish SO - Polymers (Basel). 2022 Oct 18;14(20):4389. doi: 10.3390/polym14204389.