PMID- 36394606 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20221205 IS - 1944-8252 (Electronic) IS - 1944-8244 (Print) IS - 1944-8244 (Linking) VI - 14 IP - 47 DP - 2022 Nov 30 TI - Flexible Superhydrophobic Microlens Arrays for Humid Outdoor Environment Applications. PG - 53433-53441 LID - 10.1021/acsami.2c17128 [doi] AB - A microlens array (MLA) is an essential optical imaging device in the applications of augmented and virtual realities. The imaging of MLA would become blurry in a humid outdoor atmosphere. While the incorporation of superhydrophobicity to MLA would prevent the adhesion of droplets, the complex structure and the multiple fabrication process reduce the capability of optical imaging of MLA. Herein, a flexible superhydrophobic MLA with good optical imaging capability is successfully fabricated by the combination of 3D direct laser writing (DLW) and soft lithography. 3D DLW allows the fabrication of MLA with a hierarchical pillar array (h-MLA) in one step, which ensures good optical properties of the resulting polydimethylsiloxane (PDMS) h-MLA. The resulting h-MLAs with pitches ranging between 50 and 100 mum are superhydrophobic from which water droplets slide away at a sliding angle smaller than 15.6 degrees and bounce off from the surface. Meanwhile, the hierarchical pillar array has a limited impact on the imaging capability and the field of view of h-MLA. With an optimized pitch of 60 mum, h-MLA has a transparency as good as MLA. Moreover, PDMS h-MLA retains excellent optical and superhydrophobic properties when bent and in an extremely humid environment. We believe that the proposed h-MLA could find applications in outdoor environments. FAU - Luan, Shiyi AU - Luan S AUID- ORCID: 0000-0001-6334-6058 AD - School of Power and Mechanical Engineering, Wuhan University, Wuhan430072, China. FAU - Xu, Peng AU - Xu P AD - School of Power and Mechanical Engineering, Wuhan University, Wuhan430072, China. FAU - Zhang, Yurong AU - Zhang Y AD - The Institute of Technological Sciences, Wuhan University, Wuhan430072, China. FAU - Xue, Longjian AU - Xue L AUID- ORCID: 0000-0001-5512-747X AD - School of Power and Mechanical Engineering, Wuhan University, Wuhan430072, China. AD - The Institute of Technological Sciences, Wuhan University, Wuhan430072, China. FAU - Song, Yi AU - Song Y AUID- ORCID: 0000-0001-9632-404X AD - The Institute of Technological Sciences, Wuhan University, Wuhan430072, China. AD - School of Microelectronic, Wuhan University, Wuhan430072, China. FAU - Gui, Chengqun AU - Gui C AD - The Institute of Technological Sciences, Wuhan University, Wuhan430072, China. LA - eng PT - Journal Article DEP - 20221117 PL - United States TA - ACS Appl Mater Interfaces JT - ACS applied materials & interfaces JID - 101504991 SB - IM PMC - PMC9716522 OTO - NOTNLM OT - direct laser writing lithography OT - high filling factor OT - low roughness OT - microlens array OT - superhydrophobic COIS- The authors declare no competing financial interest. EDAT- 2022/11/18 06:00 MHDA- 2022/11/18 06:01 PMCR- 2022/12/02 CRDT- 2022/11/17 13:53 PHST- 2022/11/18 06:00 [pubmed] PHST- 2022/11/18 06:01 [medline] PHST- 2022/11/17 13:53 [entrez] PHST- 2022/12/02 00:00 [pmc-release] AID - 10.1021/acsami.2c17128 [doi] PST - ppublish SO - ACS Appl Mater Interfaces. 2022 Nov 30;14(47):53433-53441. doi: 10.1021/acsami.2c17128. Epub 2022 Nov 17.