PMID- 36964159
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20230327
LR  - 20230328
IS  - 2041-1723 (Electronic)
IS  - 2041-1723 (Linking)
VI  - 14
IP  - 1
DP  - 2023 Mar 24
TI  - Supramolecular glasses with color-tunable circularly polarized afterglow through 
      evaporation-induced self-assembly of chiral metal-organic complexes.
PG  - 1654
LID - 10.1038/s41467-023-37331-0 [doi]
LID - 1654
AB  - The fabrication of chiral molecules into macroscopic systems has many valuable 
      applications, especially in the fields of optical displays, data encryption, 
      information storage, and so on. Here, we design and prepare a serious of 
      supramolecular glasses (SGs) based on Zn-L-Histidine complexes, via an 
      evaporation-induced self-assembly (EISA) strategy. Metal-ligand interactions 
      between the zinc(II) ion and chiral L-Histidine endow the SGs with interesting 
      circularly polarized afterglow (CPA). Multicolored CPA emissions from blue to red 
      with dissymmetry factor as high as 9.5 x 10(-3) and excited-state lifetime up to 
      356.7 ms are achieved under ambient conditions. Therefore, this work not only 
      communicates the bulk SGs with wide-tunable afterglow and large circular 
      polarization, but also provides an EISA method for the macroscopic self-assembly 
      of chiral metal-organic hybrids toward photonic applications.
CI  - (c) 2023. The Author(s).
FAU - Nie, Fei
AU  - Nie F
AD  - Beijing Key Laboratory of Energy Conversion and Storage Materials, College of 
      Chemistry, Key Laboratory of Radiopharmaceuticals, Ministry of Education, Beijing 
      Normal University, Beijing, 100875, P. R. China.
FAU - Wang, Ke-Zhi
AU  - Wang KZ
AD  - Beijing Key Laboratory of Energy Conversion and Storage Materials, College of 
      Chemistry, Key Laboratory of Radiopharmaceuticals, Ministry of Education, Beijing 
      Normal University, Beijing, 100875, P. R. China.
FAU - Yan, Dongpeng
AU  - Yan D
AUID- ORCID: 0000-0001-8261-154X
AD  - Beijing Key Laboratory of Energy Conversion and Storage Materials, College of 
      Chemistry, Key Laboratory of Radiopharmaceuticals, Ministry of Education, Beijing 
      Normal University, Beijing, 100875, P. R. China. yandp@bnu.edu.cn.
LA  - eng
GR  - JQ20003/Natural Science Foundation of Beijing Municipality (Beijing Natural 
      Science Foundation)/
GR  - 21822501/National Natural Science Foundation of China (National Science 
      Foundation of China)/
GR  - 21978021/National Natural Science Foundation of China (National Science 
      Foundation of China)/
GR  - 22275021/National Natural Science Foundation of China (National Science 
      Foundation of China)/
GR  - 22061130206/National Natural Science Foundation of China (National Science 
      Foundation of China)/
GR  - 171008/Fok Ying Tong Education Foundation/
PT  - Journal Article
DEP - 20230324
PL  - England
TA  - Nat Commun
JT  - Nature communications
JID - 101528555
SB  - IM
PMC - PMC10039082
COIS- The authors declare no competing interests.
EDAT- 2023/03/26 06:00
MHDA- 2023/03/26 06:01
PMCR- 2023/03/24
CRDT- 2023/03/25 00:15
PHST- 2022/10/11 00:00 [received]
PHST- 2023/03/11 00:00 [accepted]
PHST- 2023/03/25 00:15 [entrez]
PHST- 2023/03/26 06:00 [pubmed]
PHST- 2023/03/26 06:01 [medline]
PHST- 2023/03/24 00:00 [pmc-release]
AID - 10.1038/s41467-023-37331-0 [pii]
AID - 37331 [pii]
AID - 10.1038/s41467-023-37331-0 [doi]
PST - epublish
SO  - Nat Commun. 2023 Mar 24;14(1):1654. doi: 10.1038/s41467-023-37331-0.