PMID- 36642694
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20230228
LR  - 20230228
IS  - 1521-3773 (Electronic)
IS  - 1433-7851 (Linking)
VI  - 62
IP  - 11
DP  - 2023 Mar 6
TI  - Boosting Hydrogen Production via Selective Two-electron Mild Electrochemical 
      Oxidation of Tetrahydroisoquinolines Completely to Dihydroisoquinolines.
PG  - e202216347
LID - 10.1002/anie.202216347 [doi]
AB  - Different from the previous study that biomass derivatives replace water 
      oxidation for enhancing hydrogen production, we found that mild oxidation was 
      more conductive to cathodic hydrogen production. In this study, maximum Faradaic 
      efficiency (>99 %) and lower energy consumption for hydrogen production was 
      achieved by precisely controlling the two-electron mild electrochemical oxidation 
      of tetrahydroisoquinolines (THIQs) to dihydroisoquinolines (DHIQs) in place of 
      the four-electron deep oxidation to isoquinolines (IQs). Moreover, the high 
      value-added DHIQs were prepared from THIQs with high selectivity (>99 %) at the 
      low potential of 1.36 V. Operando electrochemical Raman and density functional 
      theory proved that the high selectivity was attributed to the regulable active 
      species of NiOOH induced by the interaction of Co and Fe for preferentially 
      breaking C-H bond rather than N-H of THIQs. This novel method provides important 
      insight into efficient biomass-assisted hydrogen production.
CI  - (c) 2023 Wiley-VCH GmbH.
FAU - Zhou, Zhaoyu
AU  - Zhou Z
AD  - School of Chemical Science and Engineering, Shanghai Key Lab of Chemical 
      Assessment and Sustainability, Tongji University, 1239 Siping Road, Shanghai, 
      200092, P. R. China.
FAU - Pan, Xun
AU  - Pan X
AD  - School of Chemical Science and Engineering, Shanghai Key Lab of Chemical 
      Assessment and Sustainability, Tongji University, 1239 Siping Road, Shanghai, 
      200092, P. R. China.
FAU - Sun, Lingzhi
AU  - Sun L
AD  - School of Chemical Science and Engineering, Shanghai Key Lab of Chemical 
      Assessment and Sustainability, Tongji University, 1239 Siping Road, Shanghai, 
      200092, P. R. China.
FAU - Xie, Yanan
AU  - Xie Y
AD  - School of Chemical Science and Engineering, Shanghai Key Lab of Chemical 
      Assessment and Sustainability, Tongji University, 1239 Siping Road, Shanghai, 
      200092, P. R. China.
FAU - Zheng, Jingui
AU  - Zheng J
AD  - School of Chemical Science and Engineering, Shanghai Key Lab of Chemical 
      Assessment and Sustainability, Tongji University, 1239 Siping Road, Shanghai, 
      200092, P. R. China.
FAU - Li, Lina
AU  - Li L
AD  - Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, 
      Shanghai, 201800, P. R. China.
FAU - Zhao, Guohua
AU  - Zhao G
AUID- ORCID: 0000-0002-8693-1193
AD  - School of Chemical Science and Engineering, Shanghai Key Lab of Chemical 
      Assessment and Sustainability, Tongji University, 1239 Siping Road, Shanghai, 
      200092, P. R. China.
LA  - eng
GR  - 22076140/National Natural Science Foundation of China/
GR  - 21876128/National Natural Science Foundation of China/
GR  - 21537003/National Natural Science Foundation of China/
GR  - 2022-SSRF-PT-020439/Shanghai Synchrotron Radiation Facility/
GR  - 2022-SSRF-PT-020432/Shanghai Synchrotron Radiation Facility/
PT  - Journal Article
DEP - 20230201
PL  - Germany
TA  - Angew Chem Int Ed Engl
JT  - Angewandte Chemie (International ed. in English)
JID - 0370543
SB  - IM
OTO - NOTNLM
OT  - Hydrogen Production
OT  - Mild Oxidation
OT  - NiOOH Species
OT  - Operando Technologies
OT  - Selective Conversion
EDAT- 2023/01/16 06:00
MHDA- 2023/01/16 06:01
CRDT- 2023/01/15 22:12
PHST- 2022/11/06 00:00 [received]
PHST- 2023/01/16 06:00 [pubmed]
PHST- 2023/01/16 06:01 [medline]
PHST- 2023/01/15 22:12 [entrez]
AID - 10.1002/anie.202216347 [doi]
PST - ppublish
SO  - Angew Chem Int Ed Engl. 2023 Mar 6;62(11):e202216347. doi: 
      10.1002/anie.202216347. Epub 2023 Feb 1.