PMID- 36450681
OWN - NLM
STAT- MEDLINE
DCOM- 20221202
LR  - 20221202
IS  - 0273-1223 (Print)
IS  - 0273-1223 (Linking)
VI  - 86
IP  - 10
DP  - 2022 Nov
TI  - A novel carbonized derivative of Fe-Cu bimetallic organic framework 
      (Fe-Cu-MOF@C): preparation and optimization.
PG  - 2701-2717
LID - 10.2166/wst.2022.363 [doi]
AB  - A carbon derivative with Fe-Cu bimetallic organic framework (Fe-Cu-MOF@C) was 
      prepared by microwave synthesis and pyrolysis. Using potassium persulfate (PS) as 
      oxidant and 2,4-dichlorophenol (2,4-DCP) as target pollutant, the optimal 
      preparation conditions of Fe-Cu-MOF@C were studied. The factors affecting the 
      synthesis of Fe-Cu-MOF include microwave power, microwave time, microwave 
      temperature, the molar ratio of metal ions to organic ligands, the molar ratio of 
      iron and copper, etc. In addition, the influence of pyrolysis temperature on the 
      performance of Fe-Cu-MOF@C cannot be ignored. The results show that Fe-Cu-MOF@C 
      has the best catalytic performance when the microwave time is 30 min, the 
      microwave power is 600 W, the microwave temperature is 150  degrees C, the molar ratio of 
      (Fe(2+) + Cu(2+))/H(2)BDC is 10:3, the molar ratio of Fe(2+)/Cu(2+) is 10:1, and 
      the pyrolysis temperature is 700  degrees C. After 90 min of reaction, 2,4-DCP was 
      completely removed. Repeatable experiments show that Fe-Cu-MOF@C has good 
      stability and its service life can be restored by heat treatment. In this study, 
      a heterogeneous catalyst with strong catalytic capacity, high stability and easy 
      recovery was prepared by a simple and efficient process, which is conducive to 
      the development of advanced oxidation technology and the progress of water 
      environmental protection.
FAU - Guo, Shengxuan
AU  - Guo S
AD  - Wuhan University of Science and Technology, Wuhan, China E-mail: dj_ren@163.com.
FAU - Ren, Dajun
AU  - Ren D
AD  - Wuhan University of Science and Technology, Wuhan, China E-mail: dj_ren@163.com.
FAU - Huang, Yongwei
AU  - Huang Y
AD  - Wuhan University of Science and Technology, Wuhan, China E-mail: dj_ren@163.com.
FAU - Wang, Zhaobo
AU  - Wang Z
AD  - Wuhan University of Science and Technology, Wuhan, China E-mail: dj_ren@163.com.
FAU - Zhang, Shuqin
AU  - Zhang S
AD  - Wuhan University of Science and Technology, Wuhan, China E-mail: dj_ren@163.com.
FAU - Zhang, Xiaoqing
AU  - Zhang X
AD  - Wuhan University of Science and Technology, Wuhan, China E-mail: dj_ren@163.com.
FAU - Gong, Xiangyi
AU  - Gong X
AD  - Wuhan University of Science and Technology, Wuhan, China E-mail: dj_ren@163.com.
LA  - eng
PT  - Journal Article
PL  - England
TA  - Water Sci Technol
JT  - Water science and technology : a journal of the International Association on 
      Water Pollution Research
JID - 9879497
RN  - 7440-44-0 (Carbon)
RN  - 789U1901C5 (Copper)
SB  - IM
MH  - *Pyrolysis
MH  - *Microwaves
MH  - Catalysis
MH  - Carbon
MH  - Copper
EDAT- 2022/12/01 06:00
MHDA- 2022/12/03 06:00
CRDT- 2022/11/30 22:32
PHST- 2022/11/30 22:32 [entrez]
PHST- 2022/12/01 06:00 [pubmed]
PHST- 2022/12/03 06:00 [medline]
AID - 10.2166/wst.2022.363 [doi]
PST - ppublish
SO  - Water Sci Technol. 2022 Nov;86(10):2701-2717. doi: 10.2166/wst.2022.363.