PMID- 36857891
OWN - NLM
STAT- MEDLINE
DCOM- 20230321
LR  - 20230321
IS  - 1095-8630 (Electronic)
IS  - 0301-4797 (Linking)
VI  - 335
DP  - 2023 Jun 1
TI  - Comprehensive evaluation of corrosion inhibition performance and ecotoxicological 
      effect of cinchona IIa as a green corrosion inhibitor for pickling of Q235 steel.
PG  - 117531
LID - S0301-4797(23)00319-5 [pii]
LID - 10.1016/j.jenvman.2023.117531 [doi]
AB  - Here, to prevent the corrosion of Q235 steel in the pickling and discover novel 
      green corrosion inhibitors, the corrosion inhibition performance and eco-toxicity 
      of cinchonain IIa were evaluated. Electrochemical experiments confirms that 
      200 mg/L cinchonain IIa reveals good corrosion inhibition performance with 94.08% 
      on Q235 steel in HCl for 48 h. Scanning electron microscope (SEM) and atomic 
      force microscope (AFM) observations suggest that cinchonain IIa can be firmly 
      attached to the metal surface by forming a barrier film. The X-ray photoelectron 
      spectroscopy (XPS) results further verify the bonding interaction between the 
      functional groups and the steel matrix, and indicate the existence of protective 
      film on the steel. Meanwhile, the inhibition mechanism at the molecular/atomic 
      level is revealed through molecular dynamics simulation. Additionally, acute 
      toxicity test shows that cinchonain IIa is a low toxic corrosion inhibitor. 
      Moreover, the antioxidant enzyme activity experiments confirm that cinchonain IIa 
      discloses no obvious damage to the antioxidant system of zebrafish. Overall, 
      cinchonain IIa exhibits low potential risks to the healthy development of aquatic 
      organisms and ecosystems. As a proven green and low toxic corrosion inhibitor, 
      cinchonain IIa has a sustainable application in the anti-corrosion industry.
CI  - Copyright (c) 2023 Elsevier Ltd. All rights reserved.
FAU - Huang, Li
AU  - Huang L
AD  - Weihai Key Laboratory of Active Factor of Marine Products, School of Chemistry 
      and Chemical Engineering, Harbin Institute of Technology, Harbin, 150006, PR 
      China.
FAU - Li, Hui-Jing
AU  - Li HJ
AD  - Weihai Key Laboratory of Active Factor of Marine Products, School of Chemistry 
      and Chemical Engineering, Harbin Institute of Technology, Harbin, 150006, PR 
      China.
FAU - Wu, Yan-Chao
AU  - Wu YC
AD  - Weihai Key Laboratory of Active Factor of Marine Products, School of Chemistry 
      and Chemical Engineering, Harbin Institute of Technology, Harbin, 150006, PR 
      China. Electronic address: yanchaowu@iccas.ac.cn.
LA  - eng
PT  - Journal Article
DEP - 20230227
PL  - England
TA  - J Environ Manage
JT  - Journal of environmental management
JID - 0401664
RN  - 0 (Antioxidants)
RN  - 12597-69-2 (Steel)
RN  - 0 (Water Pollutants, Chemical)
SB  - IM
MH  - Animals
MH  - Antioxidants/metabolism
MH  - *Cinchona/toxicity
MH  - Ecosystem
MH  - Steel/chemistry
MH  - Zebrafish
MH  - *Water Pollutants, Chemical/toxicity
MH  - Ecotoxicology
OTO - NOTNLM
OT  - Cinchonain IIa
OT  - Environmental toxicity
OT  - Green corrosion inhibitor
OT  - MD simulation
OT  - XPS
COIS- Declaration of competing interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2023/03/02 06:00
MHDA- 2023/03/15 06:00
CRDT- 2023/03/01 18:10
PHST- 2022/08/24 00:00 [received]
PHST- 2023/02/12 00:00 [revised]
PHST- 2023/02/15 00:00 [accepted]
PHST- 2023/03/02 06:00 [pubmed]
PHST- 2023/03/15 06:00 [medline]
PHST- 2023/03/01 18:10 [entrez]
AID - S0301-4797(23)00319-5 [pii]
AID - 10.1016/j.jenvman.2023.117531 [doi]
PST - ppublish
SO  - J Environ Manage. 2023 Jun 1;335:117531. doi: 10.1016/j.jenvman.2023.117531. Epub 
      2023 Feb 27.