PMID- 36913507
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20230328
LR  - 20230328
IS  - 1520-5827 (Electronic)
IS  - 0743-7463 (Linking)
VI  - 39
IP  - 12
DP  - 2023 Mar 28
TI  - Influence of the Au-Ti Active Site of the Titanosilicate MWW Zeolite on the 
      Catalytic Activity of Ethane Dehydrogenation in the Presence of O(2).
PG  - 4427-4438
LID - 10.1021/acs.langmuir.3c00083 [doi]
AB  - The titanosilicate zeolite with a MWW topology structure was synthesized by the 
      atom-planting method through the dehydrochlorination of the hydroxyl group in the 
      deboronated ERB-1 zeolite (D-ERB-1) and TiCl(4), and Au was further loaded with 
      the deposition precipitation method to apply for the ethane direct 
      dehydrogenation (DH) and dehydrogenation of ethane in the presence of O(2) 
      (O(2)-DH). It was found that Au nanoparticles (NPs) below 5 nm exhibited good 
      activity for ethane direct dehydrogenation and O(2)-DH. The addition of titanium 
      can not only anchor more Au but also make Au have a more dispersed homogeneous 
      distribution. The ethane O(2)-DH catalytic performances of Au-loaded 
      Ti-incorporated D-ERB-1 (Ti-D-ERB-1) were compared to those of Au-loaded 
      ZnO-D-ERB-1 and pure silicate D-ERB-1. The results confirm that ethane O(2)-DH 
      catalyzed by Au-Ti paired active sites is a tandem reaction of catalytic ethane 
      DH and selective H(2) combustion (SHC) of generated H(2). According to the 
      experimental results and calculated kinetic parameters, such as the activation 
      energy of DH and SHC reaction heat of O(2)-DH, SHC catalyzed by the Au/Ti-D-ERB-1 
      catalyst containing the Au-Ti active site can not only break the ethane 
      dehydrogenation thermodynamic equilibrium limitation to improve the ethylene 
      yield but also suppress the CO(2) and CO selectivity.
FAU - Meng, Xu
AU  - Meng X
AD  - Key Laboratory for Green Chemical Process of Ministry of Education, Hubei Novel 
      Reactor & Green Chemical Technology Key Laboratory, School of Chemical 
      Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan, Hubei 430205, 
      People's Republic of China.
FAU - Wu, Guiying
AU  - Wu G
AD  - Key Laboratory for Green Chemical Process of Ministry of Education, Hubei Novel 
      Reactor & Green Chemical Technology Key Laboratory, School of Chemical 
      Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan, Hubei 430205, 
      People's Republic of China.
FAU - Cheng, Xiaojie
AU  - Cheng X
AD  - Research Institute of Petroleum Processing, Sinopec, Beijing 10083, People's 
      Republic of China.
FAU - Wang, Jing
AU  - Wang J
AD  - Key Laboratory of Catalysis, Center Tech Tianjin Chemical Research and Design 
      Institute Company, Limited, Tianjin 300131, People's Republic of China.
FAU - Peng, Aoqiang
AU  - Peng A
AD  - Key Laboratory for Green Chemical Process of Ministry of Education, Hubei Novel 
      Reactor & Green Chemical Technology Key Laboratory, School of Chemical 
      Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan, Hubei 430205, 
      People's Republic of China.
FAU - Liang, Tingyu
AU  - Liang T
AD  - Key Laboratory for Green Chemical Process of Ministry of Education, Hubei Novel 
      Reactor & Green Chemical Technology Key Laboratory, School of Chemical 
      Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan, Hubei 430205, 
      People's Republic of China.
FAU - Jin, Fang
AU  - Jin F
AUID- ORCID: 0000-0001-7946-9722
AD  - Key Laboratory for Green Chemical Process of Ministry of Education, Hubei Novel 
      Reactor & Green Chemical Technology Key Laboratory, School of Chemical 
      Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan, Hubei 430205, 
      People's Republic of China.
LA  - eng
PT  - Journal Article
DEP - 20230313
PL  - United States
TA  - Langmuir
JT  - Langmuir : the ACS journal of surfaces and colloids
JID - 9882736
SB  - IM
EDAT- 2023/03/14 06:00
MHDA- 2023/03/14 06:01
CRDT- 2023/03/13 14:12
PHST- 2023/03/14 06:01 [medline]
PHST- 2023/03/14 06:00 [pubmed]
PHST- 2023/03/13 14:12 [entrez]
AID - 10.1021/acs.langmuir.3c00083 [doi]
PST - ppublish
SO  - Langmuir. 2023 Mar 28;39(12):4427-4438. doi: 10.1021/acs.langmuir.3c00083. Epub 
      2023 Mar 13.