PMID- 36500426
OWN - NLM
STAT- MEDLINE
DCOM- 20221216
LR  - 20221222
IS  - 1420-3049 (Electronic)
IS  - 1420-3049 (Linking)
VI  - 27
IP  - 23
DP  - 2022 Nov 29
TI  - Highly Selective Methodology for Entrapment and Subsequent Removal of Cobalt (II) 
      Ions under Optimized Conditions by Micellar-Enhanced Ultrafiltration.
LID - 10.3390/molecules27238332 [doi]
LID - 8332
AB  - Micellar-enhanced ultrafiltration (MEUF), being a separation technique, was used 
      to remove cobalt metal ion (Co(2+)) from their aqueous solutions in an 
      application to reduce the toxicity level from industrial effluents using a 
      micellar solution of anionic and cationic surfactants. The metal ions were first 
      adsorbed by using anionic surfactants, i.e., sodium dodecyl sulfate (SDS) and 
      sodium oleate (SO). The calculations for partition (K(x)) and binding constants 
      (K(b)) and their respective free energy of partition and binding (DeltaG(p) and DeltaG(b) 
      kJmol(-1)) helped significantly to find out the extent of binding or interaction 
      of Co(2+) with the surfactant and DeltaG(p) and DeltaG(b) were found to be -29.50 and 
      -19.38 kJmol(-1) for SDS and -23.95 and -12.67 kJmol(-1) in the case of SO. MEUF 
      work was also performed to find out the optimal conditions to remove metal 
      pollutants from the aqueous system. For the said purpose, various factors and 
      concentrations effect were studied, such as the concentration of the surfactant, 
      concentration of the electrolyte (NaCl), transmembrane pressure, RPM, and pH. The 
      efficiency of this process was checked by calculating various parameters, such as 
      rejection percentage (R%) and permeate flux (J). A maximum rejection of 99.95% 
      with SDS and 99.99% with SO was attained.
FAU - Yusaf, Amnah
AU  - Yusaf A
AUID- ORCID: 0000-0002-0812-111X
AD  - Department of Chemistry, Government College University, Faisalabad 38000, 
      Pakistan.
AD  - Department of Chemistry, University College London, London WC1E 6BT, UK.
AD  - Department of Chemistry, Government College Women University, Faisalabad 38000, 
      Pakistan.
FAU - Usman, Muhammad
AU  - Usman M
AD  - Department of Chemistry, Government College University, Faisalabad 38000, 
      Pakistan.
FAU - Ahmad, Matloob
AU  - Ahmad M
AUID- ORCID: 0000-0003-1302-8056
AD  - Department of Chemistry, Government College University, Faisalabad 38000, 
      Pakistan.
FAU - Siddiq, Muhammad
AU  - Siddiq M
AUID- ORCID: 0000-0001-7894-8342
AD  - Department of Chemistry, Quaid-i-Azam University, Islamabad 45320, Pakistan.
FAU - Mansha, Asim
AU  - Mansha A
AUID- ORCID: 0000-0001-5659-0562
AD  - Department of Chemistry, Government College University, Faisalabad 38000, 
      Pakistan.
FAU - Al-Hussain, Sami A
AU  - Al-Hussain SA
AD  - Department of Chemistry, College of Science, Imam Mohammad Ibn Saud Islamic 
      University (IMSIU), Riyadh 13623, Saudi Arabia.
FAU - Zaki, Magdi E A
AU  - Zaki MEA
AUID- ORCID: 0000-0002-5643-9202
AD  - Department of Chemistry, College of Science, Imam Mohammad Ibn Saud Islamic 
      University (IMSIU), Riyadh 13623, Saudi Arabia.
FAU - Rehman, Hafiza Fatima
AU  - Rehman HF
AD  - Department of Zoology, Government College University, Faisalabad 38000, Pakistan.
LA  - eng
GR  - 20-3367/NRPU/R&D/HEC/14/Higher Education Commission of Pakistan/
PT  - Journal Article
DEP - 20221129
PL  - Switzerland
TA  - Molecules
JT  - Molecules (Basel, Switzerland)
JID - 100964009
RN  - 0 (Micelles)
RN  - 3G0H8C9362 (Cobalt)
RN  - 368GB5141J (Sodium Dodecyl Sulfate)
RN  - 0 (Surface-Active Agents)
RN  - 0 (Ions)
SB  - IM
MH  - *Micelles
MH  - *Cobalt
MH  - Ultrafiltration/methods
MH  - Sodium Dodecyl Sulfate
MH  - Surface-Active Agents
MH  - Ions
PMC - PMC9736276
OTO - NOTNLM
OT  - MEUF
OT  - RPM
OT  - adsorption
OT  - binding constant
OT  - concentration of surfactant
OT  - electrolyte
OT  - metal ions
OT  - micelles
OT  - pH
OT  - partition coefficient
OT  - permeate flux
OT  - rejection percentage
OT  - transmembrane pressure
COIS- The authors declare no conflict of interest.
EDAT- 2022/12/12 06:00
MHDA- 2022/12/15 06:00
PMCR- 2022/11/29
CRDT- 2022/12/11 01:27
PHST- 2022/10/29 00:00 [received]
PHST- 2022/11/18 00:00 [revised]
PHST- 2022/11/24 00:00 [accepted]
PHST- 2022/12/11 01:27 [entrez]
PHST- 2022/12/12 06:00 [pubmed]
PHST- 2022/12/15 06:00 [medline]
PHST- 2022/11/29 00:00 [pmc-release]
AID - molecules27238332 [pii]
AID - molecules-27-08332 [pii]
AID - 10.3390/molecules27238332 [doi]
PST - epublish
SO  - Molecules. 2022 Nov 29;27(23):8332. doi: 10.3390/molecules27238332.