PMID- 36465260
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20221206
IS  - 2574-0962 (Electronic)
VI  - 5
IP  - 11
DP  - 2022 Nov 28
TI  - Driving up the Electrocatalytic Performance for Carbon Dioxide Conversion through 
      Interface Tuning in Graphene Oxide-Bismuth Oxide Nanocomposites.
PG  - 13356-13366
LID - 10.1021/acsaem.2c02013 [doi]
AB  - The integration of graphene oxide (GO) into nanostructured Bi(2)O(3) 
      electrocatalysts for CO(2) reduction (CO(2)RR) brings up remarkable improvements 
      in terms of performance toward formic acid (HCOOH) production. The GO scaffold is 
      able to facilitate electron transfers toward the active Bi(2)O(3) phase, amending 
      for the high metal oxide (MO) intrinsic electric resistance, resulting in 
      activation of the CO(2) with smaller overpotential. Herein, the structure of the 
      GO-MO nanocomposite is tailored according to two synthetic protocols, giving rise 
      to two different nanostructures, one featuring reduced GO (rGO) supporting 
      Bi@Bi(2)O(3) core-shell nanoparticles (NP) and the other GO supporting fully 
      oxidized Bi(2)O(3) NP. The two structures differentiate in terms of 
      electrocatalytic behavior, suggesting the importance of constructing a suitable 
      interface between the nanocarbon and the MO, as well as between MO and metal.
CI  - (c) 2022 The Authors. Published by American Chemical Society.
FAU - Melchionna, Michele
AU  - Melchionna M
AUID- ORCID: 0000-0001-9813-9753
AD  - Department of Chemical and Pharmaceutical Sciences, University of Trieste and 
      Consortium INSTM, Via L. Giorgieri 1, 34127Trieste, Italy.
FAU - Moro, Miriam
AU  - Moro M
AD  - Department of Chemistry "Giacomo Ciamician", University of Bologna and Consortium 
      INSTM, via Selmi 2, 40126Bologna, Italy.
FAU - Adorinni, Simone
AU  - Adorinni S
AD  - Department of Chemical and Pharmaceutical Sciences, University of Trieste and 
      Consortium INSTM, Via L. Giorgieri 1, 34127Trieste, Italy.
FAU - Nasi, Lucia
AU  - Nasi L
AD  - CNR-IMEM Institute, Parco area delle Scienze 37/A, 43124Parma, Italy.
FAU - Colussi, Sara
AU  - Colussi S
AUID- ORCID: 0000-0001-5316-1746
AD  - Department Politecnico, University of Udine, Unita di Ricerca INSTM Udine, Via 
      del Cotonificio 108, 33100Udine, Italy.
FAU - Poggini, Lorenzo
AU  - Poggini L
AD  - Institute of Chemistry of Organometallic Compounds, National Research Council of 
      Italy (ICCOM-CNR), Via Madonna del Piano 10, 50019Sesto Fiorentino, Florence, 
      Italy.
FAU - Marchesan, Silvia
AU  - Marchesan S
AD  - Department of Chemical and Pharmaceutical Sciences, University of Trieste and 
      Consortium INSTM, Via L. Giorgieri 1, 34127Trieste, Italy.
FAU - Valenti, Giovanni
AU  - Valenti G
AUID- ORCID: 0000-0002-6223-2072
AD  - Department of Chemistry "Giacomo Ciamician", University of Bologna and Consortium 
      INSTM, via Selmi 2, 40126Bologna, Italy.
FAU - Paolucci, Francesco
AU  - Paolucci F
AUID- ORCID: 0000-0003-4614-8740
AD  - Department of Chemistry "Giacomo Ciamician", University of Bologna and Consortium 
      INSTM, via Selmi 2, 40126Bologna, Italy.
FAU - Prato, Maurizio
AU  - Prato M
AUID- ORCID: 0000-0002-8869-8612
AD  - Department of Chemical and Pharmaceutical Sciences, University of Trieste and 
      Consortium INSTM, Via L. Giorgieri 1, 34127Trieste, Italy.
AD  - Carbon Nanobiotechnology Laboratory, CIC biomaGUNE, Paseo de Miramon 182, 
      20009Donostia-San Sebastian, Spain.
AD  - Ikerbasque, Basque Foundation for Science, 48013Bilbao, Spain.
FAU - Fornasiero, Paolo
AU  - Fornasiero P
AUID- ORCID: 0000-0003-1082-9157
AD  - Department of Chemical and Pharmaceutical Sciences, University of Trieste and 
      Consortium INSTM, Via L. Giorgieri 1, 34127Trieste, Italy.
AD  - ICCOM-CNR, University of Trieste, Via L. Giorgieri 1, 34127Trieste, Italy.
LA  - eng
PT  - Journal Article
DEP - 20221020
PL  - United States
TA  - ACS Appl Energy Mater
JT  - ACS applied energy materials
JID - 101718976
PMC - PMC9710520
COIS- The authors declare no competing financial interest.
EDAT- 2022/12/06 06:00
MHDA- 2022/12/06 06:01
PMCR- 2022/11/30
CRDT- 2022/12/05 03:37
PHST- 2022/06/28 00:00 [received]
PHST- 2022/10/11 00:00 [accepted]
PHST- 2022/12/05 03:37 [entrez]
PHST- 2022/12/06 06:00 [pubmed]
PHST- 2022/12/06 06:01 [medline]
PHST- 2022/11/30 00:00 [pmc-release]
AID - 10.1021/acsaem.2c02013 [doi]
PST - ppublish
SO  - ACS Appl Energy Mater. 2022 Nov 28;5(11):13356-13366. doi: 
      10.1021/acsaem.2c02013. Epub 2022 Oct 20.