PMID- 36422664
OWN - NLM
STAT- MEDLINE
DCOM- 20230710
LR  - 20230802
IS  - 1618-2650 (Electronic)
IS  - 1618-2642 (Linking)
VI  - 415
IP  - 18
DP  - 2023 Jul
TI  - PEG-modified halloysite as a hydrophilic interaction and cation exchange 
      mixed-mode sorbent for solid-phase extraction of biogenic amines in fish samples.
PG  - 4265-4275
LID - 10.1007/s00216-022-04441-5 [doi]
AB  - A novel type of PEG-modified halloysite was prepared and used as a hydrophilic 
      interaction and cation exchange mixed-mode sorbent for solid-phase extraction of 
      biogenic amines in fish samples. The eluates were analyzed by high-performance 
      liquid chromatography-ultraviolet detection after the derivatization with benzoyl 
      chloride. The developed sorbent was characterized by scanning electron 
      microscopy, infrared spectroscopy, X-ray diffraction, zeta potential analyzer, 
      and thermo-gravimetric analysis. After the optimization of various parameters 
      influencing the extraction efficiency, the PEG-modified halloysite-based SPE 
      method was evaluated. The adsorption capacities of putrescine, spermine, 
      phenethylamine, and histamine were as high as 9.3, 8.5, 5.7, and 5.6 mg g(-1), 
      respectively. Satisfactory reproducibility of sorbent preparation was obtained 
      with within-batch and batch-to-batch relative standard deviations (RSDs) lower 
      than 3.9% and 8.6%, respectively. The biogenic amine spiking recoveries in fish 
      samples ranged from 84.3 to 105.5% with good RSDs lower than 7.8%. Intra-day and 
      inter-day precision, expressed as RSDs, were better than 8.8%. The limits of 
      detection of histamine, putrescine, phenethylamine, and spermine were 9.4, 1.9, 
      0.5, and 0.9 mug L(-1), respectively. This work provides a new hydrophilic 
      interaction and cation exchange mixed-mode sorbent and is successfully applied to 
      the extraction of trace biogenic amines from fish samples.
CI  - (c) 2022. Springer-Verlag GmbH Germany, part of Springer Nature.
FAU - Wang, Tingting
AU  - Wang T
AD  - School of Materials and Chemical Engineering, Ningbo University of Technology, 
      Ningbo, 315211, People's Republic of China. shiming-49@163.com.
AD  - Zhejiang Institute of Tianjin University, Ningbo, 315201, People's Republic of 
      China. shiming-49@163.com.
FAU - Chen, Yihui
AU  - Chen Y
AD  - Ningbo Academy of Inspection and Quarantine, Ningbo, 315012, People's Republic of 
      China.
FAU - Hou, Chunyan
AU  - Hou C
AD  - Department of Oncology, Lombardi Comprehensive Cancer Center, Georgetown 
      University Medical Center, Washington, DC, 20057, USA.
FAU - Qiao, Xiaoqiang
AU  - Qiao X
AD  - College of Pharmaceutical Sciences, Key Laboratory of Medicinal Chemistry and 
      Molecular Diagnosis, Ministry of Education, Hebei University, Baoding, 071002, 
      People's Republic of China.
LA  - eng
GR  - 202003N4168/Ningbo Natural Science Foundation of China/
GR  - LGC19B050004/Zhejiang Province Public Welfare Technology Application Research 
      Project/
PT  - Journal Article
DEP - 20221124
PL  - Germany
TA  - Anal Bioanal Chem
JT  - Analytical and bioanalytical chemistry
JID - 101134327
RN  - T1FAD4SS2M (Clay)
RN  - 820484N8I3 (Histamine)
RN  - V10TVZ52E4 (Putrescine)
RN  - 2FZ7Y3VOQX (Spermine)
RN  - 0 (Biogenic Amines)
SB  - IM
MH  - Animals
MH  - Clay
MH  - *Histamine/analysis
MH  - Reproducibility of Results
MH  - *Putrescine
MH  - Spermine
MH  - Solid Phase Extraction/methods
MH  - Chromatography, High Pressure Liquid/methods
MH  - Biogenic Amines/analysis
MH  - Hydrophobic and Hydrophilic Interactions
OTO - NOTNLM
OT  - Benzoyl chloride
OT  - Biogenic amines
OT  - Halloysite
OT  - Liquid chromatography
OT  - Solid-phase extraction
EDAT- 2022/11/25 06:00
MHDA- 2023/07/10 06:42
CRDT- 2022/11/24 11:23
PHST- 2022/07/24 00:00 [received]
PHST- 2022/11/16 00:00 [accepted]
PHST- 2022/11/10 00:00 [revised]
PHST- 2023/07/10 06:42 [medline]
PHST- 2022/11/25 06:00 [pubmed]
PHST- 2022/11/24 11:23 [entrez]
AID - 10.1007/s00216-022-04441-5 [pii]
AID - 10.1007/s00216-022-04441-5 [doi]
PST - ppublish
SO  - Anal Bioanal Chem. 2023 Jul;415(18):4265-4275. doi: 10.1007/s00216-022-04441-5. 
      Epub 2022 Nov 24.