PMID- 37111974 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20230430 IS - 2073-4360 (Electronic) IS - 2073-4360 (Linking) VI - 15 IP - 8 DP - 2023 Apr 9 TI - Mechanical, Thermal, and Fire Retardant Properties of Rice Husk Biochar Reinforced Recycled High-Density Polyethylene Composite Material. LID - 10.3390/polym15081827 [doi] LID - 1827 AB - This study concentrated on the influence of rice husk biochar on the structural, thermal, flammable, and mechanical properties of recycled high-density polyethylene (HDPE). The percentage of rice husk biochar with recycled HDPE was varied between 10% and 40%, and the optimum percentages were found for the various properties. Mechanical characteristics were evaluated in terms of the tensile, flexural, and impact properties. Similarly, the flame retardancy of the composites was observed by means of horizontal and vertical burning tests (UL-94 tests), limited oxygen index, and cone calorimetry. The thermal properties were characterized using thermogravimetric analysis (TGA). For detailed characterization, Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) tests were performed, to elaborate on the variation in properties. The composite with 30% rice husk biochar demonstrated the maximum increase in tensile and flexural strength, i.e., 24% and 19%, respectively, compared to the recycled HDPE, whereas the 40% composite showed a 22.5% decrease in impact strength. Thermogravimetric analysis revealed that the 40% rice husk biochar reinforced composite exhibited the best thermal stability, due to having the highest amount of biochar. In addition, the 40% composite also displayed the lowest burning rate in the horizontal burning test and the lowest V-1 rating in the vertical burning test. The 40% composite material also showed the highest limited oxygen index (LOI), whereas it had the lowest peak heat release rate (PHRR) value (52.40% reduced) and total heat release rate (THR) value (52.88% reduced) for cone calorimetry, when compared with the recycled HDPE. These tests proved that rice husk biochar is a significant additive for enhancing the mechanical, thermal, and fire-retardant properties of recycled HDPE. FAU - Shah, Atta Ur Rehman AU - Shah AUR AUID- ORCID: 0000-0002-2456-9408 AD - Department of Mechanical Engineering, COMSATS University Islamabad, Wah Campus, Wah Cantt 47040, Pakistan. FAU - Imdad, Anas AU - Imdad A AD - Department of Mechanical Engineering, HITEC University, Taxila 47050, Pakistan. FAU - Sadiq, Atiya AU - Sadiq A AUID- ORCID: 0000-0002-4713-1716 AD - Department of Mechanical Engineering, HITEC University, Taxila 47050, Pakistan. FAU - Malik, Rizwan Ahmed AU - Malik RA AD - Department of Metallurgy & Materials Engineering, Faculty of Mechanical and Aeronautical Engineering, University of Engineering and Technology, Taxila 47050, Pakistan. FAU - Alrobei, Hussein AU - Alrobei H AUID- ORCID: 0000-0002-5294-9678 AD - Department of Mechanical Engineering, College of Engineering, Prince Sattam bin Abdullaziz University, AlKharj 11942, Saudi Arabia. FAU - Badruddin, Irfan Anjum AU - Badruddin IA AD - Department of Mechanical Engineering, College of Engineering, King Khalid University, Abha 61421, Saudi Arabia. LA - eng PT - Journal Article DEP - 20230409 PL - Switzerland TA - Polymers (Basel) JT - Polymers JID - 101545357 PMC - PMC10142718 OTO - NOTNLM OT - mechanical properties OT - polymer composites OT - recycled high density polyethylene OT - rice husk biochar OT - thermal properties COIS- The authors declare no conflict of interest. EDAT- 2023/04/28 06:41 MHDA- 2023/04/28 06:42 PMCR- 2023/04/09 CRDT- 2023/04/28 01:49 PHST- 2023/02/18 00:00 [received] PHST- 2023/03/30 00:00 [revised] PHST- 2023/03/31 00:00 [accepted] PHST- 2023/04/28 06:42 [medline] PHST- 2023/04/28 06:41 [pubmed] PHST- 2023/04/28 01:49 [entrez] PHST- 2023/04/09 00:00 [pmc-release] AID - polym15081827 [pii] AID - polymers-15-01827 [pii] AID - 10.3390/polym15081827 [doi] PST - epublish SO - Polymers (Basel). 2023 Apr 9;15(8):1827. doi: 10.3390/polym15081827.