PMID- 37140689
OWN - NLM
STAT- MEDLINE
DCOM- 20230508
LR  - 20230508
IS  - 1436-5073 (Electronic)
IS  - 0026-3672 (Linking)
VI  - 190
IP  - 5
DP  - 2023 May 4
TI  - Highly efficient nanocomposites based on molecularly imprinted magnetic covalent 
      organic frameworks for selective extraction of bisphenol A from liquid matrices.
PG  - 200
LID - 10.1007/s00604-023-05778-z [doi]
AB  - Highly efficient nanocomposites, hydrophobic molecularly imprinted magnetic 
      covalent organic frameworks (MI-MCOF), have been farbricated by a facile 
      Schiff-base reaction. The MI-MCOF was based on terephthalaldehyde (TPA) and 
      1,3,5-tris(4-aminophenyl) benzene (TAPB) as functional monomer and crosslinker, 
      anhydrous acetic acid as catalyst, bisphenol AF as dummy template, and 
      NiFe(2)O(4) as magnetic core. This organic framework significantly reduced the 
      time consumption of conventional imprinted polymerization and avoided the use of 
      traditional initiator and cross-linking agents. The synthesized MI-MCOF exhibited 
      superior magnetic responsivity and affinity, as well as high selectivity and 
      kinetics for bisphenol A (BPA) in water and urine samples. The equilibrium 
      adsorption capacity (Q(e)) of BPA on the MI-MCOF was 50.65 mg g(-1), which was 
      3-7-fold higher than of its three structural analogues. The imprinting factor of 
      BPA reached up to 3.17, and the selective coefficients of three analogues were 
      all > 2.0, evidencing the excellent selectivity of fabricated nanocomposites to 
      BPA. Based on the MI-MCOF nanocomposites, the magnetic solid-phase extraction 
      (MSPE), combined with HPLC and fluorescence detection (HPLC-FLD), offered 
      superior analytical performance: wide linear range of 0.1-100 mug L(-1), high 
      correlation coefficient of 0.9996, low limit of detection of 0.020 mug L(-1), good 
      recoveries of 83.5-110%, and relative standard deviations (RSDs) of 0.5-5.7% in 
      environmental water, beverage, and human urine samples. Consequently, the 
      MI-MCOF-MSPE/HPLC-FLD method provides a good prospect in selective extraction of 
      BPA from complex matrices while replacing traditional magnetic separation and 
      adsorption materials.
CI  - (c) 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Austria, 
      part of Springer Nature.
FAU - Xiang, Jianxing
AU  - Xiang J
AD  - College of Public Health and Management, Wenzhou Medical University, Wenzhou, 
      325035, China.
AD  - Chongqing Jiangbei Center for Disease Control and Prevention, Chongqing, 400000, 
      China.
FAU - Zhou, Peipei
AU  - Zhou P
AD  - College of Public Health and Management, Wenzhou Medical University, Wenzhou, 
      325035, China.
FAU - Mei, He
AU  - Mei H
AD  - College of Public Health and Management, Wenzhou Medical University, Wenzhou, 
      325035, China.
FAU - Liu, Xiaodong
AU  - Liu X
AD  - College of Public Health and Management, Wenzhou Medical University, Wenzhou, 
      325035, China.
FAU - Wang, Huili
AU  - Wang H
AD  - School of Environmental Science and Engineering, Suzhou University of Science and 
      Technology, Suzhou, 215009, China.
FAU - Wang, Xuedong
AU  - Wang X
AD  - School of Environmental Science and Engineering, Suzhou University of Science and 
      Technology, Suzhou, 215009, China. zjuwxd@163.com.
FAU - Li, Yanyan
AU  - Li Y
AD  - College of Public Health and Management, Wenzhou Medical University, Wenzhou, 
      325035, China. liyan@wmu.edu.cn.
AD  - Department of Sports and Health, Guangzhou Sport University, Guangzhou, 510500, 
      China. liyan@wmu.edu.cn.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20230504
PL  - Austria
TA  - Mikrochim Acta
JT  - Mikrochimica acta
JID - 7808782
RN  - 0 (Metal-Organic Frameworks)
RN  - MLT3645I99 (bisphenol A)
RN  - 059QF0KO0R (Water)
SB  - IM
MH  - Humans
MH  - *Metal-Organic Frameworks
MH  - *Molecular Imprinting/methods
MH  - Water
MH  - *Nanocomposites
MH  - Magnetic Phenomena
OTO - NOTNLM
OT  - Bisphenol A and structural analogues
OT  - High imprinting factor
OT  - Magnetic solid-phase extraction
OT  - Molecularly imprinted magnetic covalent organic frameworks
EDAT- 2023/05/04 12:42
MHDA- 2023/05/08 06:41
CRDT- 2023/05/04 11:08
PHST- 2022/12/09 00:00 [received]
PHST- 2023/04/02 00:00 [accepted]
PHST- 2023/05/08 06:41 [medline]
PHST- 2023/05/04 12:42 [pubmed]
PHST- 2023/05/04 11:08 [entrez]
AID - 10.1007/s00604-023-05778-z [pii]
AID - 10.1007/s00604-023-05778-z [doi]
PST - epublish
SO  - Mikrochim Acta. 2023 May 4;190(5):200. doi: 10.1007/s00604-023-05778-z.