PMID- 36677680
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20230123
LR  - 20230124
IS  - 1420-3049 (Electronic)
IS  - 1420-3049 (Linking)
VI  - 28
IP  - 2
DP  - 2023 Jan 7
TI  - Amino Phenyl Copper Phosphate-Bridged Reactive Phosphaphenanthrene to Intensify 
      Fire Safety of Epoxy Resins.
LID - 10.3390/molecules28020623 [doi]
LID - 623
AB  - To improve the compatibility between flame retardant and epoxy resin (EP) matrix, 
      amino phenyl copper phosphate-9, 
      10-dihydro-9-oxygen-10-phospha-phenanthrene-10-oxide (CuPPA-DOPO) is synthesized 
      through surface grafting, which is blended with EP matrix to prepare 
      EP/CuPPA-DOPO composites. The amorphous structure of CuPPA-DOPO is characterized 
      by X-ray diffraction and Fourier-transform infrared spectroscopy. Scanning 
      electron microscope (SEM) images indicate that the agglomeration of hybrids is 
      improved, resisting the intense intermolecular attractions on account of the 
      acting force between CuPPA and DOPO. The results of thermal analysis show that 
      CuPPA-DOPO can promote the premature decomposition of EP and increase the 
      residual amount of EP composites. It is worth mentioning that EP/6 wt% CuPPA-DOPO 
      composites reach UL-94 V-1 level and limiting oxygen index (LOI) of 32.6%. 
      Meanwhile, their peak heat release rate (PHRR), peak smoke production release 
      (PSPR) and CO(2) production (CO(2)P) are decreased by 52.5%, 26.1% and 41.4%, 
      respectively, compared with those of EP. The inhibition effect of CuPPA-DOPO on 
      the combustion of EP may be due to the release of phosphorus and ammonia free 
      radicals, as well as the catalytic charring ability of metal oxides and 
      phosphorus phases.
FAU - Chai, Huiyu
AU  - Chai H
AD  - School of Emergency Management, Jiangsu University, Zhenjiang 212013, China.
FAU - Li, Weixi
AU  - Li W
AD  - School of Emergency Management, Jiangsu University, Zhenjiang 212013, China.
FAU - Wan, Shengbing
AU  - Wan S
AD  - Zhejiang Jiamin New Materials Co., Ltd., Jiaxing 314027, China.
FAU - Liu, Zheng
AU  - Liu Z
AD  - Zhejiang Jiamin New Materials Co., Ltd., Jiaxing 314027, China.
FAU - Zhang, Yafen
AU  - Zhang Y
AD  - Zhejiang Jiamin New Materials Co., Ltd., Jiaxing 314027, China.
FAU - Zhang, Yunlong
AU  - Zhang Y
AD  - School of Emergency Management, Jiangsu University, Zhenjiang 212013, China.
FAU - Zhang, Junhao
AU  - Zhang J
AUID- ORCID: 0000-0002-9878-4629
AD  - School of Environmental and Chemical Engineering, Jiangsu University of Science 
      and Technology, Zhenjiang 212003, China.
FAU - Kong, Qinghong
AU  - Kong Q
AD  - School of Emergency Management, Jiangsu University, Zhenjiang 212013, China.
LA  - eng
PT  - Journal Article
DEP - 20230107
PL  - Switzerland
TA  - Molecules
JT  - Molecules (Basel, Switzerland)
JID - 100964009
SB  - IM
PMC - PMC9861604
OTO - NOTNLM
OT  - amino phenyl metal phosphate
OT  - epoxy resin
OT  - organic-inorganic hybrid
OT  - reactive flame retardant
COIS- The authors declare no conflict of interest.
EDAT- 2023/01/22 06:00
MHDA- 2023/01/22 06:01
PMCR- 2023/01/07
CRDT- 2023/01/21 01:43
PHST- 2022/12/09 00:00 [received]
PHST- 2023/01/03 00:00 [revised]
PHST- 2023/01/04 00:00 [accepted]
PHST- 2023/01/21 01:43 [entrez]
PHST- 2023/01/22 06:00 [pubmed]
PHST- 2023/01/22 06:01 [medline]
PHST- 2023/01/07 00:00 [pmc-release]
AID - molecules28020623 [pii]
AID - molecules-28-00623 [pii]
AID - 10.3390/molecules28020623 [doi]
PST - epublish
SO  - Molecules. 2023 Jan 7;28(2):623. doi: 10.3390/molecules28020623.