PMID- 37011511
OWN - NLM
STAT- MEDLINE
DCOM- 20230426
LR  - 20230426
IS  - 1090-2414 (Electronic)
IS  - 0147-6513 (Linking)
VI  - 256
DP  - 2023 May
TI  - Sulfurized nano zero-valent iron prepared via different methods: Effect of 
      stability and types of surface corrosion products on removal of 
      2,4,6-trichlorophenol.
PG  - 114864
LID - S0147-6513(23)00368-8 [pii]
LID - 10.1016/j.ecoenv.2023.114864 [doi]
AB  - Sulfurization improves the stability and activity of nano zero-valent iron 
      (nZVI). The sulfurized nZVI (S-nZVI) were prepared with ball milling, vacuum 
      chemical vapor deposition (CVD) and liquid-phase reduction techniques and the 
      corresponding products were the mixture of FeS(2) and nZVI (nZVI/FeS(2)), 
      well-defined core-shell structure (FeS(x)@Fe) or seriously oxidized (S-nZVI(aq)), 
      respectively. All these materials were applied to eliminate 2,4,6-trichlorophenol 
      (TCP) from water. The removal of TCP was irrelevant with the structure of S-nZVI. 
      Both nZVI/FeS(2) and FeS(x)@Fe showed remarkable performance for the degradation 
      of TCP. S-nZVI(aq) possessed poor mineralization efficiency to TCP due to its bad 
      crystallinity degree and severe leaching of Fe ions, which retarded the affinity 
      of TCP. Desorption and quenching experiments suggested that TCP removal by nZVI 
      and S-nZVI was based on surface adsorption and subsequent direct reduction by 
      Fe(0), oxidation by in-situ produced ROS and polymerization on the surface of 
      these materials. In the reaction process, the corrosion products of these 
      materials transformed into crystalline Fe(3)O(4) and alpha/beta-FeOOH, which enhanced 
      the stability of nZVI and S-nZVI materials and was conductive to the electron 
      transferring from Fe(0) to TCP and strong affinity of TCP onto Fe or FeS(x) 
      phases. All these were contributed to high performance of nZVI and sulfurized 
      nZVI in removal and minerazilation of TCP in continuous recycle test.
CI  - Copyright (c) 2023 The Authors. Published by Elsevier Inc. All rights reserved.
FAU - Li, Li
AU  - Li L
AD  - School of Chemistry and Materials Science, Ludong University, Yantai, Shandong 
      Province 264025, China; State Key Laboratory of Environmental Chemistry and 
      Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of 
      Sciences, Beijing 100085, China.
FAU - Jin, Huiwen
AU  - Jin H
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China; School of Life Science, North China University of Science and 
      Technology, Tangshan, Hebei Province 063210, China.
FAU - Luo, Na
AU  - Luo N
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China; University of Chinese Academy of Sciences, Beijing, 100049, China.
FAU - Niu, Hongyun
AU  - Niu H
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China. Electronic address: hyniu@rcees.ac.cn.
FAU - Cai, Yaqi
AU  - Cai Y
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China; University of Chinese Academy of Sciences, Beijing, 100049, China; 
      Institute of Environment and Health, Hangzhou Institute for Advanced Study, UCAS, 
      Hangzhou, Zhejiang Province 310013, China.
FAU - Cao, Dong
AU  - Cao D
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China.
FAU - Zhang, Shengxiao
AU  - Zhang S
AD  - School of Chemistry and Materials Science, Ludong University, Yantai, Shandong 
      Province 264025, China. Electronic address: beijingzsx@163.com.
LA  - eng
PT  - Journal Article
DEP - 20230401
PL  - Netherlands
TA  - Ecotoxicol Environ Saf
JT  - Ecotoxicology and environmental safety
JID - 7805381
RN  - E1UOL152H7 (Iron)
RN  - MHS8C5BAUZ (2,4,6-trichlorophenol)
RN  - 0 (Water Pollutants, Chemical)
RN  - 1310-14-1 (goethite)
SB  - IM
MH  - *Iron/chemistry
MH  - Corrosion
MH  - *Water Pollutants, Chemical/analysis
MH  - Adsorption
OTO - NOTNLM
OT  - 2,4,6-Trichlorophenol
OT  - Ball milling method
OT  - Liquid-phase reduction
OT  - Sulfurized nanometer zero-valent iron
OT  - Vacuum CVD
COIS- Declaration of Competing Interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2023/04/04 06:00
MHDA- 2023/04/26 06:41
CRDT- 2023/04/03 18:04
PHST- 2022/12/28 00:00 [received]
PHST- 2023/03/21 00:00 [revised]
PHST- 2023/03/30 00:00 [accepted]
PHST- 2023/04/26 06:41 [medline]
PHST- 2023/04/04 06:00 [pubmed]
PHST- 2023/04/03 18:04 [entrez]
AID - S0147-6513(23)00368-8 [pii]
AID - 10.1016/j.ecoenv.2023.114864 [doi]
PST - ppublish
SO  - Ecotoxicol Environ Saf. 2023 May;256:114864. doi: 10.1016/j.ecoenv.2023.114864. 
      Epub 2023 Apr 1.