PMID- 37141778
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20230518
LR  - 20230518
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 454
DP  - 2023 Jul 15
TI  - Light and nitrogen vacancy-intensified nonradical oxidation of organic 
      contaminant with Mn (III) doped carbon nitride in peroxymonosulfate activation.
PG  - 131463
LID - S0304-3894(23)00746-X [pii]
LID - 10.1016/j.jhazmat.2023.131463 [doi]
AB  - Recently, Mn-based materials have a great potential for selective removal of 
      organic contaminants with the assistance of oxidants (PMS, H(2)O(2)) and the 
      direct oxidation. However, the rapid oxidation of organic pollutants by Mn-based 
      materials in PMS activation still presents a challenge due to the lower 
      conversion of surface Mn (III)/Mn (IV) and higher reactive energy barrier for 
      reactive intermediates. Here, we constructed Mn (III) and nitrogen vacancies (Nv) 
      modified graphite carbon nitride (MNCN) to break these aforementioned 
      limitations. Through analysis of in-situ spectra and various experiments, a novel 
      mechanism of light-assistance non-radical reaction is clearly elucidated in 
      MNCN/PMS-Light system. Adequate results indicate that Mn (III) only provide a few 
      electrons to decompose Mn (III)-PMS* complex under light irradiation. Thus, the 
      lacking electrons necessarily are supplied from BPA, resulting in its greater 
      removal, then the decomposition of the Mn (III)-PMS* complex and light synergism 
      form the surface Mn (IV) species. Above Mn-PMS complex and surface Mn (IV) 
      species lead to the BPA oxidation in MNCN/PMS-Light system without the 
      involvement of sulfate (SO(4)(* ̶)) and hydroxyl radicals (*OH). The study 
      provides a new understanding for accelerating non-radical reaction in light/PMS 
      system for the selective removal of contaminant.
CI  - Copyright (c) 2023 Elsevier B.V. All rights reserved.
FAU - Si, Qishi
AU  - Si Q
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Inst 
      Technology, Harbin, Heilongjiang 150090 People's Republic of China.
FAU - Wang, Huazhe
AU  - Wang H
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Inst 
      Technology, Harbin, Heilongjiang 150090 People's Republic of China.
FAU - Kuang, Junyan
AU  - Kuang J
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Inst 
      Technology, Harbin, Heilongjiang 150090 People's Republic of China.
FAU - Liu, Banghai
AU  - Liu B
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Inst 
      Technology, Harbin, Heilongjiang 150090 People's Republic of China.
FAU - Zheng, Shanshan
AU  - Zheng S
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Inst 
      Technology, Harbin, Heilongjiang 150090 People's Republic of China.
FAU - Zhao, Qi
AU  - Zhao Q
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Inst 
      Technology, Harbin, Heilongjiang 150090 People's Republic of China.
FAU - Jia, Wenrui
AU  - Jia W
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Inst 
      Technology, Harbin, Heilongjiang 150090 People's Republic of China.
FAU - Wu, Yaohua
AU  - Wu Y
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Inst 
      Technology, Harbin, Heilongjiang 150090 People's Republic of China.
FAU - Lu, Hao
AU  - Lu H
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Inst 
      Technology, Harbin, Heilongjiang 150090 People's Republic of China.
FAU - Wu, Qinglian
AU  - Wu Q
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Inst 
      Technology, Harbin, Heilongjiang 150090 People's Republic of China.
FAU - Yu, Tao
AU  - Yu T
AD  - Tianjin Univ, Sch Chem Eng & Technol, Tianjin 300350, People's Republic of China.
FAU - Guo, Wanqian
AU  - Guo W
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Inst 
      Technology, Harbin, Heilongjiang 150090 People's Republic of China. Electronic 
      address: guowanqian@hit.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20230421
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
SB  - IM
OTO - NOTNLM
OT  - Light assistance
OT  - Mn-PMS complex
OT  - Nitrogen vacancy
OT  - Non-radical reaction
OT  - Surface Mn (IV) species
COIS- Declaration of Competing Interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2023/05/05 00:42
MHDA- 2023/05/05 00:43
CRDT- 2023/05/04 18:06
PHST- 2023/03/02 00:00 [received]
PHST- 2023/04/19 00:00 [revised]
PHST- 2023/04/19 00:00 [accepted]
PHST- 2023/05/05 00:43 [medline]
PHST- 2023/05/05 00:42 [pubmed]
PHST- 2023/05/04 18:06 [entrez]
AID - S0304-3894(23)00746-X [pii]
AID - 10.1016/j.jhazmat.2023.131463 [doi]
PST - ppublish
SO  - J Hazard Mater. 2023 Jul 15;454:131463. doi: 10.1016/j.jhazmat.2023.131463. Epub 
      2023 Apr 21.