PMID- 36658953
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20230120
IS  - 2095-9281 (Electronic)
IS  - 2095-9273 (Linking)
VI  - 63
IP  - 12
DP  - 2018 Jun 30
TI  - Controlling reduction degree of graphene oxide membranes for improved water 
      permeance.
PG  - 788-794
LID - S2095-9273(18)30236-6 [pii]
LID - 10.1016/j.scib.2018.05.015 [doi]
AB  - Tailoring the pore structure and surface chemistry of graphene-based laminates is 
      essentially important for their applications as separation membranes. Usually, 
      pure graphene oxide (GO) and completely reduced GO (rGO) membranes suffer from 
      low water permeance because of the lack of pristine graphitic sp(2) domains and 
      very small interlayer spacing, respectively. In this work, we studied the 
      influence of reduction degree on the structure and separation performance of rGO 
      membranes. It was found that weak reduction retains the good dispersion and 
      hydrophilicity of GO nanosheets. More importantly, it increases the number of 
      pristine graphitic sp(2) domains in rGO nanosheets while keeping the large 
      interlayer spacing of the GO membranes in most regions at the same time. The 
      resultant membranes show a high water permeance of 56.3 L m(-2) h(-1) bar(-1), 
      which is about 4 times and over 10(4) times larger than those of the GO and 
      completely reduced rGO membranes, respectively, and high rejection over 95% for 
      various dyes. Furthermore, they show better structure stability and more superior 
      separation performance than GO membranes in acid and alkali environments.
CI  - Copyright (c) 2018 Science China Press. Published by Elsevier B.V. All rights 
      reserved.
FAU - Zhang, Qing
AU  - Zhang Q
AD  - Shenyang National Laboratory for Materials Science, Institute of Metal Research, 
      Chinese Academy of Sciences, Shenyang 110016, China; School of Materials Science 
      and Engineering, University of Science and Technology of China, Shenyang 110016, 
      China.
FAU - Qian, Xitang
AU  - Qian X
AD  - Shenyang National Laboratory for Materials Science, Institute of Metal Research, 
      Chinese Academy of Sciences, Shenyang 110016, China; School of Materials Science 
      and Engineering, University of Science and Technology of China, Shenyang 110016, 
      China.
FAU - Thebo, Khalid Hussain
AU  - Thebo KH
AD  - Shenyang National Laboratory for Materials Science, Institute of Metal Research, 
      Chinese Academy of Sciences, Shenyang 110016, China; University of Chinese 
      Academy of Sciences, Beijing 100049, China.
FAU - Cheng, Hui-Ming
AU  - Cheng HM
AD  - Shenyang National Laboratory for Materials Science, Institute of Metal Research, 
      Chinese Academy of Sciences, Shenyang 110016, China; School of Materials Science 
      and Engineering, University of Science and Technology of China, Shenyang 110016, 
      China; Tsinghua-Berkeley Shenzhen Institute (TBSI), Tsinghua University, Shenzhen 
      518055, China.
FAU - Ren, Wencai
AU  - Ren W
AD  - Shenyang National Laboratory for Materials Science, Institute of Metal Research, 
      Chinese Academy of Sciences, Shenyang 110016, China; School of Materials Science 
      and Engineering, University of Science and Technology of China, Shenyang 110016, 
      China. Electronic address: wcren@imr.ac.cn.
LA  - eng
PT  - Journal Article
DEP - 20180525
PL  - Netherlands
TA  - Sci Bull (Beijing)
JT  - Science bulletin
JID - 101655530
SB  - IM
OTO - NOTNLM
OT  - Graphene oxide
OT  - Reduction
OT  - Separation membrane
OT  - Water permeance
EDAT- 2018/06/30 00:00
MHDA- 2018/06/30 00:01
CRDT- 2023/01/20 01:06
PHST- 2018/04/23 00:00 [received]
PHST- 2018/04/29 00:00 [revised]
PHST- 2018/04/30 00:00 [accepted]
PHST- 2023/01/20 01:06 [entrez]
PHST- 2018/06/30 00:00 [pubmed]
PHST- 2018/06/30 00:01 [medline]
AID - S2095-9273(18)30236-6 [pii]
AID - 10.1016/j.scib.2018.05.015 [doi]
PST - ppublish
SO  - Sci Bull (Beijing). 2018 Jun 30;63(12):788-794. doi: 10.1016/j.scib.2018.05.015. 
      Epub 2018 May 25.