PMID- 36792676 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20230216 LR - 20230218 IS - 2045-2322 (Electronic) IS - 2045-2322 (Linking) VI - 13 IP - 1 DP - 2023 Feb 15 TI - Effects of Al(2)O(3), SiO(2) nanoparticles, and g-C(3)N(4) nanosheets on biocement production from agricultural wastes. PG - 2720 LID - 10.1038/s41598-023-29180-0 [doi] LID - 2720 AB - Environmental issues are brought up concerning the production of Portland cement. As a result, biocement serves as a reliable substitute for Portland cement in green construction projects. This study created a brand-new technique to create high-quality biocement from agricultural wastes. The technique is based on nanomaterials that improve and accelerate the "Microbially Induced Calcite Precipitation (MICP)" process, which improves the quality of the biocement produced. The mixture was further mixed with the addition of 5 mg/l of graphitic carbon nitride nanosheets (g-C(3)N(4) NSs), alumina nanoparticles (Al(2)O(3) NPs), or silica nanoparticles (SiO(2) NPs). The cement: sand ratio was 1:3, the ash: cement ratio was 1:9, and water: cement ratio was 1:2. Cubes molds were prepared, and then cast and compacted. Subsequent de-molding, all specimens were cured in nutrient broth-urea (NBU) media until testing at 28 days. The medium was replenished at an interval of 7 days. The results show that the addition of 5 mg/l of g-C(3)N(4) NSs with corncob ash delivered the highest "Compressive Strength" and the highest "Flexural Strength" of biocement mortar cubes of 18 and 7.6 megapascal (MPa), respectively; and an acceptable "Water Absorption" (5.42%) compared to all other treatments. This treatment delivered a "Compressive Strength", "Flexural Strength", and "Water Absorption" reduction of 1.67, 1.26, and 1.21 times the control (standard Portland cement). It was concluded that adding 5 mg/l of g-C(3)N(4) NSs to the cementitious mixture enhances its properties, where the resulting biocement is a promising substitute for conventional Portland cement. Adding nanomaterials to cement reduces its permeability to ions, increasing its strength and durability. The use of these nanomaterials can enhance the performance of concrete infrastructures. The use of nanoparticles is an effective solution to reduce the environmental impact associated with concrete production. CI - (c) 2023. The Author(s). FAU - Abdelsalam, Essam M AU - Abdelsalam EM AD - Department of ​Laser Applications in Metrology, Photochemistry and Agriculture (LAMPA), National Institute of Laser Enhanced Sciences (NILES), Cairo University, Giza, Egypt. abdelsalam@niles.cu.edu.eg. FAU - Samer, Mohamed AU - Samer M AD - Department of Agricultural Engineering, Faculty of Agriculture, Cairo University, Giza, Egypt. msamer@agr.cu.edu.eg. FAU - Seifelnasr, Amira AU - Seifelnasr A AD - Department of Agricultural Engineering, Faculty of Agriculture, Cairo University, Giza, Egypt. FAU - Moselhy, Mohamed A AU - Moselhy MA AD - Department of Microbiology, Faculty of Agriculture, Cairo University, Giza, Egypt. FAU - Ibrahim, Hatem H A AU - Ibrahim HHA AD - Department of Structural Engineering, Faculty of Engineering, Cairo University, Giza, Egypt. FAU - Faried, Maryam AU - Faried M AD - Department of Agricultural Engineering, Faculty of Agriculture, Cairo University, Giza, Egypt. FAU - Attia, Yasser A AU - Attia YA AD - Department of ​Laser Applications in Metrology, Photochemistry and Agriculture (LAMPA), National Institute of Laser Enhanced Sciences (NILES), Cairo University, Giza, Egypt. yasserniles@niles.cu.edu.eg. LA - eng PT - Journal Article DEP - 20230215 PL - England TA - Sci Rep JT - Scientific reports JID - 101563288 SB - IM PMC - PMC9932060 COIS- The authors declare no competing interests. EDAT- 2023/02/16 06:00 MHDA- 2023/02/16 06:01 PMCR- 2023/02/15 CRDT- 2023/02/15 23:19 PHST- 2022/11/09 00:00 [received] PHST- 2023/01/31 00:00 [accepted] PHST- 2023/02/15 23:19 [entrez] PHST- 2023/02/16 06:00 [pubmed] PHST- 2023/02/16 06:01 [medline] PHST- 2023/02/15 00:00 [pmc-release] AID - 10.1038/s41598-023-29180-0 [pii] AID - 29180 [pii] AID - 10.1038/s41598-023-29180-0 [doi] PST - epublish SO - Sci Rep. 2023 Feb 15;13(1):2720. doi: 10.1038/s41598-023-29180-0.