PMID- 36727727
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20230406
LR  - 20230406
IS  - 1521-3773 (Electronic)
IS  - 1433-7851 (Linking)
VI  - 62
IP  - 17
DP  - 2023 Apr 17
TI  - Locally Concentrated Ionic Liquid Electrolytes for Lithium-Metal Batteries.
PG  - e202219318
LID - 10.1002/anie.202219318 [doi]
AB  - Non-flammable ionic liquid electrolytes (ILEs) are well-known candidates for 
      safer and long-lifespan lithium metal batteries (LMBs). However, the high 
      viscosity and insufficient Li(+) transport limit their practical application. 
      Recently, non-solvating and low-viscosity co-solvents diluting ILEs without 
      affecting the local Li(+) solvation structure are employed to solve these 
      problems. The diluted electrolytes, i.e., locally concentrated ionic liquid 
      electrolytes (LCILEs), exhibiting lower viscosity, faster Li(+) transport, and 
      enhanced compatibility toward lithium metal anodes, are feasible options for the 
      next-generation high-energy-density LMBs. Herein, the progress of the recently 
      developed LCILEs are summarised, including their physicochemical properties, 
      solution structures, and applications in LMBs with a variety of high-energy 
      cathode materials. Lastly, a perspective on the future research directions of 
      LCILEs to further understanding and achieve improved cell performances is 
      outlined.
CI  - (c) 2023 The Authors. Angewandte Chemie International Edition published by 
      Wiley-VCH GmbH.
FAU - Liu, Xu
AU  - Liu X
AD  - Helmholtz Institute Ulm (HIU), Helmholtzstrasse 11, 89081 Ulm (Germany), Karlsruhe 
      Institute of Technology (KIT), P.O. Box 3640, 76021, UlmKarlsruhe, Germany.
FAU - Mariani, Alessandro
AU  - Mariani A
AD  - Helmholtz Institute Ulm (HIU), Helmholtzstrasse 11, 89081 Ulm (Germany), Karlsruhe 
      Institute of Technology (KIT), P.O. Box 3640, 76021, UlmKarlsruhe, Germany.
AD  - Present address: ELETTRA Synchrotron of Trieste, 34012 Basovizza, Trieste, Italy.
FAU - Adenusi, Henry
AU  - Adenusi H
AD  - Hong Kong Quantum AI Lab, 17 Science Park West Avenue, Hong Kong, China.
FAU - Passerini, Stefano
AU  - Passerini S
AUID- ORCID: 0000-0002-6606-5304
AD  - Helmholtz Institute Ulm (HIU), Helmholtzstrasse 11, 89081 Ulm (Germany), Karlsruhe 
      Institute of Technology (KIT), P.O. Box 3640, 76021, UlmKarlsruhe, Germany.
AD  - Chemistry Department, Sapienza University, Piazzale A. Moro 5, 00185, Rome, 
      Italy.
LA  - eng
GR  - China Scholarship Council/
GR  - Helmholtz-Gemeinschaft/
GR  - Hong Kong Quantum AI Lab Limited/
PT  - Journal Article
PT  - Review
DEP - 20230215
PL  - Germany
TA  - Angew Chem Int Ed Engl
JT  - Angewandte Chemie (International ed. in English)
JID - 0370543
SB  - IM
OTO - NOTNLM
OT  - Ionic Liquid Electrolytes
OT  - Lithium Metal Anodes
OT  - Lithium-Metal Batteries
OT  - Locally Concentrated Electrolytes
OT  - Non-Solvating Solvents
EDAT- 2023/02/03 06:00
MHDA- 2023/02/03 06:01
CRDT- 2023/02/02 07:35
PHST- 2022/12/30 00:00 [received]
PHST- 2023/02/03 06:01 [medline]
PHST- 2023/02/03 06:00 [pubmed]
PHST- 2023/02/02 07:35 [entrez]
AID - 10.1002/anie.202219318 [doi]
PST - ppublish
SO  - Angew Chem Int Ed Engl. 2023 Apr 17;62(17):e202219318. doi: 
      10.1002/anie.202219318. Epub 2023 Feb 15.