PMID- 36600630
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20230313
LR  - 20230313
IS  - 1521-4095 (Electronic)
IS  - 0935-9648 (Linking)
VI  - 35
IP  - 10
DP  - 2023 Mar
TI  - Photoredox-Promoted Co-Production of Dihydroisoquinoline and H(2) O(2) over 
      Defective Zn(3) In(2) S(6).
PG  - e2210110
LID - 10.1002/adma.202210110 [doi]
AB  - One of the most sustainable and promising approaches for hydrogen peroxide (H(2) 
      O(2) ) production in a low-cost and environment-friendly way is photosynthesis, 
      which, however, suffers from poor carrier utilization and low H(2) O(2) 
      productivity. The addition of proton donors such as isopropanol or ethanol can 
      increase H(2) O(2) production, which, unfortunately, will inevitably elevate the 
      entire cost while wasting the oxidizing power of holes (h(+) ). Herein, the 
      tetrahydroisoquinolines (THIQs) is employed as a distinctive proton donor for the 
      thermodynamically feasible and selective semi-dehydrogenation reaction to highly 
      valuable dihydroisoquinolines (DHIQs), and meanwhile, to couple with and promote 
      H(2) O(2) generation in one photoredox reaction under the photocatalysis by 
      dual-functional Zn(3) In(2) S(6) photocatalyst. Surprisingly, the suitably 
      defective Zn(3) In(2) S(6) offers an excellent and near-stoichiometric 
      co-production performance of H(2) O(2) and DHIQs at unprecedentedly high rates of 
      66.4 and 62.1 mmol h(-1) g(-1) under visible light (lambda >/= 400 nm), respectively, 
      which outperforms all the previously available reports even though sacrificial 
      agents were employed in those reports. Additionally, photocatalytic redox 
      reaction mechanism demonstrates that H(2) O(2) can be generated through multiple 
      pathways, highlighting the synergistic effect among ROS (.O(2) (-) and (1) O(2) 
      ), h(+) and proton donor, which has been ignored in previous studies.
CI  - (c) 2023 Wiley-VCH GmbH.
FAU - Luo, Juanjuan
AU  - Luo J
AD  - Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of 
      Chemistry and Molecular Engineering, East China Normal University, Shanghai, 
      200062, China.
FAU - Wei, Xinfa
AU  - Wei X
AD  - Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of 
      Chemistry and Molecular Engineering, East China Normal University, Shanghai, 
      200062, China.
FAU - Qiao, Yang
AU  - Qiao Y
AD  - Suzhou NATA Opto-Electronic Materials Ltd, Suzhou, 215127, China.
FAU - Wu, Chenyao
AU  - Wu C
AD  - Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of 
      Chemistry and Molecular Engineering, East China Normal University, Shanghai, 
      200062, China.
FAU - Li, Lanxin
AU  - Li L
AD  - Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of 
      Chemistry and Molecular Engineering, East China Normal University, Shanghai, 
      200062, China.
FAU - Chen, Lisong
AU  - Chen L
AD  - Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of 
      Chemistry and Molecular Engineering, East China Normal University, Shanghai, 
      200062, China.
AD  - Institute of Eco-Chongming, Shanghai, 202162, China.
FAU - Shi, Jianlin
AU  - Shi J
AUID- ORCID: 0000-0001-8790-195X
AD  - State Key Laboratory of High Performance Ceramics and Superfine Microstructures, 
      Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, 
      China.
LA  - eng
GR  - 2022YFB4002700/National Key R&D Program of China/
GR  - 22QA1403400/Shanghai Science and Technology Committee Rising-Star Program/
GR  - 21ZR1418700/Natural Science Foundation of Shanghai/
PT  - Journal Article
DEP - 20230113
PL  - Germany
TA  - Adv Mater
JT  - Advanced materials (Deerfield Beach, Fla.)
JID - 9885358
SB  - IM
OTO - NOTNLM
OT  - dual-functional semiconductors
OT  - hydrogen peroxide evolution
OT  - photosynthesis
OT  - reactive oxygen species
OT  - value-added chemicals
EDAT- 2023/01/06 06:00
MHDA- 2023/01/06 06:01
CRDT- 2023/01/05 01:53
PHST- 2022/12/13 00:00 [revised]
PHST- 2022/11/01 00:00 [received]
PHST- 2023/01/06 06:00 [pubmed]
PHST- 2023/01/06 06:01 [medline]
PHST- 2023/01/05 01:53 [entrez]
AID - 10.1002/adma.202210110 [doi]
PST - ppublish
SO  - Adv Mater. 2023 Mar;35(10):e2210110. doi: 10.1002/adma.202210110. Epub 2023 Jan 
      13.