PMID- 36643534 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20230117 IS - 2470-1343 (Electronic) IS - 2470-1343 (Linking) VI - 8 IP - 1 DP - 2023 Jan 10 TI - Effect of Seawater Ions on Polymer Hydration in the Presence of a Chelating Agent: Application to Hydraulic Fracturing. PG - 969-975 LID - 10.1021/acsomega.2c06356 [doi] AB - Seawater (SW) and produced water (PW) could replace freshwater in hydraulic fracturing operations, but their high salinity impacts the fluid stability and results in formation damage. Few researchers investigated SW and PW individual ions' impact on polymer hydration and rheology. This research examines the rheology of carboxy methyl hydroxy propyl guar (CMHPG) polymer hydrated in salt ions in the presence of a chelating agent. The effect of various molar concentrations of SW and PW salt ions on the rheology of CMHPG polymer solution was examined. The tested salt ions included calcium chloride, magnesium chloride, sodium chloride, and sodium sulfate, which were compared to SW and deionized water (DI) solutions. The solutions were tested at 70 degrees C temperature, 500 psi pressure, and 100 1/s shear rate. A GLDA chelating agent was utilized at different concentrations to examine their impact on stabilizing the solution viscosity. We found that adding the GLDA to magnesium and calcium chloride solutions increased the viscosity. Results showed that sulfate ions control the rheology of seawater due to their similar rheological response to the addition of GLDA. The results help to understand how the SW and PW ions impact the rheology of fracturing fluids. CI - (c) 2022 The Authors. Published by American Chemical Society. FAU - Othman, Amro AU - Othman A AD - Department of Petroleum Engineering, King Fahd University of Petroleum & Minerals, 31261 Dhahran, Saudi Arabia. FAU - Murtaza, Mobeen AU - Murtaza M AUID- ORCID: 0000-0003-4279-4665 AD - Center for Integrative Petroleum Research, King Fahd University of Petroleum & Minerals, 31261 Dhahran, Saudi Arabia. FAU - Aljawad, Murtada Saleh AU - Aljawad MS AUID- ORCID: 0000-0002-3540-6807 AD - Department of Petroleum Engineering, King Fahd University of Petroleum & Minerals, 31261 Dhahran, Saudi Arabia. AD - Center for Integrative Petroleum Research, King Fahd University of Petroleum & Minerals, 31261 Dhahran, Saudi Arabia. FAU - Kamal, Muhammad Shahzad AU - Kamal MS AUID- ORCID: 0000-0003-2359-836X AD - Center for Integrative Petroleum Research, King Fahd University of Petroleum & Minerals, 31261 Dhahran, Saudi Arabia. FAU - Mahmoud, Mohamed AU - Mahmoud M AUID- ORCID: 0000-0002-4395-9567 AD - Department of Petroleum Engineering, King Fahd University of Petroleum & Minerals, 31261 Dhahran, Saudi Arabia. AD - Center for Integrative Petroleum Research, King Fahd University of Petroleum & Minerals, 31261 Dhahran, Saudi Arabia. FAU - Kalgaonkar, Rajendra A AU - Kalgaonkar RA AD - EXPECR ARC, Saudi Aramco, 31311 Dhahran, Saudi Arabia. LA - eng PT - Journal Article DEP - 20221225 PL - United States TA - ACS Omega JT - ACS omega JID - 101691658 PMC - PMC9835794 COIS- The authors declare no competing financial interest. EDAT- 2023/01/17 06:00 MHDA- 2023/01/17 06:01 PMCR- 2022/12/25 CRDT- 2023/01/16 02:41 PHST- 2022/10/02 00:00 [received] PHST- 2022/12/15 00:00 [accepted] PHST- 2023/01/16 02:41 [entrez] PHST- 2023/01/17 06:00 [pubmed] PHST- 2023/01/17 06:01 [medline] PHST- 2022/12/25 00:00 [pmc-release] AID - 10.1021/acsomega.2c06356 [doi] PST - epublish SO - ACS Omega. 2022 Dec 25;8(1):969-975. doi: 10.1021/acsomega.2c06356. eCollection 2023 Jan 10.