PMID- 36716772
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20230329
LR  - 20230329
IS  - 1521-4095 (Electronic)
IS  - 0935-9648 (Linking)
VI  - 35
IP  - 13
DP  - 2023 Mar
TI  - Flexible Zinc-Air Batteries with Ampere-Hour Capacities and Wide-Temperature 
      Adaptabilities.
PG  - e2209980
LID - 10.1002/adma.202209980 [doi]
AB  - Flexible Zn-air batteries (FZABs) have significant potentials as efficient energy 
      storage devices for wearable electronics because of their safeties and high 
      energy-to-cost ratios. However, their application is limited by their short cycle 
      lives, low discharge capacities per cycle, and high charge/discharge 
      polarizations. Accordingly, herein, a poly(sodium acrylate)-polyvinyl alcohol 
      (PANa-PVA)-ionic liquid (IL) hydrogel (PANa-PVA-IL) is prepared using a 
      hygroscopic IL, 1-ethyl-3-methylimidazolium chloride, as an additive for 
      twin-chain PANa-PVA. PANa-PVA-IL exhibits a high conductivity of 306.9 mS cm(-1) 
      and a water uptake of 2515 wt% at room temperature. Moreover, a low-cost 
      bifunctional catalyst, namely, Co(9) S(8) nanoparticles anchored on N- and 
      S-co-doped activated carbon black pearls 2000 (Co(9) S(8) -NSABP), is 
      synthesized, which demonstrates a low O(2) reversibility potential gap of 
      0.629 V. FZABs based on PANa-PVA-IL and Co(9) S(8) -NSABP demonstrate high 
      discharge capacities of 1.67 mAh cm(-2) per cycle and long cycle lives of 
      330 h. Large-scale flexible rechargeable Zn-air pouch cells exhibit total 
      capacities of 1.03 Ah and energy densities of 246 Wh kg(cell) (-1) . This study 
      provides new information about hydrogels with high ionic conductivities and water 
      uptakes and should facilitate the application of FZABs in wearable electronics.
CI  - (c) 2023 Wiley-VCH GmbH.
FAU - Zhong, Xiongwei
AU  - Zhong X
AUID- ORCID: 0000-0003-2307-0450
AD  - Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute & Tsinghua 
      Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055, 
      China.
FAU - Zheng, Zhiyang
AU  - Zheng Z
AD  - Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute & Tsinghua 
      Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055, 
      China.
FAU - Xu, Jiahe
AU  - Xu J
AD  - Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute & Tsinghua 
      Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055, 
      China.
FAU - Xiao, Xiao
AU  - Xiao X
AD  - Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute & Tsinghua 
      Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055, 
      China.
FAU - Sun, Chongbo
AU  - Sun C
AD  - Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute & Tsinghua 
      Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055, 
      China.
FAU - Zhang, Mengtian
AU  - Zhang M
AD  - Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute & Tsinghua 
      Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055, 
      China.
FAU - Ma, Jiabin
AU  - Ma J
AD  - Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute & Tsinghua 
      Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055, 
      China.
FAU - Xu, Baomin
AU  - Xu B
AD  - Department of Materials Science and Engineering, Southern University of Science 
      and Technology, Shenzhen, 518055, China.
FAU - Yu, Kuang
AU  - Yu K
AD  - Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute & Tsinghua 
      Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055, 
      China.
FAU - Zhang, Xuan
AU  - Zhang X
AD  - Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute & Tsinghua 
      Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055, 
      China.
FAU - Cheng, Hui-Ming
AU  - Cheng HM
AD  - Faculty of Materials Science and Energy Engineering/Institute of Technology for 
      Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of 
      Science, Shenzhen, 518055, China.
AD  - Shenyang National Laboratory for Materials Science, Institute of Metal Research, 
      Chinese Academy of Sciences, 72 Wenhua Road, Shenyang, 110016, China.
FAU - Zhou, Guangmin
AU  - Zhou G
AUID- ORCID: 0000-0002-3629-5686
AD  - Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute & Tsinghua 
      Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055, 
      China.
LA  - eng
GR  - 2019YFA0705700/National Key Research and Development Program of China/
GR  - 52072205/National Natural Science Foundation of China/
GR  - 2021ZT09L197/Guangdong Innovative and Entrepreneurial Research Team Program/
GR  - KQTD20210811090112002/Shenzhen Science and Technology Program/
GR  - Start-up funds of Tsinghua Shenzhen International Graduate School/
GR  - JCYJ20200109141014474/Shenzhen Science and Technology Innovation Committee/
GR  - 2022A1515110117/Guangdong Basic and Applied Basic Research Foundation/
GR  - 2020M680542/China Postdoctoral Science Foundation/
PT  - Journal Article
DEP - 20230217
PL  - Germany
TA  - Adv Mater
JT  - Advanced materials (Deerfield Beach, Fla.)
JID - 9885358
SB  - IM
OTO - NOTNLM
OT  - broad temperature range
OT  - flexible zinc-air batteries
OT  - hydrogels
OT  - ionic liquids
OT  - wearable electronics
EDAT- 2023/01/31 06:00
MHDA- 2023/01/31 06:01
CRDT- 2023/01/30 19:03
PHST- 2023/01/19 00:00 [revised]
PHST- 2022/10/28 00:00 [received]
PHST- 2023/01/31 06:01 [medline]
PHST- 2023/01/31 06:00 [pubmed]
PHST- 2023/01/30 19:03 [entrez]
AID - 10.1002/adma.202209980 [doi]
PST - ppublish
SO  - Adv Mater. 2023 Mar;35(13):e2209980. doi: 10.1002/adma.202209980. Epub 2023 Feb 
      17.