PMID- 36365595
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20221117
IS  - 2073-4360 (Electronic)
IS  - 2073-4360 (Linking)
VI  - 14
IP  - 21
DP  - 2022 Oct 29
TI  - Assembling of Metal-Polymer Nanocomposites in Irradiated Solutions of 
      1-Vinyl-1,2,4-triazole and Au(III) Ions: Features of Polymerization and 
      Nanoparticles Formation.
LID - 10.3390/polym14214601 [doi]
LID - 4601
AB  - Gold nanoparticles (AuNPs) stabilized with poly(1-vinyl-1,2,4-triazole) (PVT) 
      have been synthesized via a one-pot manner in irradiated solutions of 
      1-vinyl-1,2,4-triazole (VT) and Au(III) ions. The transmission electron 
      microscopy examinations have shown that the sizes of nanoparticles formed range 
      from 1 to 11 nm and are affected by the ratio of VT to gold ions. To study the 
      kinetics peculiarities of the VT polymerization and assembling of AuNPs, UV-Vis 
      spectroscopy was used. The analysis of the data obtained reveals that an 
      inhibition period, influenced by Au(III) concentration, is followed by the 
      polymerization of a monomer. Importantly, the absorbed doses, corresponding to 
      the onset of rapid polymerization, correlate with the doses at which the 
      accelerated formation of AuNPs begins. The kinetics aspects, which could lead to 
      such an effect, are discussed.
FAU - Zharikov, Alexey A
AU  - Zharikov AA
AUID- ORCID: 0000-0002-2653-5332
AD  - Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, 
      Russia.
FAU - Zezina, Elena A
AU  - Zezina EA
AD  - Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, 
      Russia.
FAU - Vinogradov, Rodion A
AU  - Vinogradov RA
AD  - Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, 
      Russia.
FAU - Pozdnyakov, Alexander S
AU  - Pozdnyakov AS
AUID- ORCID: 0000-0002-9365-3697
AD  - Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy 
      of Sciences, Favorsky St., 1, 664033 Irkutsk, Russia.
FAU - Feldman, Vladimir I
AU  - Feldman VI
AUID- ORCID: 0000-0002-5407-8685
AD  - Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, 
      Russia.
FAU - Chvalun, Sergey N
AU  - Chvalun SN
AUID- ORCID: 0000-0001-9405-4509
AD  - Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of 
      Sciences, Profsoyuznaya St., 70, 117393 Moscow, Russia.
FAU - Vasiliev, Alexander L
AU  - Vasiliev AL
AD  - Moscow Institute of Physics and Technology, National Research University, 141701 
      Dolgoprudny, Russia.
FAU - Zezin, Alexey A
AU  - Zezin AA
AUID- ORCID: 0000-0003-2080-0876
AD  - Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, 
      Russia.
AD  - Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of 
      Sciences, Profsoyuznaya St., 70, 117393 Moscow, Russia.
LA  - eng
GR  - 075-15-2020-794/Ministry of Science and Higher Education of the Russian 
      Federation/
PT  - Journal Article
DEP - 20221029
PL  - Switzerland
TA  - Polymers (Basel)
JT  - Polymers
JID - 101545357
PMC - PMC9657828
OTO - NOTNLM
OT  - gold nanoparticles
OT  - kinetics of radiation-induced polymerization
OT  - metal-polymer nanocomposites
OT  - one-pot synthesis
OT  - poly(1-vinyl-1,2,4-triazole)
COIS- The authors declare no conflict of interest.
EDAT- 2022/11/12 06:00
MHDA- 2022/11/12 06:01
PMCR- 2022/10/29
CRDT- 2022/11/11 01:50
PHST- 2022/10/09 00:00 [received]
PHST- 2022/10/24 00:00 [revised]
PHST- 2022/10/25 00:00 [accepted]
PHST- 2022/11/11 01:50 [entrez]
PHST- 2022/11/12 06:00 [pubmed]
PHST- 2022/11/12 06:01 [medline]
PHST- 2022/10/29 00:00 [pmc-release]
AID - polym14214601 [pii]
AID - polymers-14-04601 [pii]
AID - 10.3390/polym14214601 [doi]
PST - epublish
SO  - Polymers (Basel). 2022 Oct 29;14(21):4601. doi: 10.3390/polym14214601.