PMID- 36738716
OWN - NLM
STAT- MEDLINE
DCOM- 20230303
LR  - 20230303
IS  - 1095-8630 (Electronic)
IS  - 0301-4797 (Linking)
VI  - 332
DP  - 2023 Apr 15
TI  - Degradation of 2,4-diclorophenol via coupling zero valent iron and hydrodynamic 
      cavitation for sulfite activation: A turbulence modeling.
PG  - 117295
LID - S0301-4797(23)00083-X [pii]
LID - 10.1016/j.jenvman.2023.117295 [doi]
AB  - The 2,4-dichlorophenol (2,4-DCP) is an important chemical precursor that can 
      affect human endocrine system and induce pathological symptoms. This research 
      reports the degradation of 2,4-DCP using lab-scale hydrodynamic cavitation (HC) 
      approach, which is considered a green and effective method. To promote the 
      degradation efficiency, the zero-valent iron (Fe(0)) as the catalyst for sulfate 
      radical (SO(4)(*-)) generation via activation of sulfite (SO(3)(2-)) salts was 
      simultaneously used. Degradation efficiency was favorable in acidic pH than the 
      alkaline pH due to higher production of active radicals and was dependent on the 
      dose of Fe(0) and SO(3)(2-). Under optimal condition, degradation efficiency by 
      Fe(0)/HC/sulfite (96.67 +/- 2.90%) was considerably enhanced compared to HC alone 
      (45.37 +/- 2.26%). Quenching experiments suggested that SO(4)(*-), (*)OH, (1)O(2), 
      and O(2)(*-) radicals were involved in the degradation of 2,4-DCP by 
      Fe(0)/HC/sulfite process, but the dominant role was related to (*)OH (70.09% 
      contribution) and SO(4)(*-) (29.91% contribution) radicals. From the turbulence 
      model, turbulent pressure at venturi throat decreased from -0.42 MPa to -2.02 MPa 
      by increasing the inlet pressure from 1.0 to 4.0 bar and increase in pressure 
      gradient has intensified bubble collapse due to higher turbulence tension.
CI  - Copyright (c) 2023 Elsevier Ltd. All rights reserved.
FAU - Azizollahi, Nastaran
AU  - Azizollahi N
AD  - Department of Environmental Health Engineering, School of Health, Isfahan 
      University of Medical Sciences, Isfahan, Iran; Student Research Committee, School 
      of Health, Isfahan University of Medical Sciences, Isfahan, Iran.
FAU - Fatehizadeh, Ali
AU  - Fatehizadeh A
AD  - Department of Environmental Health Engineering, School of Health, Isfahan 
      University of Medical Sciences, Isfahan, Iran; Environment Research Center, 
      Research Institute for Primordial Prevention of Non-Communicable Disease, Isfahan 
      University of Medical Sciences, Isfahan, Iran.
FAU - Pourzamani, Hamidreza
AU  - Pourzamani H
AD  - Department of Environmental Health Engineering, School of Health, Isfahan 
      University of Medical Sciences, Isfahan, Iran; Environment Research Center, 
      Research Institute for Primordial Prevention of Non-Communicable Disease, Isfahan 
      University of Medical Sciences, Isfahan, Iran.
FAU - Taheri, Ensiyeh
AU  - Taheri E
AD  - Department of Environmental Health Engineering, School of Health, Isfahan 
      University of Medical Sciences, Isfahan, Iran; Environment Research Center, 
      Research Institute for Primordial Prevention of Non-Communicable Disease, Isfahan 
      University of Medical Sciences, Isfahan, Iran. Electronic address: 
      e_taheri@hlth.mui.ac.ir.
FAU - Aminabhavi, Tejraj M
AU  - Aminabhavi TM
AD  - School of Advanced Sciences, KLE Technological University, Hubballi, 580031, 
      India; Department of Chemistry, Karnatak University, Dharwad, 580 003, India; 
      School of Engineering, University of Petroleum and Energy Studies, Dehradun, 248 
      007, India; Center for Energy and Environment,School of Advanced Sciences,KLE 
      Technological University,Hubballi 580031 India. Electronic address: 
      aminabhavit@gmail.com.
LA  - eng
PT  - Journal Article
DEP - 20230202
PL  - England
TA  - J Environ Manage
JT  - Journal of environmental management
JID - 0401664
RN  - E1UOL152H7 (Iron)
RN  - 0 (Water Pollutants, Chemical)
RN  - 0 (Sulfites)
SB  - IM
MH  - Humans
MH  - *Iron
MH  - Hydrodynamics
MH  - *Water Pollutants, Chemical
MH  - Catalysis
MH  - Sulfites
MH  - Oxidation-Reduction
OTO - NOTNLM
OT  - 2,4-Diclorophenol
OT  - Advanced oxidation
OT  - Hydrodynamic cavitation
OT  - Sulfate radicals
OT  - Turbulence modeling
OT  - Zero-valent iron
COIS- Declaration of competing interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2023/02/05 06:00
MHDA- 2023/03/04 06:00
CRDT- 2023/02/04 18:20
PHST- 2022/11/16 00:00 [received]
PHST- 2023/01/11 00:00 [revised]
PHST- 2023/01/11 00:00 [accepted]
PHST- 2023/02/05 06:00 [pubmed]
PHST- 2023/03/04 06:00 [medline]
PHST- 2023/02/04 18:20 [entrez]
AID - S0301-4797(23)00083-X [pii]
AID - 10.1016/j.jenvman.2023.117295 [doi]
PST - ppublish
SO  - J Environ Manage. 2023 Apr 15;332:117295. doi: 10.1016/j.jenvman.2023.117295. 
      Epub 2023 Feb 2.