PMID- 36437082 OWN - NLM STAT- MEDLINE DCOM- 20221129 LR - 20221129 IS - 0250-3301 (Print) IS - 0250-3301 (Linking) VI - 43 IP - 11 DP - 2022 Nov 8 TI - [Adsorption of Phosphate and Heavy Metals by Lanthanum Modified Zeolite and Its Performance in Sediment Inactivation]. PG - 5106-5114 LID - 10.13227/j.hjkx.202202022 [doi] AB - Due to the large scale of mining and smelting activities, considerable amounts of heavy metals are discharged into the environment and accumulate in the sediment of rivers and lakes. The combined pollution of heavy metals and the intrinsic phosphorus in sediment calls for novel remediation technologies. In this study, lanthanum-modified zeolite (LMZ) was employed as an inactivation agent for the immobilization of phosphorus, zinc, and lead in sediments. The adsorption capacities as well as the inactivation performance of LMZ for P, Zn, and Pb were investigated, and the adsorption mechanisms were explored via desorption experiments, X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD). The results indicated that the adsorption maximums of LMZ for P, Zn, and Pb were 53.76, 27.70, and 123.45 mg.g(-1), respectively. Pre-adsorption of Zn and Pb had a negligible effect on the P adsorption by LMZ, whereas the adsorption of Zn and Pb were inhibited significantly by the pre-adsorption. P, Zn, and Pb in the sediment were transformed to more stable or less bioavailable forms by dosing 0.83% and 1.66% weight percentages of LMZ. It was found that P, Zn, and Pb were adsorbed through the formation of inner-sphere complexes. Further, desorption experiments and XRD patterns suggested that electrostatic attraction and surface precipitation also contributed to the adsorption of Zn and Pb, respectively. FAU - Wang, Zhe AU - Wang Z AD - State Key Laboratory of Eco-hydraulics in Northwest Arid Region of China, Xi'an University of Technology, Xi'an 710048, China. FAU - Zhu, Jun AU - Zhu J AD - State Key Laboratory of Eco-hydraulics in Northwest Arid Region of China, Xi'an University of Technology, Xi'an 710048, China. AD - School of Environmental & Chemical Engineering, Shanghai University, Shanghai 200444, China. FAU - Li, Wen AU - Li W AD - State Key Laboratory of Eco-hydraulics in Northwest Arid Region of China, Xi'an University of Technology, Xi'an 710048, China. FAU - Yan, De-Xin AU - Yan DX AD - State Key Laboratory of Eco-hydraulics in Northwest Arid Region of China, Xi'an University of Technology, Xi'an 710048, China. FAU - Dong, Wen AU - Dong W AD - State Key Laboratory of Eco-hydraulics in Northwest Arid Region of China, Xi'an University of Technology, Xi'an 710048, China. FAU - Liu, Yu-Ling AU - Liu YL AD - State Key Laboratory of Eco-hydraulics in Northwest Arid Region of China, Xi'an University of Technology, Xi'an 710048, China. FAU - Li, Jia-Ke AU - Li JK AD - State Key Laboratory of Eco-hydraulics in Northwest Arid Region of China, Xi'an University of Technology, Xi'an 710048, China. LA - chi PT - English Abstract PT - Journal Article PL - China TA - Huan Jing Ke Xue JT - Huan jing ke xue= Huanjing kexue JID - 8405344 RN - 1318-02-1 (Zeolites) RN - 6I3K30563S (Lanthanum) RN - 0 (Phosphates) RN - 2P299V784P (Lead) RN - 0 (Metals, Heavy) RN - 27YLU75U4W (Phosphorus) SB - IM MH - *Zeolites/chemistry MH - Lanthanum MH - Phosphates/chemistry MH - Adsorption MH - Lead MH - *Metals, Heavy/chemistry MH - Phosphorus OTO - NOTNLM OT - heavy metals OT - inactivation OT - lanthanum-modified zeolite OT - phosphorus OT - sediment EDAT- 2022/11/28 06:00 MHDA- 2022/11/30 06:00 CRDT- 2022/11/27 21:23 PHST- 2022/11/27 21:23 [entrez] PHST- 2022/11/28 06:00 [pubmed] PHST- 2022/11/30 06:00 [medline] AID - 10.13227/j.hjkx.202202022 [doi] PST - ppublish SO - Huan Jing Ke Xue. 2022 Nov 8;43(11):5106-5114. doi: 10.13227/j.hjkx.202202022.