PMID- 36764260
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20230228
LR  - 20230228
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 448
DP  - 2023 Apr 15
TI  - Source identification of PCBs in Antarctic air by compound-specific isotope 
      analysis of chlorine (CSIA-Cl) using HRGC/HRMS.
PG  - 130907
LID - S0304-3894(23)00189-9 [pii]
LID - 10.1016/j.jhazmat.2023.130907 [doi]
AB  - Occurrence of persistent organic pollutants (POPs) in the Polar Regions has 
      received great concern in the past several decades due to their long-term adverse 
      effect on biological health in such a fragile environment. However, there is 
      still argument over their source and fate in these pristine areas. Here we 
      attempted to use a novel approach (compound-specific isotope analysis of 
      chlorine, CSIA-Cl) to identify the source of POPs in Antarctic air by comparison 
      with the source area. The results showed that the relative isotope-ratio 
      variation of Cl (delta(37)Cl') values showed a large variation from - 137 to 9.04  per thousand 
      in the gas-phase samples, and a significantly negative correlation (p < 0.01) was 
      obtained against the logKoa values of PCBs. There were no significant 
      correlations (p > 0.05) observed between the delta(37)Cl' values and meteorological 
      parameters except for PCB-28 which showed temperature dependence. By contrast, 
      the delta(37)Cl' values in the urban (Beijing) air ranged from - 12.8 to 2.03  per thousand. The 
      larger variation of delta(37)Cl' in Antarctic air indicated evidently influence of 
      long-range atmospheric transport (LRAT) on isotopologue fractionation of PCBs. 
      This study may shed light on the application of CSIA-Cl for source identification 
      of chlorinated POPs on a large scale.
CI  - Copyright (c) 2023 Elsevier B.V. All rights reserved.
FAU - Wang, Pu
AU  - Wang P
AD  - Hubei Key Laboratory of Environmental and Health Effects of Persistent Toxic 
      Substances, School of Environment and Health, Jianghan University, Wuhan 430056, 
      China.
FAU - Meng, Wenying
AU  - Meng W
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China.
FAU - Zhang, Weiwei
AU  - Zhang W
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China.
FAU - Fu, Min
AU  - Fu M
AD  - Key Laboratory of Research on Marine Hazards Forecasting, National Marine 
      Environmental Forecasting Center, Beijing 100081, China.
FAU - Li, Yingming
AU  - Li Y
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China.
FAU - Yang, Ruiqiang
AU  - Yang R
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China.
FAU - Zhang, Qinghua
AU  - Zhang Q
AD  - Hubei Key Laboratory of Environmental and Health Effects of Persistent Toxic 
      Substances, School of Environment and Health, Jianghan University, Wuhan 430056, 
      China; State Key Laboratory of Environmental Chemistry and Ecotoxicology, 
      Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, 
      Beijing 100085, China; University of Chinese Academy of Sciences, Beijing 100049, 
      China. Electronic address: qhzhang@rcees.ac.cn.
FAU - Jiang, Guibin
AU  - Jiang G
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China; University of Chinese Academy of Sciences, Beijing 100049, China.
LA  - eng
PT  - Journal Article
DEP - 20230129
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
SB  - IM
OTO - NOTNLM
OT  - Antarctic air
OT  - CSIA-Cl
OT  - LRAT
OT  - PCBs
OT  - Urban air
COIS- Declaration of Competing Interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2023/02/11 06:00
MHDA- 2023/02/11 06:01
CRDT- 2023/02/10 18:21
PHST- 2022/12/01 00:00 [received]
PHST- 2023/01/27 00:00 [revised]
PHST- 2023/01/28 00:00 [accepted]
PHST- 2023/02/11 06:00 [pubmed]
PHST- 2023/02/11 06:01 [medline]
PHST- 2023/02/10 18:21 [entrez]
AID - S0304-3894(23)00189-9 [pii]
AID - 10.1016/j.jhazmat.2023.130907 [doi]
PST - ppublish
SO  - J Hazard Mater. 2023 Apr 15;448:130907. doi: 10.1016/j.jhazmat.2023.130907. Epub 
      2023 Jan 29.