PMID- 36493831 OWN - NLM STAT- MEDLINE DCOM- 20230119 LR - 20230119 IS - 1879-1026 (Electronic) IS - 0048-9697 (Linking) VI - 862 DP - 2023 Mar 1 TI - Cropland carbon stocks driven by soil characteristics, rainfall and elevation. PG - 160602 LID - S0048-9697(22)07705-1 [pii] LID - 10.1016/j.scitotenv.2022.160602 [doi] AB - Soil organic carbon (SOC) can influence atmospheric CO(2) concentration and then the extent to which the climate emergency is mitigated globally. It follows the elucidation of the driving factors of cropland SOC stocks, which is fundamental to reducing soil carbon loss and promoting soil carbon sequestration. Here, we examined the influence of 16 environmental variables on SOC stocks and sequestration based on three machine learning soil mapping methods, i.e. multiple linear regression (MLR), random forest (RF) and extreme gradient boosting (XGBOOST), with 2875 observed soil samples from cropland topsoil across Hunan Province, China in 2010. We employed a structural equation model (SEM) to extricate the driving mechanisms of environmental variables on SOC stocks at the regional scale. Our results show that XGBOOST had the most reliable performance in predicting SOC stocks, explaining 66 % of the total SOC stock variation. Croplands with high SOC stocks were distributed in low-altitude and water-sufficient areas. The partial dependence of SOC on precipitation showed a trend of increasing and then slowly decreasing. In addition, the grid-based SEM results clearly presented the direct and indirect routes of environmental variables' impacts on cropland SOC stocks. Soil properties regulated by elevation, were the most influential natural factor on SOC stocks. Precipitation and elevation drove SOC stocks through direct and indirect effects respectively. Our SEM combined with machine learning approach can provide an effective explanation of the driving mechanism for SOC accumulation. We expect our proposed modelling approach can be applied to other regions and offer new insights, as a reference for mitigating cropland soil carbon loss under climate emergency conditions. CI - Copyright (c) 2022 Elsevier B.V. All rights reserved. FAU - Chen, Fangzheng AU - Chen F AD - College of Land Science and Technology, China Agricultural University, Key Laboratory of Arable Land Conservation (North China), Ministry of Agriculture, Beijing, PR China. FAU - Feng, Puyu AU - Feng P AD - College of Land Science and Technology, China Agricultural University, Key Laboratory of Arable Land Conservation (North China), Ministry of Agriculture, Beijing, PR China. Electronic address: fengpuyu@cau.edu.cn. FAU - Harrison, Matthew Tom AU - Harrison MT AD - Tasmanian Institute of Agriculture, University of Tasmania, Newnham, Launceston, Tasmania 7248, Australia. FAU - Wang, Bin AU - Wang B AD - New South Wales Department of Primary Industries, Wagga Wagga Agriculture Institute, Wagga Wagga, New South Wales 2650, Australia. FAU - Liu, Ke AU - Liu K AD - Tasmanian Institute of Agriculture, University of Tasmania, Newnham, Launceston, Tasmania 7248, Australia; Engineering Research Center of Ecology and Agricultural Use of Wetland, College of Agriculture, Yangtze University, Jingzhou 434025, Hubei, China. FAU - Zhang, Chenxia AU - Zhang C AD - College of Land Science and Technology, China Agricultural University, Key Laboratory of Arable Land Conservation (North China), Ministry of Agriculture, Beijing, PR China. FAU - Hu, Kelin AU - Hu K AD - College of Land Science and Technology, China Agricultural University, Key Laboratory of Arable Land Conservation (North China), Ministry of Agriculture, Beijing, PR China. LA - eng PT - Journal Article DEP - 20221207 PL - Netherlands TA - Sci Total Environ JT - The Science of the total environment JID - 0330500 RN - 0 (Soil) RN - 7440-44-0 (Carbon) SB - IM MH - *Soil/chemistry MH - *Carbon/chemistry MH - Carbon Sequestration MH - Altitude MH - Crops, Agricultural OTO - NOTNLM OT - Cropland OT - Driving mechanisms OT - Machine learning OT - Soil organic carbon OT - Structural equation modelling COIS- Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2022/12/10 06:00 MHDA- 2023/01/20 06:00 CRDT- 2022/12/09 19:32 PHST- 2022/09/24 00:00 [received] PHST- 2022/11/21 00:00 [revised] PHST- 2022/11/26 00:00 [accepted] PHST- 2022/12/10 06:00 [pubmed] PHST- 2023/01/20 06:00 [medline] PHST- 2022/12/09 19:32 [entrez] AID - S0048-9697(22)07705-1 [pii] AID - 10.1016/j.scitotenv.2022.160602 [doi] PST - ppublish SO - Sci Total Environ. 2023 Mar 1;862:160602. doi: 10.1016/j.scitotenv.2022.160602. Epub 2022 Dec 7.