PMID- 36426100 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20221126 IS - 2296-2646 (Print) IS - 2296-2646 (Electronic) IS - 2296-2646 (Linking) VI - 10 DP - 2022 TI - Aging phenomena in non-crosslinked polyolefin blend cable insulation material: Electrical treeing and thermal aging. PG - 903986 LID - 10.3389/fchem.2022.903986 [doi] LID - 903986 AB - Non-crosslinked polyolefin blends have become a favorable alternative material to crosslinked polyethylene (XLPE) cable insulation owing to their low power consumption in the production process and good recyclability at the end of service life. Although studies on non-crosslinked materials have achieved significant results, the electrical and thermal aging properties of these materials undeniably need extensive research attention and systematic exploration. Aging performance is directly related to the lifetime and reliability of cables. In this study, the electrical treeing and thermal aging phenomena of 70 wt.% linear low-density polyethylene (LLDPE) and 30 wt.% high-density polyethylene (HDPE) blends (abbreviated as 70L-30H) were studied and compared with those of XLPE by investigating the microstructural feature, electrical treeing behavior, and mechanical performance during thermal aging. Electrical treeing tests show that 70L-30H blends exhibited smaller treeing dimensions and lower electrical tree growth rates than those of XLPE. Thermal aging tests exhibit that the mechanical property degradation of 70L-30H blends is less than that of XLPE under the same aging time. Through differential scanning calorimetry analysis and microstructure observation, the 70L-30H blend shows higher melting temperature, thicker lamellae, and higher crystallinity with a uniform and fine spherulite structure, which are responsible for good anti-aging performance. This study indicates that the blends exhibit better electrical and thermal aging resistance than XLPE, which provides a performance guarantee for its further application in the non-crosslinked cable system. CI - Copyright (c) 2022 Lunzhi, Jinghui, Lisheng, Kai and Xiaohan. FAU - Lunzhi, Li AU - Lunzhi L AD - School of Electronic and Control Engineering, Chang'an University, Xi'an, China. AD - State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an, China. FAU - Jinghui, Gao AU - Jinghui G AD - State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an, China. FAU - Lisheng, Zhong AU - Lisheng Z AD - State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an, China. FAU - Kai, Zhang AU - Kai Z AD - State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an, China. FAU - Xiaohan, Zhao AU - Xiaohan Z AD - School of Electronic and Control Engineering, Chang'an University, Xi'an, China. LA - eng PT - Journal Article DEP - 20221108 PL - Switzerland TA - Front Chem JT - Frontiers in chemistry JID - 101627988 PMC - PMC9679882 OTO - NOTNLM OT - cable insulation OT - electrical treeing OT - non-crosslinked OT - polyolefin blend OT - thermal aging COIS- The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest. EDAT- 2022/11/26 06:00 MHDA- 2022/11/26 06:01 PMCR- 2022/01/01 CRDT- 2022/11/25 02:58 PHST- 2022/03/25 00:00 [received] PHST- 2022/10/21 00:00 [accepted] PHST- 2022/11/25 02:58 [entrez] PHST- 2022/11/26 06:00 [pubmed] PHST- 2022/11/26 06:01 [medline] PHST- 2022/01/01 00:00 [pmc-release] AID - 903986 [pii] AID - 10.3389/fchem.2022.903986 [doi] PST - epublish SO - Front Chem. 2022 Nov 8;10:903986. doi: 10.3389/fchem.2022.903986. eCollection 2022.