PMID- 37019224 OWN - NLM STAT- MEDLINE DCOM- 20230529 LR - 20230529 IS - 1879-1026 (Electronic) IS - 0048-9697 (Linking) VI - 880 DP - 2023 Jul 1 TI - Assessing pollution and health risks from chromite mine tailings contaminated soils in India by employing synergistic statistical approaches. PG - 163228 LID - S0048-9697(23)01847-8 [pii] LID - 10.1016/j.scitotenv.2023.163228 [doi] AB - Potentially toxic elements (PTEs) contamination in the agricultural soil can generate a detrimental effect on the ecosystem and poses a threat to human health. The present work evaluates the PTEs concentration, source identification, probabilistic assessment of health hazards, and dietary risk analysis due to PTEs pollution in the region of the chromite-asbestos mine, India. To evaluate the health risks associated with PTEs in soil, soil tailings and rice grains were collected and studied. The results revealed that the PTEs concentration (mainly Cr and Ni) of total, DTPA-bioavailable, and rice grain was significantly above the permissible limit in site 1 (tailings) and site 2 (contaminated) as compared with site 3 (uncontaminated). The Free ion activity model (FIAM) was applied to detect the solubility of PTEs in polluted soil and their probable transfer from soil to rice grain. The hazard quotient values were significantly higher than the safe (FIAM-HQ < 0.5) for Cr (1.50E+00), Ni (1.32E+00), and, Pb (5.55E+00) except for Cd (1.43E-03), Cu (5.82E-02). Severity adjustment margin of exposure (SAMOE) results denote that the PTEs contaminated raw rice grain has high health risk [Cr(SAMOE): 0.001; Ni(SAMOE): 0.002; Cd(SAMOE): 0.007; Pb(SAMOE): 0.008] for humans except for Cu. The Positive matrix factorization (PMF) along with correlation used to apportion the source. Self-organizing map (SOM) and PMF analysis identified the source of pollution mainly from mines in this region. Monte Carlo simulation (MCS) revealed that TCR (total carcinogenic risk) cannot be insignificant and children were the maximum sufferers relative to adults via ingestion-pathway. In the spatial distribution map, the region nearer to mine is highly prone to ecological risk with respect to PTEs pollution. Based on appropriate and reasonable evaluation methods, this work will help environmental scientists and policymakers' control PTEs pollution in agricultural soils near the vicinity of mines. CI - Copyright (c) 2023 Elsevier B.V. All rights reserved. FAU - Banerjee, Sonali AU - Banerjee S AD - Agricultural and Ecological Research Unit, Indian Statistical Institute, Giridih, Jharkhand 815301, India. FAU - Ghosh, Saibal AU - Ghosh S AD - Agricultural and Ecological Research Unit, Indian Statistical Institute, Giridih, Jharkhand 815301, India. FAU - Jha, Sonam AU - Jha S AD - Agricultural and Ecological Research Unit, Indian Statistical Institute, Giridih, Jharkhand 815301, India. FAU - Kumar, Sumit AU - Kumar S AD - Agricultural and Ecological Research Unit, Indian Statistical Institute, Giridih, Jharkhand 815301, India. FAU - Mondal, Gourav AU - Mondal G AD - Agricultural and Ecological Research Unit, Indian Statistical Institute, Giridih, Jharkhand 815301, India. FAU - Sarkar, Dibyendu AU - Sarkar D AD - Stevens Institute of Technology, Department of Civil, Environmental, and Ocean Engineering, Hoboken, NJ 07030, USA. FAU - Datta, Rupali AU - Datta R AD - Department of Biological Science, Michigan Technological University, MI, USA. FAU - Mukherjee, Abhishek AU - Mukherjee A AD - Agricultural and Ecological Research Unit, Indian Statistical Institute, Giridih, Jharkhand 815301, India. FAU - Bhattacharyya, Pradip AU - Bhattacharyya P AD - Agricultural and Ecological Research Unit, Indian Statistical Institute, Giridih, Jharkhand 815301, India. Electronic address: pradip.bhattacharyya@gmail.com. LA - eng PT - Journal Article DEP - 20230403 PL - Netherlands TA - Sci Total Environ JT - The Science of the total environment JID - 0330500 RN - 0 (Metals, Heavy) RN - 00BH33GNGH (Cadmium) RN - 2P299V784P (Lead) RN - 0 (Soil Pollutants) RN - 0 (Soil) SB - IM MH - Child MH - Adult MH - Humans MH - *Metals, Heavy/analysis MH - Cadmium/analysis MH - Environmental Monitoring/methods MH - Ecosystem MH - Lead/analysis MH - *Soil Pollutants/analysis MH - Soil MH - India MH - Risk Assessment MH - China OTO - NOTNLM OT - Chromite -asbestos mine OT - Multi-model analysis OT - Potentially toxic elements OT - Soil and health risk evaluation OT - Source apportionment COIS- Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2023/04/06 06:00 MHDA- 2023/05/29 06:42 CRDT- 2023/04/05 19:24 PHST- 2022/12/29 00:00 [received] PHST- 2023/03/29 00:00 [revised] PHST- 2023/03/29 00:00 [accepted] PHST- 2023/05/29 06:42 [medline] PHST- 2023/04/06 06:00 [pubmed] PHST- 2023/04/05 19:24 [entrez] AID - S0048-9697(23)01847-8 [pii] AID - 10.1016/j.scitotenv.2023.163228 [doi] PST - ppublish SO - Sci Total Environ. 2023 Jul 1;880:163228. doi: 10.1016/j.scitotenv.2023.163228. Epub 2023 Apr 3.