PMID- 36555570
OWN - NLM
STAT- MEDLINE
DCOM- 20221226
LR  - 20221227
IS  - 1422-0067 (Electronic)
IS  - 1422-0067 (Linking)
VI  - 23
IP  - 24
DP  - 2022 Dec 14
TI  - Facet-Dependent SERS Activity of Co(3)O(4).
LID - 10.3390/ijms232415930 [doi]
LID - 15930
AB  - Surface-enhanced Raman spectroscopy (SERS) is an ultra-sensitive and rapid 
      technique that is able to significantly enhance the Raman signals of analytes 
      absorbed on functional substrates by orders of magnitude. Recently, 
      semiconductor-based SERS substrates have shown rapid progress due to their great 
      cost-effectiveness, stability and biocompatibility. In this work, three types of 
      faceted Co(3)O(4) microcrystals with dominantly exposed 100 facets, 111 
      facets and co-exposed 100-111 facets (denoted as C-100, C-111 and C-both, 
      respectively) are utilized as SERS substrates to detect the rhodamine 6G (R6G) 
      molecule and nucleic acids (adenine and cytosine). C-100 exhibited the highest 
      SERS sensitivity among these samples, and the lowest detection limits (LODs) to 
      R6G and adenine can reach 10(-7) M. First-principles density functional theory 
      (DFT) simulations further unveiled a stronger photoinduced charge transfer (PICT) 
      in C-100 than in C-111. This work provides new insights into the facet-dependent 
      SERS for semiconductor materials.
FAU - Feng, Yibo
AU  - Feng Y
AD  - Beijing Key Laboratory and Institute of Microstructure and Property of Advanced 
      Materials, Faculty of Materials and Manufacturing, Beijing University of 
      Technology, Beijing 100124, China.
FAU - Wang, Jiaxing
AU  - Wang J
AD  - Beijing Key Laboratory and Institute of Microstructure and Property of Advanced 
      Materials, Faculty of Materials and Manufacturing, Beijing University of 
      Technology, Beijing 100124, China.
FAU - Hou, Jixiang
AU  - Hou J
AD  - Beijing Key Laboratory and Institute of Microstructure and Property of Advanced 
      Materials, Faculty of Materials and Manufacturing, Beijing University of 
      Technology, Beijing 100124, China.
FAU - Zhang, Xu
AU  - Zhang X
AD  - Beijing Key Laboratory and Institute of Microstructure and Property of Advanced 
      Materials, Faculty of Materials and Manufacturing, Beijing University of 
      Technology, Beijing 100124, China.
FAU - Gao, Yuhang
AU  - Gao Y
AD  - Beijing Key Laboratory and Institute of Microstructure and Property of Advanced 
      Materials, Faculty of Materials and Manufacturing, Beijing University of 
      Technology, Beijing 100124, China.
FAU - Wang, Kaiwen
AU  - Wang K
AUID- ORCID: 0000-0002-1046-4525
AD  - Beijing Key Laboratory and Institute of Microstructure and Property of Advanced 
      Materials, Faculty of Materials and Manufacturing, Beijing University of 
      Technology, Beijing 100124, China.
LA  - eng
GR  - 12009015202001/National Natural Science Foundation of China/
PT  - Journal Article
DEP - 20221214
PL  - Switzerland
TA  - Int J Mol Sci
JT  - International journal of molecular sciences
JID - 101092791
RN  - 0 (cobalt tetraoxide)
SB  - IM
MH  - *Metal Nanoparticles/chemistry
MH  - Spectrum Analysis, Raman/methods
MH  - Semiconductors
PMC - PMC9788474
OTO - NOTNLM
OT  - Co3O4
OT  - DFT simulation
OT  - SERS
OT  - facet-dependent
COIS- The authors declare no conflict of interest.
EDAT- 2022/12/24 06:00
MHDA- 2022/12/27 06:00
PMCR- 2022/12/14
CRDT- 2022/12/23 01:35
PHST- 2022/11/26 00:00 [received]
PHST- 2022/12/09 00:00 [revised]
PHST- 2022/12/12 00:00 [accepted]
PHST- 2022/12/23 01:35 [entrez]
PHST- 2022/12/24 06:00 [pubmed]
PHST- 2022/12/27 06:00 [medline]
PHST- 2022/12/14 00:00 [pmc-release]
AID - ijms232415930 [pii]
AID - ijms-23-15930 [pii]
AID - 10.3390/ijms232415930 [doi]
PST - epublish
SO  - Int J Mol Sci. 2022 Dec 14;23(24):15930. doi: 10.3390/ijms232415930.