PMID- 36464018
OWN - NLM
STAT- MEDLINE
DCOM- 20230111
LR  - 20230111
IS  - 1879-1298 (Electronic)
IS  - 0045-6535 (Linking)
VI  - 313
DP  - 2023 Feb
TI  - Mechanochemical remediation of the chlorinated compounds contaminated soil 
      depending on the minerals inside-the most reasonable approach.
PG  - 137449
LID - S0045-6535(22)03942-X [pii]
LID - 10.1016/j.chemosphere.2022.137449 [doi]
AB  - This study explored a possible destruction of hexachlorobenzene (HCB) as example 
      of persistent organic pollutants (POPs) as well as the dechlorination mechanism 
      by directly using minerals in the soil, such as antigorite, talc and olivine. 
      Compared with a stable quartz phase of SiO(2), all three Mg silicate minerals 
      demonstrated certain degrading capacity for HCB with different efficiency order 
      as: antigorite > talc > olivine > SiO(2) at 2 h of milling time. Interestingly, 
      olivine exhibited a better performance than antigorite at 4 h of milling time, 
      giving destruction percentage of 92.7% over 89.0% even at high concentrated HCB 
      up to 5% added. Raman and ESR characterizations of the ball milled sample with 
      olivine indicated the formation of amorphous carbon and graphitic carbon, and the 
      occurrence of free radicals was observed to play an important role in 
      dechlorination and carbonization of HCB. The first identified effectiveness of 
      directly using Mg silicate minerals, allowed no addition of active chemicals 
      during the ball milling, therefore avoided the concern over extrinsic 
      contaminations on the soil. Olivine was further utilized to deal with actual 
      contaminated soil and showed unique advantages on application prospects.
CI  - Copyright (c) 2022 Elsevier Ltd. All rights reserved.
FAU - Yao, Zhenzhen
AU  - Yao Z
AD  - School of Resources and Environmental Engineering, Wuhan University of 
      Technology, Wuhan, 430070, China.
FAU - He, Xiaoman
AU  - He X
AD  - School of Resources and Environmental Engineering, Wuhan University of 
      Technology, Wuhan, 430070, China. Electronic address: hexiaoman@whut.edu.cn.
FAU - Wang, Qian
AU  - Wang Q
AD  - School of Resources and Environmental Engineering, Wuhan University of 
      Technology, Wuhan, 430070, China.
FAU - Wang, Chao
AU  - Wang C
AD  - School of Resources and Environmental Engineering, Wuhan University of 
      Technology, Wuhan, 430070, China.
FAU - Shi, Qing
AU  - Shi Q
AD  - School of Resources and Environmental Engineering, Wuhan University of 
      Technology, Wuhan, 430070, China.
FAU - Zhang, Qiwu
AU  - Zhang Q
AD  - School of Resources and Environmental Engineering, Wuhan University of 
      Technology, Wuhan, 430070, China. Electronic address: zhangqw@whut.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20221201
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 95548S7QBV (olivine)
RN  - 0 (Soil Pollutants)
RN  - 4Z87H0LKUY (Hexachlorobenzene)
RN  - 0 (Soil)
RN  - 0 (Asbestos, Serpentine)
RN  - 7631-86-9 (Silicon Dioxide)
RN  - 14807-96-6 (Talc)
RN  - 0 (Minerals)
RN  - 7440-44-0 (Carbon)
SB  - IM
MH  - *Environmental Restoration and Remediation
MH  - *Soil Pollutants/analysis
MH  - Hexachlorobenzene/chemistry
MH  - Soil/chemistry
MH  - Asbestos, Serpentine
MH  - Silicon Dioxide
MH  - Talc
MH  - Minerals
MH  - Carbon
OTO - NOTNLM
OT  - Contaminated soil
OT  - Destruction
OT  - Mechanochemistry
OT  - Minerals
OT  - POPs
COIS- Declaration of competing interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2022/12/05 06:00
MHDA- 2023/01/12 06:00
CRDT- 2022/12/04 19:24
PHST- 2022/08/27 00:00 [received]
PHST- 2022/11/25 00:00 [revised]
PHST- 2022/11/30 00:00 [accepted]
PHST- 2022/12/05 06:00 [pubmed]
PHST- 2023/01/12 06:00 [medline]
PHST- 2022/12/04 19:24 [entrez]
AID - S0045-6535(22)03942-X [pii]
AID - 10.1016/j.chemosphere.2022.137449 [doi]
PST - ppublish
SO  - Chemosphere. 2023 Feb;313:137449. doi: 10.1016/j.chemosphere.2022.137449. Epub 
      2022 Dec 1.