PMID- 36375903
OWN - NLM
STAT- MEDLINE
DCOM- 20221116
LR  - 20221116
IS  - 1001-0742 (Print)
IS  - 1001-0742 (Linking)
VI  - 125
DP  - 2023 Mar
TI  - Biomass chemical looping gasification for syngas production using modified 
      hematite as oxygen carriers.
PG  - 171-184
LID - S1001-0742(21)00504-0 [pii]
LID - 10.1016/j.jes.2021.11.028 [doi]
AB  - Syngas is a clean energy carrier and a major industrial feedstock. In this paper, 
      syngas was produced via biomass chemical looping gasification (CLG) process. 
      Hematite, the most common Fe-based oxygen carrier (OC), was modified with 
      different metal oxides (CeO(2), CaO and MgO) by the impregnation method. The 
      hematite modified by CeO(2), CaO and MgO was namely as CeO(2)-hematite 
      (CeO(2)-H), CaO-hematite (CaO-H) and MgO-hematite (MgO-H), respectively. The 
      introduction of CeO(2), CaO and MgO enhanced the reactivity of lattice oxygen of 
      hematite. The optimum condition for syngas production had been explored as the 
      mass ratio of oxygen carrier to biomass (O/B) of 0.2, the mass ratio of steam to 
      biomass (S/B) of 0.75 and temperature of 800 degrees C in the biomass CLG process. The 
      CeO(2)-H exhibited the most wonderful performance compared to that for CaO-H and 
      MgO-H. The crystal composition of OC influenced greatly in the CLG process. 
      CeFeO(3) had a good oxygen mobility property and lattice oxygen releasing 
      capacity due to the most oxygen vacancy distributed on the OC surface and the 
      most active lattice oxygen, which is conducive to the biomass chemical looping 
      gasification process for syngas production, leading to the highest gasification 
      efficiency of 95.86% and gas yield of 1.20 m(3)/kg of the three. Cyclic test 
      proved that CeO(2)-H had well sintering resistance and cyclic performance.
CI  - Copyright (c) 2021. Published by Elsevier B.V.
FAU - Jiang, Cong
AU  - Jiang C
AD  - School of Environmental Science and Engineering, Huazhong University of Science 
      and Technology, Wuhan 430074, China.
FAU - Jin, Xiaoyu
AU  - Jin X
AD  - School of Environmental Science and Engineering, Huazhong University of Science 
      and Technology, Wuhan 430074, China.
FAU - Xu, Tingting
AU  - Xu T
AD  - School of Environmental Science and Engineering, Huazhong University of Science 
      and Technology, Wuhan 430074, China; State Key Laboratory of Coal Combustion, 
      Huazhong University of Science and Technology, Wuhan 430074, China. Electronic 
      address: tingtingxu1225@126.com.
FAU - Xiao, Bo
AU  - Xiao B
AD  - School of Environmental Science and Engineering, Huazhong University of Science 
      and Technology, Wuhan 430074, China.
FAU - Hu, Zhiquan
AU  - Hu Z
AD  - School of Environmental Science and Engineering, Huazhong University of Science 
      and Technology, Wuhan 430074, China.
FAU - Wang, Xun
AU  - Wang X
AD  - School of Environmental Science and Engineering, Huazhong University of Science 
      and Technology, Wuhan 430074, China. Electronic address: xunw@hust.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20211214
PL  - Netherlands
TA  - J Environ Sci (China)
JT  - Journal of environmental sciences (China)
JID - 100967627
RN  - S88TT14065 (Oxygen)
RN  - 1K09F3G675 (ferric oxide)
RN  - 0 (Gases)
RN  - 3A3U0GI71G (Magnesium Oxide)
SB  - IM
MH  - Biomass
MH  - *Oxygen
MH  - *Gases
MH  - Magnesium Oxide
OTO - NOTNLM
OT  - Chemical looping gasification
OT  - Modified hematite
OT  - Oxygen carrier
OT  - Pine sawdust
OT  - Syngas
EDAT- 2022/11/15 06:00
MHDA- 2022/11/18 06:00
CRDT- 2022/11/14 21:05
PHST- 2021/09/06 00:00 [received]
PHST- 2021/11/22 00:00 [revised]
PHST- 2021/11/25 00:00 [accepted]
PHST- 2022/11/14 21:05 [entrez]
PHST- 2022/11/15 06:00 [pubmed]
PHST- 2022/11/18 06:00 [medline]
AID - S1001-0742(21)00504-0 [pii]
AID - 10.1016/j.jes.2021.11.028 [doi]
PST - ppublish
SO  - J Environ Sci (China). 2023 Mar;125:171-184. doi: 10.1016/j.jes.2021.11.028. Epub 
      2021 Dec 14.