PMID- 36639587 OWN - NLM STAT- MEDLINE DCOM- 20230405 LR - 20230405 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 30 IP - 14 DP - 2023 Mar TI - Mechanochemical treatment of hexachlorobenzene-contaminated soil with additives. PG - 41910-41922 LID - 10.1007/s11356-023-25212-4 [doi] AB - The use of mechanochemistry for the remediation of hexachlorobenzene (HCB)-contaminated soil was investigated. Additives such as alkaline materials, neutral materials, natural minerals, and solid waste were studied to explore their effect on the degradation of hexachlorobenzene in soil with single or combined addition by mechanochemical method. The best combination of materials were determined based on HCB destruction percentage by considering the impact on soil quality, the treatment cost, and the availability of additives. Scanning electron microscope (SEM) images and X-ray photoelectron spectrometer (XPS) analysis were conducted for the mechanism studies. The combination of albite and ferric oxide (Fe(3)O(4)) was found to achieve the best performance in the degradation of HCB with the destruction percentage from 74.3 to 92.5% after 2-h and 6-h reaction, respectively. The developed fracture structure and complex compositions of albite provided abundant reaction sites for mechanochemical degradation of HCB in soil. CI - (c) 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. FAU - Li, Xue AU - Li X AD - School of Energy and Environment, Southeast University, Nanjing, 210096, China. FAU - Chen, Huichao AU - Chen H AD - School of Energy and Environment, Southeast University, Nanjing, 210096, China. hcchen@seu.edu.cn. LA - eng GR - 2018YFC1800104-5/National Key Research and Development Program of China/ PT - Journal Article DEP - 20230114 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 4Z87H0LKUY (Hexachlorobenzene) RN - 0 (Soil Pollutants) RN - 0 (Soil) SB - IM MH - Hexachlorobenzene/analysis MH - *Environmental Restoration and Remediation MH - *Soil Pollutants/analysis MH - Environmental Pollution/analysis MH - Soil/chemistry OTO - NOTNLM OT - Additives OT - Contaminated soil OT - Dechlorination OT - Mechanochemistry EDAT- 2023/01/14 06:00 MHDA- 2023/04/05 06:42 CRDT- 2023/01/13 23:27 PHST- 2022/09/26 00:00 [received] PHST- 2023/01/05 00:00 [accepted] PHST- 2023/04/05 06:42 [medline] PHST- 2023/01/14 06:00 [pubmed] PHST- 2023/01/13 23:27 [entrez] AID - 10.1007/s11356-023-25212-4 [pii] AID - 10.1007/s11356-023-25212-4 [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2023 Mar;30(14):41910-41922. doi: 10.1007/s11356-023-25212-4. Epub 2023 Jan 14.