PMID- 36716401
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20230213
LR  - 20230217
IS  - 1520-510X (Electronic)
IS  - 0020-1669 (Print)
IS  - 0020-1669 (Linking)
VI  - 62
IP  - 6
DP  - 2023 Feb 13
TI  - Chiral Co(3)Y Propeller-Shaped Chemosensory Platforms Based on (19)F-NMR.
PG  - 2680-2693
LID - 10.1021/acs.inorgchem.2c03737 [doi]
AB  - Two propeller-shaped chiral Co(III)(3)Y(III) complexes built from fluorinated 
      ligands are synthesized and characterized by single-crystal X-ray diffraction 
      (SXRD), IR, UV-vis, circular dichroism (CD), elemental analysis, 
      thermogravimetric analysis (TGA), electron spray ionization mass spectroscopy 
      (ESI-MS), and NMR ((1)H, (13)C, and (19)F). This work explores the sensing and 
      discrimination abilities of these complexes, thus providing an innovative sensing 
      method using a (19)F NMR chemosensory system and opening new directions in 3d/4f 
      chemistry. Control experiments and theoretical studies shed light on the sensing 
      mechanism, while the scope and limitations of this method are discussed and 
      presented.
FAU - Audsley, Gabrielle
AU  - Audsley G
AD  - Department of Chemistry, School of Life Sciences, University of Sussex, Brighton 
      BN1 9QJ, UK.
FAU - Carpenter, Harry
AU  - Carpenter H
AD  - Department of Chemistry, School of Life Sciences, University of Sussex, Brighton 
      BN1 9QJ, UK.
FAU - Essien, Nsikak B
AU  - Essien NB
AD  - Department of Chemistry, School of Life Sciences, University of Sussex, Brighton 
      BN1 9QJ, UK.
FAU - Lai-Morrice, James
AU  - Lai-Morrice J
AUID- ORCID: 0000-0001-6319-0698
AD  - Department of Chemistry, School of Life Sciences, University of Sussex, Brighton 
      BN1 9QJ, UK.
FAU - Al-Hilaly, Youssra
AU  - Al-Hilaly Y
AUID- ORCID: 0000-0003-2289-4597
AD  - Sussex Neuroscience, School of Life Sciences, University of Sussex, Brighton BN1 
      9QG, UK.
AD  - Chemistry Department, College of Science, Mustansiriyah University, Baghdad 
      10001, Iraq.
FAU - Serpell, Louise C
AU  - Serpell LC
AUID- ORCID: 0000-0001-9335-7751
AD  - Sussex Neuroscience, School of Life Sciences, University of Sussex, Brighton BN1 
      9QG, UK.
FAU - Akien, Geoffrey R
AU  - Akien GR
AD  - Department of Chemistry, Lancaster University, Lancaster LA1 4YB, UK.
FAU - Tizzard, Graham J
AU  - Tizzard GJ
AD  - UK National Crystallography Service, Chemistry, University of Southampton, 
      Southampton SO1 71BJ, UK.
FAU - Coles, Simon J
AU  - Coles SJ
AUID- ORCID: 0000-0001-8414-9272
AD  - UK National Crystallography Service, Chemistry, University of Southampton, 
      Southampton SO1 71BJ, UK.
FAU - Ulldemolins, Cristina Pubill
AU  - Ulldemolins CP
AD  - Department of Chemistry, School of Life Sciences, University of Sussex, Brighton 
      BN1 9QJ, UK.
FAU - Kostakis, George E
AU  - Kostakis GE
AUID- ORCID: 0000-0002-4316-4369
AD  - Department of Chemistry, School of Life Sciences, University of Sussex, Brighton 
      BN1 9QJ, UK.
LA  - eng
PT  - Journal Article
DEP - 20230130
PL  - United States
TA  - Inorg Chem
JT  - Inorganic chemistry
JID - 0366543
SB  - IM
PMC - PMC9930122
COIS- The authors declare no competing financial interest.
EDAT- 2023/01/31 06:00
MHDA- 2023/01/31 06:01
PMCR- 2023/02/15
CRDT- 2023/01/30 15:53
PHST- 2023/01/31 06:00 [pubmed]
PHST- 2023/01/31 06:01 [medline]
PHST- 2023/01/30 15:53 [entrez]
PHST- 2023/02/15 00:00 [pmc-release]
AID - 10.1021/acs.inorgchem.2c03737 [doi]
PST - ppublish
SO  - Inorg Chem. 2023 Feb 13;62(6):2680-2693. doi: 10.1021/acs.inorgchem.2c03737. Epub 
      2023 Jan 30.