PMID- 36832120 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20230228 IS - 2075-4418 (Print) IS - 2075-4418 (Electronic) IS - 2075-4418 (Linking) VI - 13 IP - 4 DP - 2023 Feb 8 TI - Graphene Oxide-PAMAM Nanocomposite and Ionic Liquid Modified Carbon Paste Electrode: An Efficient Electrochemical Sensor for Simultaneous Determination of Catechol and Resorcinol. LID - 10.3390/diagnostics13040632 [doi] LID - 632 AB - In this paper, a simple strategy was proposed for the analysis of catechol by a carbon paste electrode (CPE) modified with graphene oxide-third generation of poly(amidoamine) dendrimer (GO/G3-PAMAM) nanocomposite and ionic liquid (IL). The synthesis of GO-PAMAM nanocomposite was confirmed using X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), field emission scanning electron microscopy (FE-SEM), and Fourier transform infrared spectroscopy (FT-IR) techniques. The prepared modified electrode (GO-PAMAM/ILCPE) exhibited good performance to detect catechol with a notable decrease in overpotential and increase in current compared with an unmodified CPE. Under optimum experimental conditions, GO-PAMAM/ILCPE electrochemical sensors indicated a lower limit of detection (LOD) of 0.034 muM and a linear response in the concentration range of 0.1 to 200.0 microM for the quantitative measurement of catechol in aqueous solutions. In addition, GO-PAMAM/ILCPE sensor exhibited an ability to simultaneously determine catechol and resorcinol. It can be found that catechol and resorcinol could be completely separated on the GO-PAMAM/ILCPE with the differential pulse voltammetry (DPV) technique. Finally, a GO-PAMAM/ILCPE sensor was utilized to detect catechol and resorcinol in water samples with recoveries of 96.2% to 103.3% and relative standard deviations (RSDs) of less than 1.7%. FAU - Garkani Nejad, Fariba AU - Garkani Nejad F AD - Department of Chemistry, Faculty of Science, Shahid Bahonar University of Kerman, Kerman 7616914111, Iran. FAU - Beitollahi, Hadi AU - Beitollahi H AUID- ORCID: 0000-0002-0669-5216 AD - Environment Department, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman 7631818356, Iran. FAU - Sheikhshoaie, Iran AU - Sheikhshoaie I AD - Department of Chemistry, Faculty of Science, Shahid Bahonar University of Kerman, Kerman 7616914111, Iran. LA - eng PT - Journal Article DEP - 20230208 PL - Switzerland TA - Diagnostics (Basel) JT - Diagnostics (Basel, Switzerland) JID - 101658402 PMC - PMC9954798 OTO - NOTNLM OT - carbon paste electrode OT - catechol OT - electrochemical sensor OT - graphene oxide-poly(amidoamine) dendrimer nanocomposite OT - ionic liquid OT - resorcinol COIS- The authors declare no conflict of interest. EDAT- 2023/02/26 06:00 MHDA- 2023/02/26 06:01 PMCR- 2023/02/08 CRDT- 2023/02/25 01:49 PHST- 2022/12/27 00:00 [received] PHST- 2023/02/03 00:00 [revised] PHST- 2023/02/05 00:00 [accepted] PHST- 2023/02/25 01:49 [entrez] PHST- 2023/02/26 06:00 [pubmed] PHST- 2023/02/26 06:01 [medline] PHST- 2023/02/08 00:00 [pmc-release] AID - diagnostics13040632 [pii] AID - diagnostics-13-00632 [pii] AID - 10.3390/diagnostics13040632 [doi] PST - epublish SO - Diagnostics (Basel). 2023 Feb 8;13(4):632. doi: 10.3390/diagnostics13040632.