PMID- 36972874
OWN - NLM
STAT- MEDLINE
DCOM- 20230414
LR  - 20230414
IS  - 1879-1298 (Electronic)
IS  - 0045-6535 (Linking)
VI  - 327
DP  - 2023 Jun
TI  - Efficient remediation of the field soil contaminated with PAHs by amorphous 
      porous iron material activated peroxymonosulfate.
PG  - 138516
LID - S0045-6535(23)00783-X [pii]
LID - 10.1016/j.chemosphere.2023.138516 [doi]
AB  - An amorphous porous iron material (FH) was firstly self-synthesized using a 
      simple coprecipitation approach and then utilized to activate peroxymonosulfate 
      (PMS) for the catalytic degradation of pyrene and remediation of PAHs 
      contaminated soil on site. FH exhibited more excellent catalytic activity than 
      traditional hydroxy ferric oxide and possessed stability at a pH range of 
      3.0-11.0. According to quenching studies and electron paramagnetic resonance 
      (EPR) analyses, non-radicals (Fe(IV) = O and 1O2) were the major reactive oxygen 
      species (ROS) in the FH/PMS system's degradation of pyrene. X-ray photoelectron 
      spectroscopy (XPS) and Fourier transform infrared spectroscopy (FT-IR) of FH 
      before and after the catalytic reaction, as well as active site substitution 
      experiments and electrochemical analysis all verified that PMS adsorbed on FH 
      could produce more abundant bonded hydroxyl groups (Fe-OH) which dominated the 
      radical and non-radical oxidation reactions. Then, a possible pathway for pyrene 
      degradation was presented according to gas chromatography-mass spectrometry 
      (GC-MS). Furthermore, the FH/PMS system exhibited excellent catalytic degradation 
      in the remediation of PAH-contaminated soil at real sites. This work provides a 
      remarkable potential remediation technology of persistent organic pollutants 
      (POPs) in environmental and will contribute to understanding the mechanism of 
      Fe-based hydroxides in advanced oxidation processes.
CI  - Copyright (c) 2023 Elsevier Ltd. All rights reserved.
FAU - Tang, Xuejiao
AU  - Tang X
AD  - Key Laboratory of Pollution Processes and Environmental Criteria, Ministry of 
      Education, College of Environmental Science and Engineering, Nankai University, 
      Tianjin, 300350, China. Electronic address: tangxuejiao@nankai.edu.cn.
FAU - Guo, Jiacheng
AU  - Guo J
AD  - Key Laboratory of Pollution Processes and Environmental Criteria, Ministry of 
      Education, College of Environmental Science and Engineering, Nankai University, 
      Tianjin, 300350, China.
FAU - Gao, Yue
AU  - Gao Y
AD  - Key Laboratory of Pollution Processes and Environmental Criteria, Ministry of 
      Education, College of Environmental Science and Engineering, Nankai University, 
      Tianjin, 300350, China.
FAU - Zhen, Kai
AU  - Zhen K
AD  - Key Laboratory of Pollution Processes and Environmental Criteria, Ministry of 
      Education, College of Environmental Science and Engineering, Nankai University, 
      Tianjin, 300350, China.
FAU - Sun, Hongwen
AU  - Sun H
AD  - Key Laboratory of Pollution Processes and Environmental Criteria, Ministry of 
      Education, College of Environmental Science and Engineering, Nankai University, 
      Tianjin, 300350, China.
FAU - Wang, Cuiping
AU  - Wang C
AD  - Key Laboratory of Pollution Processes and Environmental Criteria, Ministry of 
      Education, College of Environmental Science and Engineering, Nankai University, 
      Tianjin, 300350, China. Electronic address: wangcp@nankai.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20230325
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 22047-43-4 (peroxymonosulfate)
RN  - E1UOL152H7 (Iron)
RN  - 0 (Peroxides)
RN  - 0 (Pyrenes)
SB  - IM
MH  - *Iron/chemistry
MH  - Porosity
MH  - Spectroscopy, Fourier Transform Infrared
MH  - *Peroxides/chemistry
MH  - Pyrenes
OTO - NOTNLM
OT  - Amorphous ferric hydroxide
OT  - Degradation pathway
OT  - PAHs
OT  - Peroxymonosulfate (PMS) activation
OT  - Radicals and non-radicals
COIS- Declaration of competing interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2023/03/28 06:00
MHDA- 2023/04/14 06:41
CRDT- 2023/03/27 20:26
PHST- 2023/01/13 00:00 [received]
PHST- 2023/03/22 00:00 [revised]
PHST- 2023/03/24 00:00 [accepted]
PHST- 2023/04/14 06:41 [medline]
PHST- 2023/03/28 06:00 [pubmed]
PHST- 2023/03/27 20:26 [entrez]
AID - S0045-6535(23)00783-X [pii]
AID - 10.1016/j.chemosphere.2023.138516 [doi]
PST - ppublish
SO  - Chemosphere. 2023 Jun;327:138516. doi: 10.1016/j.chemosphere.2023.138516. Epub 
      2023 Mar 25.