PMID- 36441272 OWN - NLM STAT- MEDLINE DCOM- 20221130 LR - 20221208 IS - 1436-5073 (Electronic) IS - 0026-3672 (Linking) VI - 189 IP - 12 DP - 2022 Nov 28 TI - Highly sensitive gold nanoparticles-modified silver nanorod arrays for determination of methyl viologen. PG - 479 LID - 10.1007/s00604-022-05590-1 [doi] AB - Gold nanoparticles-modified silver nanorod (AuNPs@AgNR) arrays were fabricated as surface-enhanced Raman spectroscopy (SERS) substrates. The coffee ring effect of the AuNPs@AgNR was explored as a preconcentration method for enriching the target analytes and increasing the "hot spots." Furthermore, methyl viologen (MV) as a toxic herbicide used in agricultural production was successfully determined to investigate the application of the coffee ring effect on AuNPs@AgNR arrays and density functional theory (DFT) was employed to calculate its vibrational modes of corresponding characteristic peaks. Good linearity was obtained in the range 0.10-100 mg/L, and the limit of detection (LOD) of MV was estimated to be 0.01 mg/L, which was lower than the US maximum residue limits (MRLs). This method was also applied to practical detection of MV in river water and apple peel with LODs of 0.10 mg/L and 0.05 mg/L, respectively. SERS results suggest that the coffee ring on AuNPs@AgNR arrays provides a promising way for monitoring environmental pollution and food safety caused by pesticides. CI - (c) 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Austria, part of Springer Nature. FAU - Luo, Ying AU - Luo Y AD - Jiangsu Key Laboratory of Advanced Laser Materials and Devices, School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou, 221116, Jiangsu, China. FAU - Zhang, Qian AU - Zhang Q AD - Jiangsu Key Laboratory of Advanced Laser Materials and Devices, School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou, 221116, Jiangsu, China. AD - Jiangsu Collaborative Innovation Center of Advanced Laser Technology and Emerging Industry, Jiangsu Normal University, Xuzhou, 221116, Jiangsu, China. FAU - Wang, Qin AU - Wang Q AD - Jiangsu Key Laboratory of Advanced Laser Materials and Devices, School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou, 221116, Jiangsu, China. AD - Jiangsu Collaborative Innovation Center of Advanced Laser Technology and Emerging Industry, Jiangsu Normal University, Xuzhou, 221116, Jiangsu, China. FAU - Liu, Zhenglin AU - Liu Z AD - Jiangsu Key Laboratory of Advanced Laser Materials and Devices, School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou, 221116, Jiangsu, China. AD - Jiangsu Collaborative Innovation Center of Advanced Laser Technology and Emerging Industry, Jiangsu Normal University, Xuzhou, 221116, Jiangsu, China. FAU - Duan, Lingfeng AU - Duan L AD - Institute of Electronics and Telecommunications, Peter the Great St. Petersburg Polytechnic University, St. Petersburg, 195251, Leningrad, Russia. FAU - Cao, Wenxi AU - Cao W AD - Jiangsu Key Laboratory of Advanced Laser Materials and Devices, School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou, 221116, Jiangsu, China. AD - Jiangsu Collaborative Innovation Center of Advanced Laser Technology and Emerging Industry, Jiangsu Normal University, Xuzhou, 221116, Jiangsu, China. FAU - Cao, Zijin AU - Cao Z AD - Jiangsu Key Laboratory of Advanced Laser Materials and Devices, School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou, 221116, Jiangsu, China. AD - Jiangsu Collaborative Innovation Center of Advanced Laser Technology and Emerging Industry, Jiangsu Normal University, Xuzhou, 221116, Jiangsu, China. FAU - Han, Caiqin AU - Han C AUID- ORCID: 0000-0002-0570-1426 AD - Jiangsu Key Laboratory of Advanced Laser Materials and Devices, School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou, 221116, Jiangsu, China. hancq@jsnu.edu.cn. AD - Jiangsu Collaborative Innovation Center of Advanced Laser Technology and Emerging Industry, Jiangsu Normal University, Xuzhou, 221116, Jiangsu, China. hancq@jsnu.edu.cn. LA - eng GR - KC20171/the Natural Science Foundation of Xuzhou City/ GR - 2021XKT1221/Graduate Research and Innovation Projects of Jiangsu Province/ PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20221128 PL - Austria TA - Mikrochim Acta JT - Mikrochimica acta JID - 7808782 RN - 7440-57-5 (Gold) RN - 3M4G523W1G (Silver) RN - PLG39H7695 (Paraquat) SB - IM MH - Gold MH - Silver MH - Paraquat MH - *Metal Nanoparticles MH - *Nanotubes OTO - NOTNLM OT - AuNPs@AgNR OT - Coffee ring effect OT - Methyl viologen OT - Surface-enhanced Raman spectroscopy EDAT- 2022/11/29 06:00 MHDA- 2022/12/01 06:00 CRDT- 2022/11/28 11:17 PHST- 2022/03/21 00:00 [received] PHST- 2022/11/23 00:00 [accepted] PHST- 2022/11/28 11:17 [entrez] PHST- 2022/11/29 06:00 [pubmed] PHST- 2022/12/01 06:00 [medline] AID - 10.1007/s00604-022-05590-1 [pii] AID - 10.1007/s00604-022-05590-1 [doi] PST - epublish SO - Mikrochim Acta. 2022 Nov 28;189(12):479. doi: 10.1007/s00604-022-05590-1.