PMID- 36363010 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20221117 IS - 1996-1944 (Print) IS - 1996-1944 (Electronic) IS - 1996-1944 (Linking) VI - 15 IP - 21 DP - 2022 Oct 22 TI - Influence of Quaternary Ammonium Salt Functionalized Chitosan Additive as Sustainable Filler for High-Density Polyethylene Composites. LID - 10.3390/ma15217418 [doi] LID - 7418 AB - In this study, an antimicrobial packaging material was successfully developed with blends of high-density polyethylene (HDPE) and chitosan (CS) made by melt processing. In the different HDPE/CS composites, the CS content effect (up to 40%), and the addition of quaternary ammonium salt functionalized chitosan (CS-CTAB) as an additive were evaluated by X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetric analyses (TG), tensile strength, scanning electron microscopy (SEM) and antimicrobial activity. When analyzing the effect of the additive in the different HDPE/CS composites, it was observed that the compositions with 10 and 20 %wt of chitosan showed better elongation values (~13% and 10%) as well as a higher decomposition temperature at 20% mass loss (T20) varying from (321-332 degrees C and 302-312 degrees C), respectively, in relation to the other compositions, regardless of the type of additive used, it acted as an antimicrobial agent, promoting inhibition of microbial growth against the strains gram-positive and gram-negative used in this work, making the different HDPE/CS composites suitable candidates for use in food packaging. FAU - de Araujo, Maria Jose G AU - de Araujo MJG AD - Graduate Program in Science and Materials Engineering, Federal University of Paraiba, Joao Pessoa 58051-900, Brazil. FAU - Barbosa, Francivandi C AU - Barbosa FC AD - Department of Materials Engineering, Federal University of Campina Grande, Campina Grande 58429-900, Brazil. FAU - Fook, Marcus Vinicius L AU - Fook MVL AD - Department of Materials Engineering, Federal University of Campina Grande, Campina Grande 58429-900, Brazil. FAU - Silva, Suedina Maria L AU - Silva SML AD - Department of Materials Engineering, Federal University of Campina Grande, Campina Grande 58429-900, Brazil. FAU - Leite, Itamara F AU - Leite IF AUID- ORCID: 0000-0002-9158-8609 AD - Department of Materials Engineering, Federal University of Paraiba, Joao Pessoa 58051-900, Brazil. LA - eng PT - Journal Article DEP - 20221022 PL - Switzerland TA - Materials (Basel) JT - Materials (Basel, Switzerland) JID - 101555929 PMC - PMC9657044 OTO - NOTNLM OT - HDPE OT - additive OT - antimicrobial activity OT - chitosan OT - quaternary ammonium COIS- The authors declare no conflict of interest. EDAT- 2022/11/12 06:00 MHDA- 2022/11/12 06:01 PMCR- 2022/10/22 CRDT- 2022/11/11 01:33 PHST- 2022/05/01 00:00 [received] PHST- 2022/07/18 00:00 [revised] PHST- 2022/07/22 00:00 [accepted] PHST- 2022/11/11 01:33 [entrez] PHST- 2022/11/12 06:00 [pubmed] PHST- 2022/11/12 06:01 [medline] PHST- 2022/10/22 00:00 [pmc-release] AID - ma15217418 [pii] AID - materials-15-07418 [pii] AID - 10.3390/ma15217418 [doi] PST - epublish SO - Materials (Basel). 2022 Oct 22;15(21):7418. doi: 10.3390/ma15217418.