PMID- 36508768
OWN - NLM
STAT- MEDLINE
DCOM- 20221227
LR  - 20221230
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1687
DP  - 2023 Jan 4
TI  - Application of electrospun composite nanofibers as an efficient sorbent for 
      extraction of pesticides from food samples.
PG  - 463699
LID - S0021-9673(22)00890-1 [pii]
LID - 10.1016/j.chroma.2022.463699 [doi]
AB  - Herein, the composite of polylactic acid (PLA)/ Iron-based metal-organic 
      framework (r-MIL-88A)/ Cellulose electrospun nanofibers was fabricated; and then, 
      applied as a novel sorbent for thin-film micro-extraction (TFME) of four selected 
      pesticides followed by GC-FID analysis. From the evaluation of scanning electron 
      microscopy, Fourier transform infrared spectroscopy energy dispersive X-ray 
      spectroscopy and X-ray diffraction, the successful fabrication of composite 
      nanaofibers was approved. The presence of r-MIL-88A/Cellulose with large surface 
      area and plenty of OH-functional groups results in improving PLA extraction 
      efficiency. The effect of various main parameters on extraction efficiency was 
      evaluated. The LODs (based on S/N = 3) were in the range of 1.0 to 1.5 ng mL(-1). 
      Intra-day and inter-day relative standard deviations (RSDs) were in the range of 
      4.8% - 5.6% and 5.2%-6.4%, respectively. In addition, the fiber to fiber relative 
      standard deviations were observed in the range of 5.2%-12.3%. By using the 
      optimized factors, acceptable linearity ranges were obtained in the range of 
      3.0-1900.0 ng mL(-1) for metribuzin and ethofumasate, and 5.0-2000.0 for atrazine 
      and ametryn (R(2) = 0.9913-0.9967). The developed method was investigated in 
      fruit juice, vegetables, milk and honey samples, and recoveries (79.3-95.6%) 
      indicate that the PLA/r-MIL-88A/Cellulose can be a prominent composite film for 
      the extraction of the target analytes in various samples.
CI  - Copyright (c) 2022. Published by Elsevier B.V.
FAU - Vosough, Sahar
AU  - Vosough S
AD  - Department of Analytical Chemistry and Pollutants, Faculty of Chemistry and 
      Petroleum Sciences, Shahid Beheshti University, Tehran, Iran.
FAU - Amini, Shima
AU  - Amini S
AD  - Department of Analytical Chemistry and Pollutants, Faculty of Chemistry and 
      Petroleum Sciences, Shahid Beheshti University, Tehran, Iran.
FAU - Ebrahimzadeh, Homeira
AU  - Ebrahimzadeh H
AD  - Department of Analytical Chemistry and Pollutants, Faculty of Chemistry and 
      Petroleum Sciences, Shahid Beheshti University, Tehran, Iran. Electronic address: 
      h-ebrahim@sbu.ac.ir.
FAU - Kandeh, Saeed Hejabri
AU  - Kandeh SH
AD  - Department of Analytical Chemistry and Pollutants, Faculty of Chemistry and 
      Petroleum Sciences, Shahid Beheshti University, Tehran, Iran.
LA  - eng
PT  - Journal Article
DEP - 20221205
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Pesticides)
RN  - 0 (Metal-Organic Frameworks)
RN  - 0 (Polyesters)
RN  - 9004-34-6 (Cellulose)
SB  - IM
MH  - *Nanofibers/chemistry
MH  - *Pesticides/analysis
MH  - *Metal-Organic Frameworks
MH  - Polyesters/analysis
MH  - Cellulose
MH  - Limit of Detection
MH  - Solid Phase Extraction/methods
OTO - NOTNLM
OT  - Agricultural pesticides
OT  - Composite nanofibers
OT  - Food analysis
OT  - Metal organic frame work
OT  - Thin-film micro-extraction
COIS- Declaration of Competing Interest The authors declare that they have no competing 
      interests.
EDAT- 2022/12/13 06:00
MHDA- 2022/12/28 06:00
CRDT- 2022/12/12 18:13
PHST- 2022/10/19 00:00 [received]
PHST- 2022/11/30 00:00 [revised]
PHST- 2022/12/02 00:00 [accepted]
PHST- 2022/12/13 06:00 [pubmed]
PHST- 2022/12/28 06:00 [medline]
PHST- 2022/12/12 18:13 [entrez]
AID - S0021-9673(22)00890-1 [pii]
AID - 10.1016/j.chroma.2022.463699 [doi]
PST - ppublish
SO  - J Chromatogr A. 2023 Jan 4;1687:463699. doi: 10.1016/j.chroma.2022.463699. Epub 
      2022 Dec 5.