PMID- 36300717
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20221215
LR  - 20221221
IS  - 1521-3773 (Electronic)
IS  - 1433-7851 (Linking)
VI  - 61
IP  - 52
DP  - 2022 Dec 23
TI  - Highly Oxidation-Resistant Electrolyte for 4.7 V Sodium Metal Batteries Enabled 
      by Anion/Cation Solvation Engineering.
PG  - e202214198
LID - 10.1002/anie.202214198 [doi]
AB  - Sodium metal batteries (SMBs) are considered as promising battery system due to 
      abundant Na sources. However, poor compatibility between electrolyte and cathode 
      severely impedes its development. Herein, we proposed an anion/cation solvation 
      strategy for realizing 4.7 V resistant SMBs electrolyte with NaClO(4) and 
      trimethoxy(pentafluorophenyl)silane (TPFS) as dual additives (DA). The ClO(4) (-) 
      can rapidly transfer to the cathode surface and strongly coordinate with Na(+) to 
      form stable polymer-like chains with solvents. Meanwhile, TPFS can preferentially 
      enter into the PF(6) (-) anion solvation sheath for reducing PF(6) -solvent 
      interaction and effectively scavenge adverse electrolyte species for protecting 
      electrode electrolyte interphases. Thus, such electrolyte elevates the oxidative 
      stability of carbonate electrolytes from 3.77 to 4.75 V, and enables Na||Na(3) 
      V(2) (PO(4) )(2) O(2) F (NVPF) battery with a capacity retention of 93 % and an 
      average Coulombic efficiency (CE) of 99.6 % after 500 cycles at 4.7 V.
CI  - (c) 2022 Wiley-VCH GmbH.
FAU - Wu, Daxiong
AU  - Wu D
AD  - School of Physics and Electronics, Hunan University, Changsha, 410082, China.
FAU - Zhu, Chunlei
AU  - Zhu C
AD  - School of Physics and Electronics, Hunan University, Changsha, 410082, China.
FAU - Wu, Mingguang
AU  - Wu M
AD  - School of Physics and Electronics, Hunan University, Changsha, 410082, China.
FAU - Wang, Huaping
AU  - Wang H
AD  - School of Physics and Electronics, Hunan University, Changsha, 410082, China.
FAU - Huang, Junda
AU  - Huang J
AD  - School of Physics and Electronics, Hunan University, Changsha, 410082, China.
FAU - Tang, Dongliang
AU  - Tang D
AD  - School of Physics and Electronics, Hunan University, Changsha, 410082, China.
FAU - Ma, Jianmin
AU  - Ma J
AUID- ORCID: 0000-0003-2081-2877
AD  - School of Physics and Electronics, Hunan University, Changsha, 410082, China.
LA  - eng
PT  - Journal Article
DEP - 20221128
PL  - Germany
TA  - Angew Chem Int Ed Engl
JT  - Angewandte Chemie (International ed. in English)
JID - 0370543
SB  - IM
OTO - NOTNLM
OT  - Additives
OT  - Electrode Electrolyte Interphases
OT  - High-Voltage Electrolytes
OT  - Sodium Metal Batteries
OT  - Solvation Sheath
EDAT- 2022/10/28 06:00
MHDA- 2022/10/28 06:01
CRDT- 2022/10/27 07:23
PHST- 2022/09/26 00:00 [received]
PHST- 2022/10/28 06:00 [pubmed]
PHST- 2022/10/28 06:01 [medline]
PHST- 2022/10/27 07:23 [entrez]
AID - 10.1002/anie.202214198 [doi]
PST - ppublish
SO  - Angew Chem Int Ed Engl. 2022 Dec 23;61(52):e202214198. doi: 
      10.1002/anie.202214198. Epub 2022 Nov 28.