PMID- 36654300
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20230119
LR  - 20230119
IS  - 2095-9281 (Electronic)
IS  - 2095-9273 (Linking)
VI  - 66
IP  - 16
DP  - 2021 Aug 30
TI  - Self-assembly of anthraquinone covalent organic frameworks as 1D superstructures 
      for highly efficient CO(2) electroreduction to CH(4).
PG  - 1659-1668
LID - S2095-9273(21)00323-6 [pii]
LID - 10.1016/j.scib.2021.05.001 [doi]
AB  - The design of selective and efficient covalent organic frameworks (COFs) based 
      electrocatalysts with tunable morphology for efficient CO(2) reduction reaction 
      (CO(2)RR) to CH(4) is highly desirable. Here, two kinds of anthraquinone-based 
      COFs (i.e., AAn-COF and OH-AAn-COF) with tunable 1D superstructures (e.g., 
      nanofibers (NF) and hollow tubes (HT)) have been produced via Schiff-base 
      condensation reaction. Interestingly, a rarely reported nanosheet-based 
      self-template mechanism and a nanosheet-crimping mechanism have been demonstrated 
      for the production of COF-based nanofibers and hollow tubes, respectively. 
      Besides, the obtained COF-based superstructures can be post-modified with 
      transition metals for efficient CO(2)RR. Specifically, AAn-COF-Cu (NF) and 
      OH-AAn-COF-Cu (HT) exhibit superior faradaic-efficiency with CH(4) (FE(CH4)) of 
      77% (-128.1 mA cm(-2), -0.9 V) and 61% (-99.5 mA cm(-2), -1.0 V) in a flow-cell, 
      respectively. Noteworthy, the achieved FE(CH4) of AAn-COF-Cu (NF) (77%) the is 
      highest one among reported crystalline COFs. This work provides a general 
      methodology in exploring morphology-controlled COFs for electrocatalytic CO(2)RR.
CI  - Copyright (c) 2021 Science China Press. Published by Elsevier B.V. All rights 
      reserved.
FAU - Liu, Ming
AU  - Liu M
AD  - Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, 
      Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials 
      Science, Nanjing Normal University, Nanjing 210023, China.
FAU - Wang, Yi-Rong
AU  - Wang YR
AD  - Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, 
      Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials 
      Science, Nanjing Normal University, Nanjing 210023, China.
FAU - Ding, Hui-Min
AU  - Ding HM
AD  - Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, 
      Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials 
      Science, Nanjing Normal University, Nanjing 210023, China.
FAU - Lu, Meng
AU  - Lu M
AD  - Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, 
      Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials 
      Science, Nanjing Normal University, Nanjing 210023, China.
FAU - Gao, Guang-Kuo
AU  - Gao GK
AD  - Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, 
      Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials 
      Science, Nanjing Normal University, Nanjing 210023, China.
FAU - Dong, Long-Zhang
AU  - Dong LZ
AD  - Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, 
      Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials 
      Science, Nanjing Normal University, Nanjing 210023, China.
FAU - Li, Qi
AU  - Li Q
AD  - Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, 
      Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials 
      Science, Nanjing Normal University, Nanjing 210023, China.
FAU - Chen, Yifa
AU  - Chen Y
AD  - Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, 
      Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials 
      Science, Nanjing Normal University, Nanjing 210023, China; School of Chemistry, 
      South China Normal University, Guangzhou 510006, China. Electronic address: 
      chyf927821@163.com.
FAU - Li, Shun-Li
AU  - Li SL
AD  - Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, 
      Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials 
      Science, Nanjing Normal University, Nanjing 210023, China.
FAU - Lan, Ya-Qian
AU  - Lan YQ
AD  - Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, 
      Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials 
      Science, Nanjing Normal University, Nanjing 210023, China; School of Chemistry, 
      South China Normal University, Guangzhou 510006, China. Electronic address: 
      yqlan@m.scnu.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20210505
PL  - Netherlands
TA  - Sci Bull (Beijing)
JT  - Science bulletin
JID - 101655530
SB  - IM
OTO - NOTNLM
OT  - 1D superstructures
OT  - CO(2) electroreduction
OT  - Covalent organic frameworks
OT  - Hollow tubes
OT  - Nanofibers
COIS- Conflict of interest The authors declare that they have no conflict of interest.
EDAT- 2021/08/30 00:00
MHDA- 2021/08/30 00:01
CRDT- 2023/01/19 01:04
PHST- 2021/03/23 00:00 [received]
PHST- 2021/04/21 00:00 [revised]
PHST- 2021/04/26 00:00 [accepted]
PHST- 2023/01/19 01:04 [entrez]
PHST- 2021/08/30 00:00 [pubmed]
PHST- 2021/08/30 00:01 [medline]
AID - S2095-9273(21)00323-6 [pii]
AID - 10.1016/j.scib.2021.05.001 [doi]
PST - ppublish
SO  - Sci Bull (Beijing). 2021 Aug 30;66(16):1659-1668. doi: 
      10.1016/j.scib.2021.05.001. Epub 2021 May 5.